• Journal of the Korean Society of Clothing and Textiles
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• v.21 no.6
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• pp.970-976
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• 1997

Synthetic leather added collagen protein was coagulated in DMF solution. With increasing collagen concentration, thickness of synthetic leather increased. In addition, water vapor permeability and water vapor absoption increased with increasing collagen protein concentration. But MIU and SMD value of surface properties decreased with increasing collagen protein concentration. As a result, synthetic leather added collagen protein showed comfort and dry touch.

• Textile Coloration and Finishing
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• v.35 no.1
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• pp.42-65
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• 2023

Leather is widely used in human lives and many industries, and the market size continues to grow. In terms of quality and durability, natural leather is still being used as the most luxurious product. And synthetic leather, made of polyvinyl chloride (PVC) and polyurethane (PU), were developed and being widely have been used as alternative materials for natural leather. Processes, properties and issues of these leather were reviewed. Then silicone leather was reviewed why they can be good candidates for leather. Properties of general silicone polymers and silicone rubber coating agents were reviewed such as eco-friendliness, human-friendliness, stain resistances, resistance to uv light and ozone, heat stability and so on. Papers and patents related to silicone leather were studied to understand current status of development and commercialization of silicone leather. Finally direction of development was described how to improve deficient performances of current silicone leather, such as formulation of silicone, combination with organic materials and manufacturing processes.

• Science of Emotion and Sensibility
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• v.25 no.2
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• pp.55-70
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• 2022

In the 21^st century, the demand for eco-friendly leather, such as eco-leather and vegan leather, is steadily increasing. This study examines the influence of eco-friendliness on consumers' purchasing intentions and the possibility of eco-friendly changes in the fashion accessory market, which is dominated by leather material and leather substitutes. This study administered a questionnaire survey to 227 males and females between 20 and 60 years of age in Korea. With a 5-point Likert scale, data were collected on evaluation criteria when purchasing shoes and bags and purchasing intention of various leather substitute materials according to the democratic variables. The eco-friendliness attitude was divided into eco-consciousness and green behavior. As the eco-friendly attitude increased, most purchasing standards increased, but the purchasing criteria, such as trends, brands, and prices, did not correlate with the eco-friendly attitude. The eco-consciousness of a consumer had a high correlation with the design evaluation criteria, while the green behavior of the consumer aligned with durability and comfort criteria when purchasing a bag. There was a preference for recycled leather, vegetable leather, synthetic leather, and chemical leather, and the fabric type was ranked as natural fiber, biodegradable fiber, and synthetic fiber. Consumers with both green behavior and eco-consciousness are more likely to purchase biodegradable textiles and vegetable leather for the material of shoes and bags.

• Journal of the Korean Society of Clothing and Textiles
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• v.23 no.4
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• pp.541-550
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• 1999

The purpose of this study is to find out the factors that explain the sense of touch and preference of man-made leather. Date base of descriptors for man-made leather was collected by interviewing 50 consumers, 33 different kinds of commercial man-made leathers(synthetic leather and artificial leather) were assessed subjectively by 605 consumers using the 9-point scale of 34 pairs of bipolar descriptors based on the data base. Subjective ratings were analyzed by principal axis factoring with varimax rota-tion. The sense of touch of man-made leather is explained by five factors ; surface property stretchiness thickness& weight thermal property(warmth & coolness) and moisture property (sticky & clingy). The difference in the sense of touch of man-made leathers is mainly attributable to surface property and stretchiness. And the preference of man-made leathers is mainly attributable to surface property and stretchiness. And the preference of man-made leather is explained by three factors ; surface property stretchiness and quality. Higher preference is found in man-mad leather of better quality touch and softness.

• Textile Coloration and Finishing
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• v.31 no.3
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• pp.177-186
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• 2019

In this study, we investigated for synthetic hydrotalcite in chloroprene rubber foam. Experiments were carried out to find the optimum content ratio by controlling the contents of MgO and Hydrotalcite. Swelling test in toluene immersion was made to measure the crosslinking density of CR foams, and the cure properties were investigated with flat die rheometer and Mooney viscosity. The difference of hardness, tensile strength and elongation at break were observed after immersing in 7% NaCl or 21% NaCl solutions for a day and four days. In addition, the volume change and water content remaining in CR foam were measured after immersing NaCl solution. As content of MgO increased, the value of the cure torque tended to increase, but it was almost constant above 2phr of MgO. However, the Mooney viscosity decreased with increasing MgO content. The crosslinking density, determined by the swelling ratio, showed that the CR compound without MgO showed a higher degree of swelling. When the content of hydrotalcite/MgO was 3:2, it was the lowest volume change of CR form. Also, As the content of hydrotalcite decreased, the difference of mechanical properties before and after immersion NaCl solution increased.

