• Title/Summary/Keyword: temperature limit

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Delayed Mode Quality Control of Argo Data and Its Verification in the Pacific Ocean (태평양 Argo 자료의 지연모드 품질관리 및 검증연구)

  • Yang, Joon-Yong;Kang, Seong-Yun;Go, Woo-Jin;Suh, Young-Sang;Seo, Jang-Won;Suk, Moon-Sik
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1353-1361
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    • 2008
  • Quality control of Argo(Array for Real-time Geostrophic Oceanography) data is crucial by reason that salinity measurements are liable to experience some drift and offset due to biofouling, contamination of sensor and wash-out of biocide. The automated Argo real-time quality control has a limit of sorting data quality, so that WJO program is adopted as standardized method of Argo delayed mode quality control (DMQc) in the world that is a precise quality control method. We conducted DMQC on pressure, temperature and salinity measured by Argo floats in the Pacific Ocean including expert evaluation. Particularly, salinity data were corrected using WJO program. 4 salinity profiles of Argo delayed mode were compared with nearby in situ CTD data and other Argo data in deep layer where oceanographic conditions are stable in time and space. The differences of both salinities were lower than target accuracy of Argo. As compared with the difference of salinities before DMQC, those after DMQC decreased by 60-80 percent. Quality of delayed mode salinity data seemed to be improved correcting salinity data suggested by WJO program.

Microstructures and Electrical Conducting Properties of $Gd_24$O_3$-$Y_2$$O_3$-$CeO_2$Solid Electrolyte ($Gd_24$O_3$-$Y_2$$O_3$-$CeO_2$계 고체 전해질의 미세구조 및 전기전도 특성)

  • 장복기;신동선;임용무
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.12 no.1
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    • pp.44-49
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    • 1999
  • In this study, microstructure and electrical conductivity of {(G $d_2$ $O_3$)$_{0.75}$( $Y_2$ $O_3$)$_{0.25}$}$_{x}$ (Ce $O_2$)$_{1-x}$ (0.01$\leq$x$\leq$0.25) was investigated as a function of composition x. GYO addition(x) increased the bulk density and G $d_2$ $O_3$ was found to be monoclinic at x>0.15. From the change of the lattice parameter with the addition(x), GYO solution limit for ceria was exceeded in the range of x=0.05 to 0.09. Thermal expansion coefficient(15~17$\times$10$^{-6}$ $^{\circ}C$) of GYC samples at x=0.01 to 0.07 was higher in value than that of 8YSZ(10.8$\times$10$^{-6}$ $^{\circ}C$). The electrical conductivity of GYC samples at x=0.05 showed the maximum(0.01S/cm) in value at 1073K which was 2 times higher than that of 8YSZ. The activation energy for the electrical conduction was determined to be 0.60eV in the temperature range of 1073K.3K..3K.

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Nanostructured Metal Organic Framework Modified Glassy Carbon Electrode as a High Efficient Non-Enzymatic Amperometric Sensor for Electrochemical Detection of H2O2

  • Naseri, Maryam;Fotouhi, Lida;Ehsani, Ali
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.28-36
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    • 2018
  • Metal-organic frameworks have recently been considered very promising modifiers in electrochemical analysis due to their unique characteristics among which tunable pore sizes, crystalline ordered structures, large surface areas and chemical tenability are worth noting. In the present research, $Cu(btec)_{0.5}DMF$ was electrodeposited on the surface of glassy carbon electrode at room temperature under cathodic potential and was initially used as the active materials for the detection of $H_2O_2$. The cyclic voltammogram of $Cu(btec)_{0.5}DMF$ modified GC electrode shows distinct redox peaks potentials at +0.002 and +0.212 V in 0.1 M phosphate buffer solution (pH 6.5) corresponding to $Cu^{(II)}/Cu^{(I)}$ in $Cu(btec)_{0.5}DMF$. Acting as the electrode materials of a non-enzymatic $H_2O_2$ biosensor, the $Cu(btec)_{0.5}DMF$ brings about a promising electrocatalytic performance. The high electrocatalytic activity of the $Cu(btec)_{0.5}DMF$ modified GC electrode is demonstrated by the amperometric response towards $H_2O_2$ reduction with a wide linear range from $5{\mu}M$ to $8000{\mu}M$, a low detection limit of $0.865{\mu}M$, good stability and high selectivity at an applied potential of -0.2 V, which was higher than some $H_2O_2$ biosensors.

