• Title/Summary/Keyword: temperature cycles

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MOD 법으로 제조한 강유전성 SBT 박막에서 하부전극이 유전 및 전기적 특성에 미치는 영향 (Effects of Bottom Electrode to Dielectric and Electrical Properties of MOD Derived Ferroelectric SBT Thin Films)

  • 김태훈;송석표;김병호
    • 한국전기전자재료학회논문지
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    • 제13권8호
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    • pp.694-699
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    • 2000
  • S $r_{0.9}$/B $i_{2.1}$/T $a_{2}$/ $O_{9}$ solutions was synthesized by MOD (metalorganic decomposition) method. SBT thin films with 2000$\AA$ thickness were prepared on Ir $O_2$/ $SiO_2$/Si and Pt/Ti/ $SiO_2$/Si substrates using the spin coating process and then investigated the dielectric and electrical properties of them. In the case of using Ir $O_2$bottom electrode the hysteresis loop was saturated at lower temperature than Pt/Ti electrode but the breakdown phenomenon was occurred at low voltage because of the rough surface morphology and porous microstructure of SBT thin films. As the results of the fatigue and imprint characteristics related to the lifetime and reliability of devices after 10$^{10}$ cycles the fatigue rates were about 10% at the Ir $O_2$and Pt/Ti bottom electrodes. Both SBT thin films with Ir $O_2$ and with Pt/Ti bottom electrodes show a slight tendency to imprint after 10$^{9}$ cycles but do not lead to a failure.e.e.

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열충격에 의한 열차폐 코팅재의 기계적 거동 변화 (Changes in the Mechanical Behavior of Thermal Barrier Coatings Caused by Thermal Shock)

  • 장빈;이기성;김태우;김철
    • 한국재료학회지
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    • 제27권1호
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    • pp.25-31
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    • 2017
  • This study investigates changes in the mechanical behaviors, especially hardness and indentation load-displacement curves, of thermal barrier coatings (TBCs) brought about by thermal shock. The TBCs on the Nickel-based bondcoat/superalloy was prepared with diameters of 25.4 mm and $600{\mu}m$ thickness. The results of thermal shock cycling test from $1100^{\circ}C$ of the highest temperature indicate that the thermal shock do not influence on the mechanical behavior, but a continuous decrease in porosity and increase in hardness were observed after 1200 thermal shock cycles; these changes are believed to be due to sintering of thermal barrier coating materials. The results that no degradation in the indentation load-displacement curves indicate that the coating shows good thermal shock resistance up to 1200 cycles at $1100^{\circ}C$ in air.

접시형 태양열 집광 시스템을 이용한 열화학 사이클의 수소생산 (TWO-STEP THERMOCHEMICAL CYCLES FOR HYDROGEN PRODUCTION WITH DISH TYPE SOLAR THERMAL SYSTEM)

  • 권해성;오상준;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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    • pp.169-176
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    • 2011
  • The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

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반복 열처리한 Nd-Fe-B 소결 자석의 미세구조 제어 및 자성특성 평가 (Microstructure Control and Magnetic Property of Nd-Fe-B Sintered Magnets After Cyclic Heat Treatment)

  • 김세훈;김훈섭;김동환;김영도
    • 한국분말재료학회지
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    • 제15권6호
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    • pp.471-476
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    • 2008
  • Sintered Nd-Fe-B magnets have been widely used due to their excellent magnetic properties, especially for driving motors of hybrid and electric vehicles. The microstructure of Nd-Fe-B magnets strongly affects their magnetic properties, in particular the coercivity. Therefore, a post-sintering process like heat-treatment is required for improving the magnetic properties of Nd-Fe-B sintered magnets. In this study, cyclic heat treatment was performed at temperatures between $350^{\circ}C$ and $450^{\circ}C$ up to 16 cycles in order to control microstructures such as size and shape of the Nd-rich phase without grain growth of the $Nd_{2}Fe_{14}B$ phase. The 2 cycles specimen at this temperature range showed more homogeneous microstructure which leads to higher coercivity of 35 kOe than as-sintered one.

팽창기를 적용한 이산화탄소 냉방시스템의 성능특성에 관한 해석적 연구 (Simulation Study on the Performance Characteristics of a $CO_2$ Cooling System with an Expander)

  • 조홍현;백창현;류창기;김용찬
    • 설비공학논문집
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    • 제19권9호
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    • pp.630-639
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    • 2007
  • A $CO_2$ cycle shows large throttling loss during the expansion process. The application of an expander into the $CO_2$ cycle can reduce the throttling loss and then improve system performance. In this study, the performance of a transcritical $CO_2$ cycle with an expander was analytically investigated in order to improve the cooling performance of the system. The expander was applied to the single-stage and two-stage compression cycles. The performance was analyzed with the variations of compressor frequency, outdoor temperature, and expander efficiency. The single-stage and two-stage compression cycles with the expander showed COP improvement of 25% and 32%, respectively, over the single-stage cycle with an EEV.