• Clean Technology
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• v.11 no.2
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• pp.83-90
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• 2005

This paper is about a new method of synthesis organic tanning agent (polymer, polyphenol, polyresin) and discusses their tanning property. It was found that properties of the leather manufactured with application of organic tanning agent were similar to those applied with conventional chrome tanning agent and reducing effects of Cr, T-N, COD, SS concentrations in the effluent.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.19 no.2
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• pp.113-126
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• 2009

In the recent years, health effect of dimethylformamide(DMF) has been one of critical industrial hygiene issues. There might be many factors to increase the exposure level of DMF. Among those factors, industrial ventilation would be one of the main factors. In this study, industrial ventilation systems of printing processes in synthetic leather factories were thoroughly surveyed and the improved ventilation systems were proposed. 7 synthetic leather factories were selected for this study. After the ventilation systems were visually inspected, each component of the system was tested by using the appropriate instruments. Hood face velocities, fan exhaust flow rates, fan static pressures, fan rotation rates, etc were measured. In addition, flow visualization techniques were used to observe flow patten around hoods and inside the factory buildings. After gathering all qualitative and quantitative information, the test results were analysed to see if any improvement might be necessary. For the system to be improved, the re-design plans were made by using computational fluid dynamics softwares. The softwares used in this study were AIRPAK and STAR-CD. The effectiveness of the several improvement options were tested, then the best cost effective option was selected. Finally, the standard ventilation systems were proposed to minimize the exposure levels of DMF.

• Journal of the Korea Fashion and Costume Design Association
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• v.2 no.2
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• pp.137-154
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• 2000

The purpose of this study is to investigate the transition of luster material after the tweentieth century. This study was conducted by means of designer collection, journal of fashion, museum data, fabric exhibition and Internet data. The results of this study were as follows: Before the synthetic fiber period, the luster materials were used satin, chamuse, gauze, damask brocade and velvet, except cashmere, mohair and rayon. They are made from silk by the way of giving difference surface property. But since 1960s, it has used not only synthetic fiber with smooth surface but also vinyl, latex, natural leather, synthetic leather and metal. Luster material recently has a tendency to natural and soft shiny, example silket finish, chintz finish, silico coating finish with paper touch feel and so forth.

• The Research Journal of the Costume Culture
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• v.24 no.6
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• pp.817-824
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• 2016

The introduction of natural dyes into modern dye houses is very promising green chemistry concept that should be popularized more to reduce the dependency of leather dyeing on some toxic and non-biodegradable synthetic dyes. In this study, the properties of dyeing of cochineal on cow leather were evaluated. The proper dyeing conditions were identified with dye uptake (K/S values) depending on the colorant concentration, dyeing duration, dyeing temperature, and dye bath pH. For the proper mordanting conditions, color changes for different mordants were observed as $La^{*}b^{*}$ and H V/C values. Color fastness (light, rubbing, and dry cleaning) was also examined. Additionally, antibacterial properties and UV protection were examined. The results were as follows: The optimized dyeing conditions were 300% o.w.f., $40^{\circ}C$, 40 min., and pH 5. The cow leather color was red in the absence of mordanting, while it was red purple after being mordanted with Al and Cu, and purple mordanted with Fe. The K/S value of cow leathers increased in the order of the dyeing using $AlK(SO_4)_2$ > $CuSO_4$ > $FeSO_4$. The colorfastness to light and rubbing were reduced compared to original (untreated) cow leather. However dry cleaning fastness was very satisfactory, with a 4~5 rating. The dyed and pre-mordanting dyed cow leather showed excellent antibacterial properties.

• Journal of Adhesion and Interface
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• v.19 no.1
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• pp.5-12
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• 2018

The purpose of this study is to evaluate the adhesive properties of polyurethane mixed aqueous dispersions by omitting the primer, dealing with the preparation of skins for synthetic leather with excellent adhesion by omitting the pre-treatment process. The two-component mixed polyurethane water dispersion was prepared by synthesizing an ester-based polyurethane resin (PU-T) and a carbonate-based polyurethane resin (PU-C) to obtain the final resin. As a result of measuring the peel strength of the adhesive specimens omitting the pre-treatment agent, it was confirmed that the state adhesive strength (ethylene vinyl acetate (middle): $4.2kg_f/cm$ and rubber (outsole): $4.4kg_f/cm$) there was. This makes it possible to omit the pre-treatment process which has been indispensably used in the shoe manufacturing process, thereby reducing the process time and reducing the amount of volatile organic compounds (VOCs) generated in the pre-treatment product, resulting in environmentally advantageous.