The Measurement and Investigation of Fire and Explosion Characteristics of Isopropyl Alcohol (이소프로필 알코올의 화재 및 폭발 특성치의 측정 및 고찰)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.16 no.3
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    • pp.8-15
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    • 2012
  • For the safe handling of isopropyl alcohol, the explosion limits were investigated. The lower flash points, upper flash points, fire point, and AITs(autoignition temperatures) by ignition time delay for isopropyl alcohol were experimented. By using literature data, the lower and upper explosion limits of isopropyl alcohol were recommended as 2.0 and 12.0 vol%, respectively. The lower flash points of isopropyl alcohol were experimented $12{\sim}14^{\circ}C$ by using closed-cup tester and $18{\sim}19^{\circ}C$ by using open cup tester. And the upper flash points of isopropyl alcohol was experimented $38^{\circ}C$ by using Setaflash closed-cup tester. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus was $463^{\circ}C$.

Thermoelectric Properties of Skutterudite FexCo4-xSb12 Synthesized by Mechanical Alloying Process (기계적 합금화에 의한 Skutterudite계 FexCo4-xSb12의 합성 및 열전특성)

  • Kwon, Joon-Chul;Kim, Il-Ho;Ur, Soon-Chul
    • Journal of Powder Materials
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    • v.12 no.5 s.52
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    • pp.357-361
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    • 2005
  • Fe-doped skutterudite $CoSb_3$ with a nominal composition of $Fe_{x}Co_{4-x}Sb_{12}(0\;{\le}\;x\;{\le}\;2.5)$ has been synthesized by mechanical alloying (MA) of elemental powders, followed by hot pressing. Phase transformations during mechanical alloying and hot pressing were systematically investigated using XRD. Single phase skutterudite was successfully produced by vacuum hot pressing using as-milled powders without subsequent annealing. However, second phase in the form of marcasite structure $FeSb_2$ was found to exist in case of $x\;{\ge}\;2$, suggesting the solubility limit of Fe with Co in this system. Thermoelectric properties as functions of temperature and Fe contents were evaluated for the hot pressed specimens. Fe substitution up to x=1.5 with Co in $Fe_{x}Co_{4-x}Sb_{12}$ appeared to increase thermoelectric figure of merit (ZT) and the maximum ZT was found to be 0.78 at 525K in this study.

Development of a Site Index Equation for Pinus koraiensis Based on Environmental Factors and Estimation of Productive Areas for Reforestation (환경요인에 의한 잣나무의 지위지수 추정식 개발과 적지 판정)

  • Shin Man-Yong;Jung Il-Bin;Koo Kyo-Sang;Won Heong-Gyu
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.8 no.2
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    • pp.97-106
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    • 2006
  • Site index is an essential tool to estimate forest productivity. Generally, a site index equation is developed and used from the relationship between stand age and dominant tree heights. However, there is a limit to the use of the site index equation in the application of variable ages, environmental influence, and estimation of site index for the unstocked forest. Therefore, it has been attempted to develop a new site index equation based on various environmental factors including site, climate, and topographical variables. This study was conducted to develop a site index equation based on the relationship between site index and environmental factors for the species of Pinus koraiensis in Yangpyung-Gun, Gyunggi Province. The influence of climatic factors (temperature and solar irradiation ratio), topographical factors (elevation, slope, ratio of slope to valley and aspect) and soil profiles (soil depth by layer and soil consistency) on site index were evaluated by multiple regression analysis. Five environmental factors were selected in the final site index equation for Pinus koraiensis. The site index equation developed in this study was also verified by three evaluation statistics: model's estimation bias, model's precision, and mean square error of measurement. Based on the site index equation, the number of productive areas for Pinus koraiensis were estimated by applying GIS technique to digitized forest maps. In addition, the distribution of productive areas was compared with the areas of current distribution of Pinus koraiensis. It is expected that the results obtained in this study could provide valuable information about the amount and distribution of productive areas for Pinus koraiensis reforestation.

Continuous Disk Winding for High Voltage Superconducting Transformer (초고압 초전도 변압기용 연속 디스크 권선)

  • Hwang, Y.I.;Kim, W.S.;Lee, S.;Chang, T.;Hahn, J.H.;Joo, H.G.;Choi, K.D.;Hahn, S.
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1234-1236
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    • 2005
  • High temperature superconducting(HTS) windings for an HTS transformer which have been developed have two kinds of type, one is the layer type and the other is disk type. The disk type windings have advantages over the layer type ones for a power transformer such as good insulation and limit of voltage stress. But this kind of HTS winding generates excessive AC losses caused by strong magnetic field component perpendicular to the surface of the HTS wire. Nevertheless, the layer type windings have adopted for an HTS power transformer so far because of the small AC losses of the HTS windings. We propose a new winding method for a high voltage HTS transformer which has advantages of both type of HTS windings, and we call it continuous disk type HTS winding. This new type of HTS winding consists of pile of lots of HTS disk windings which have no resistive joint between them. A prototype of an HTS winding was fabricated by the new winding method we proposed and characteristic test was carried out. The test result shows that the new type HTS windings can be applied to HTS power transformers, especially to the high voltage ones.