금속 수소화물 전극제조에 있어서 알카리 무전해 구리 도금법의 응용 (Application of an electroless copper coating in alkaline bath to preparation of the metal hydride electrode)

  • 최전;박충년
    • 한국수소및신에너지학회논문집
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    • 제3권2호
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    • pp.9-15
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    • 1992
  • Electroless copper plating method using an alkaline bath have been employed in copper coating of the (LM)Ni4.5Co0.1MnO.2A10.2 hydrogen storage alloy powders for electrode preparation. The plating were conducted without any pretreatment of alloy powders. For the preparation of the electrodes, about 0.12g of the copper coated alloy powder (copper to alloy ratio 1/3 by weight) was compacted with pressure of 6 tons/cm2 at room temperature. The disk-type compacts had a diameter of 10mm and thickness of about 0.24mm. The electrode characteristics were examined through SEM observations and electrochemical measurements in a half cell. The electrochemical measurement showed that the maximum discharge capacity of the electrodes prepared by using alkaline bath were 245mAh per gram of coated alloy (327mAh per gram of alloy) and appeared a considerable degradation with increasing number of cycles. The decrease of the discharge capacity after 100 cycles was about 30% It can be suggested that, with a slight of improvement, this electroless copper plating method could be applied to the preparation of the rare earth-nickel based alloy electrode.

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VRFB-LFPB 하이브리드 배터리 기반의 ESS 개발에 관한 연구 (Development of ESS Based on VRFB-LFPB Hybrid Batteries)

  • 천영식;박진수;유진호;이진
    • 한국전기전자재료학회논문지
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    • 제31권1호
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    • pp.61-67
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    • 2018
  • High-power lithium batteries are suitable for equipment with high power output needs, such as for ESS's initial start-up. However, their management cost is increased by the installation of air-conditioning to minimize the risk of explosion due to internal temperature rise and also by a restriction on the number of charge/discharge cycles. High-capacity flow batteries, on the other hand, have many advantages. They can be used for over 20 years due to their low management costs, resulting from no risk of explosion and a high number of charge/discharge cycles. In this paper, we propose an ESS based on hybrid batteries that uses a lithium iron phosphate battery (LiFePO) at the initial startup and a vanadium redox flow battery (VRFB) from the end of the transient period, with a bi-directional PCS to operate two batteries with different DC voltage levels and using an efficient energy management control algorithm.

동결-융해작용에 따른 암석풍화의 특성 - 유문암, 현무암, 응회암을 중심으로 - (The Characteristics of Rock Weathering due to Freeze-Thawing - Focused on Rhyolite, Basalt, Tuff -)

  • 양재혁
    • 한국지형학회지
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    • 제25권1호
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    • pp.47-65
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    • 2018
  • Frost shattering has traditionally been considered as one of the most effective process in rock weathering. Each slab specimens of five or six rhyolite, basalt and tuff was prepared and put in freeze-thaw cycles and repeated 300 times in the temperature of $-25^{\circ}C$ to $+30^{\circ}C$ and their weathering patterns and products were analyzed by surface observation, particle size, XRD and thin section. As the result, some changes were observed in weathering patterns and weathering products. Rock shattering was more active in waterlogging rather than atmospheric conditions, but there are many differences depending on the type of rock. Rhyolite is hardly weathered by 300 times freeze-thaw cycles and generates the least amount of weathering products. Weathering of Basalt is limited to the surface layer where water can be absorbed, and produces a few amount of platy-shape debris. Tuff are separated by blocky structure which the particles are aggregated along their edges rather than enlarged existing cracks/joins or generated new joints.

냉간가공된 TP304 스테인리스강 모재와 용접재를 이용한 반복 변형 및 손상 거동에 미치는 중성자조사 영향 모사 (Simulating Nuetron Irradiation Effect on Cyclic Deformation and Failure Behaviors using Cold-worked TP304 Stainless Steel Base and Weld Metals)

  • 김상언;김진원
    • 한국압력기기공학회 논문집
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    • 제16권2호
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    • pp.58-67
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    • 2020
  • This study presents cyclic stress-strain and tensile test results at room temperature (RT) and 316℃ using cold-worked TP304 stainless steel base and weld metals. By comparing the cyclic hardening/softening behavior and failure cycle of cold-worked materials with those of irradiated austenitic stainless steels, the feasibility of simulating the irradiation effect on cyclic deformation and failure behaviors of TP304 stainless steel base and weld metals was investigated. It was found that, in the absence of strain-induced martensite trasformation, cold-working could properly simulate the change in cyclic hardening/softening behavior of TP304 stainless steel base and weld metals due to neutron irradiation. It was also recognized that cold-working could adequately simulate the reduction in failure cycles of TP304 stainless steel base and weld metals due to neutron irradition in the low-cycle fatigue region.

Life Prediction of Hydraulic Concrete Based on Grey Residual Markov Model

  • Gong, Li;Gong, Xuelei;Liang, Ying;Zhang, Bingzong;Yang, Yiqun
    • Journal of Information Processing Systems
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    • 제18권4호
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    • pp.457-469
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    • 2022
  • Hydraulic concrete buildings in the northwest of China are often subject to the combined effects of low-temperature frost damage, during drying and wetting cycles, and salt erosion, so the study of concrete deterioration prediction is of major importance. The prediction model of the relative dynamic elastic modulus (RDEM) of four different kinds of modified concrete under the special environment in the northwest of China was established using Grey residual Markov theory. Based on the available test data, modified values of the dynamic elastic modulus were obtained based on the Grey GM(1,1) model and the residual GM(1,1) model, combined with the Markov sign correction, and the dynamic elastic modulus of concrete was predicted. The computational analysis showed that the maximum relative error of the corrected dynamic elastic modulus was significantly reduced, from 1.599% to 0.270% for the BS2 group. The analysis error showed that the model was more adjusted to the concrete mixed with fly ash and mineral powder, and its calculation error was significantly lower than that of the rest of the groups. The analysis of the data for each group proved that the model could predict the loss of dynamic elastic modulus of the deterioration of the concrete effectively, as well as the number of cycles when the concrete reached the damaged state.