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Control of Microbial Shelf Life of Perishable Food by Real-Time Monitoring of $CO_2$ Concentration of its Package (변패성 식품의 포장 내 $CO_2$ 농도의 실시간적 측정에 의한 미생물적 저장수명 제어)

  • Kim, Hwan-Ki;An, Duck-Soon;Lee, Hyuk-Jae;Lee, Dong-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.17 no.2
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    • pp.33-37
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    • 2011
  • Real time control logic of microbial shelf life of a perishable food, seasoned pork meat has been formulated which exploits monitoring of $CO_2$ concentration of the package. The potential of the proposed logic was examined for storage at dynamic temperature conditions. The start of increase in $CO_2$ production rate from the food or rate of package $CO_2$ concentration change was found to coincide with the point of microbial quality limit and could be used as an index of microbial shelf life determination. This also corresponded to lag time of $CO_2$ concentration change or time for the $CO_2$ concentration to reach a certain value. The application potential of the proposed logic was confirmed for a sensor system to measure on real time and transmit the $CO_2$ concentration wireless to the computer system.

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The Effect of Chemical Pretreatment on Steam Explosion and Oxygen-alkali Pulping of Oak Wood (참나무재의 약액함침 처리가 폭쇄 및 산소-알칼리펄프화에 미치는 영향)

  • 박승영;최태호;조남석
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.75-83
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    • 2001
  • The potential of oxygen delignification is a powerful tool to reduce detrimental environmental effects. This study was performed to investigate the effect of steam explosion treatment of chemically treated oak wood on oxygen-alkali pulping. Pulp yield during steam explosion treatment by ${Na_2}{O_3}$-NaOH impregnation was higher than the other impregnation chemicals. Also, NaOH extraction at room temperature after steam explosion treatment improved the kappa number from 140~116 to 90~64. Oxygen-alkali pulping of chemical steam explosion treated woods affected to pulp yields. ${Na_2}{O_3}$-NaOH impregnation was very effective to higher carbohydrate yields at same delignification level. Its carbohydrate yield seemed to be highly related to the effluent pH. Oxygen-alkali pulping after steam explosion treatment of ${Na_2}{O_3}$-NaOH impregnated wood was shown that carbohydrate yield was very high because its effluent pH was increase from natural to mild alkali. Even if oxygen bleaching limit the delignification to 50% in order to avoid unacceptable yield and viscosity losses, oxygen-alkali pulping after steam explosion by ${Na_2}{O_3}$-NaOH impregnation was possible to extend the delignification more than 80%. Considering high pulp yield with lower lignin content from steam explosion treated wood, it might be profitable to end the cook at a high kappa number instead of a low kappa number, and continuously apply the oxygen delignification, in order to better quality pulp.

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Determination of Aluminum Leached from Cooking Utensils by using Flow Injection Analysis (흐름주입분석법에 의한 주방용기로부터 용출된 알루미늄의 정량)

  • Choi, Yong Wook
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.281-289
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    • 2004
  • Optimal analytical conditions have been established for mixing and reaction coil length, concentrations of ECR, CTAB, and acetate, reaction temperature and pH in the determination of aluminum by using flow injection analysis(FIA). Detection limit and repeatability for this system were $3{\mu}g/L$ and better than 1% of relative standard deviation, respectively. The interference from iron(III) was suppressed up to 6mg/L of iron(III) by $0.1{\mu}M$ ascorbic acid, and the interference from fluoride could be tolerated in absorption of Al/ECR/CTAB derivative by 10mM boric acid at pH 3.5 adjusted with nitric acid. This FIA system was applied to the determination of aluminum leached from cooking utensils by distilled and tap water containing fluoride ranged from 0.5 to 2mg/L by measurement of absorbance for Al/ECR/CTAB at 585nm. The leached aluminum content was increased with increasing concentration of fluoride. The aluminum contents leached from aluminum utensils by tap water were about 9 fold higher than those leached by distilled water, whereas aluminum contents leached by distilled water containing fluoride were about 2 fold higher compared to those leached by distilled water. That represented that other dissolved substances as well as fluoride in tap water contributed to liberation of aluminum from aluminum utensils. A comparison between FIA data and ICP-AES data by correlation and paired t test showed that the FIA system could be accepted as a good alternative method for the determination of aluminum in tap water.