• 제목/요약/키워드: swelling agent

검색결과 175건 처리시간 0.021초

면편성물의 방염처리에 의한 방염성과 물성변화 (Changes of Flame Retardant and Physical Properties of Cotton Knitted Fabrics after Flame Resistant Treatment)

  • 지주원;송경근
    • 한국의류산업학회지
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    • 제5권3호
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    • pp.273-282
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    • 2003
  • Effect of fixation methods and relaxation treatment on the flame retardant(FR) and physical properties of MDPP/HMM treated cotton weft-knitted fabrics were studied. Combination of four different fixation methods - relaxation, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of cotton weft-knitted fabric with MDPP/HMM. As the results, 1. Swelling agent and wet fixation method helps FR agent penetrate the fiber efficiently. Interlock showed relatively higher values of LOI than single jersey. 2. Interlock showed relatively higher values of bending rigidity(B), shear rigidity(G) and coefficient of friction(MIU) than those of single jersey before and after flame resistant treatment. 3. An increase in internal volume of cotton fiber by relaxation treatment increased the bending rigidity(B), shear rigidity(G) and compressional energy(WC). 4. The cotton weft-knitted fabric treated wet fixation, which crossliked FR agent efficiently, showed higher bending rigidity, shear rigidity(G) and lower compressional energy(WC). Retention of swelling ability of cotton weft-knitted fabrics treated with MDPP/HMM, which increased the internal volume of cotton weft-knitted fabric, showed lower bending rigidity.

글리콜키토산을 이용한 초다공성 하이드로젤의 제조 및 팽윤거동 (Preparation and Swelling Property of Superporous Hydrogels using Glycol Chitosan)

  • 광가;이정정;윤취임;육군영;허강무
    • 한국응용과학기술학회지
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    • 제26권3호
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    • pp.263-268
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    • 2009
  • Superporous Hydrogels (SPHs) have been extensively investigated for various biomedical applications due to their fast swelling and superabsorbent properties. In this study, glycol chitosan that is one of most abundant natural polymers was used as a cross-linking agent instead of bisacrylamide (BIS), which is a broadly used crosslinking agent for preparation of SPHs. Glycol chitosan was modified to have reactive vinyl groups by chemical conjugation with glycidyl methacrylate (GMA). The vinyl group-containing glycol chitosan (GC-GMA) was characterized by FT-IR and $^1H$-NMR measurements. SPHs have been prepared in various synthetic conditions to establish the optimum synthetic process for making superporous structure, where the inner pores are interconnected to each other to form a open channel structure. Various SPHs with different GC-GMA contents have been successfully prepared and have been observed to show faster swelling properties than other conventional SPHs. From the study on the swelling behavior of SPHs, the GC-GMA content is considered to be an important factor for controlling their swelling properties.

가교제의 종류가 천연고무 발포체의 팽윤거동에 미치는 효과 (Influence of the Type of Curing Agent on Swelling Behavior of Natural Rubber Foam)

  • 이환광;정태경;김성찬;김현기;최경만;김영민;한동훈
    • 한국산학기술학회논문지
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    • 제9권6호
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    • pp.1775-1781
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    • 2008
  • 가교제의 종류가 헬리콥터 연료탱크의 자기밀폐층 소재로 적용시키기 위한 천연고무 스폰지의 팽윤에 미치는 효과를 조사하였다. 과산화물과 황을 섞은 가교방식과 과산화물에 의한 가교방식을 채택하였다. 천연고무 콤파운드를 Kneader와 Roll-Mill을 활용하여 제조하고, 고압조건의 프레스에서 부분 가교시킨 후 대기압의 금형에서 발포와 완전가교를 실시하였다. 얻어진 스폰지의 겉보기밀도를 측정하고 스폰지의 셀구조를 주사전자현미경을 통하여 관찰하였다. 톨루엔, 이소옥탄과 항공유를 사용하여 실온에서 팽윤실험을 실시하였다. 용매에 2분 동안 침적 후 얻어지는 부피팽윤비 값은 과산화물 가교에 의한 천연고무 스폰지가 비슷한 양의 황과 과산화물의 혼합가교에 의한 경우보다 높았다. 스폰지의 겉보기밀도와 셀구조는 과산화물 함량에 매우 민감하였으며 이는 또한 천연고무 스폰지의 팽윤거동에 영향을 미쳤다. 천연고무 스폰지가 연료와 접촉하여 신속한 팽윤이 얻어지기 위하여 금형에서 동시에 발생하는 두 가지 반응인 발포제의 분해반응과 천연고무의 가교반응을 적절히 조절하는 것이 중요하다.

항염 및 해열효과에 미치는 Ibuprofen과 Prednisolone의 약 상호 작용 (Drug Interactions of Ibuprofen and Prednisolone in Antiinflammatory and Antipyretic Effects)

  • 강영자;조윤성
    • 약학회지
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    • 제25권3호
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    • pp.109-114
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    • 1981
  • The authors investigated drug interaction of ibuprofen and prednisolone in antiinflammatory and antipyretic activities. We have found significant differences of the antiinflammatory and antipyretic activities between single and concurrent administration of ibuprofen and prednisolone, using Sprague-Dawley Strain rats, carrageenin as a phlogistic agent and brewer's yeast as a fever inducing agent. 1) Ibuprofen(20mg/kg) was administered to the rats orally and resulted in significant reduction of (31.70 %) the swelling of rat paw induced by carrageenin, 2) prednisolone (9mg/kg) showed significant reduction of (45.76%) the swelling, 3) concurrent administration of ibuprofen (20mg/kg) and prednisolone (9mg/kg) also reduced (57.40%) the swelling. In ibuprofen (125mg/kg) administration, the inhibition rate of edema was 39.32% and in prednisolone (1mg/kg) administration, the rate was 39.04%. In concurrent administration of ibuprofen (125mg/kg) and prednisolone (1mg/kg), the inhibition rate of edema was 63.09%. Concurrent administration of ibuprofen and prednisolone showed more anti-inflammatory effects than single administration of ibuprofen and prednisolone respectively. Prednisolone itself did not show antipyretic effect, but concurrent administration of ibuprofen and prednisolone showed more antipyretic effects than ibuprofen single administratron.

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pH-민감성 삼성분계 공중합체 젤의 합성 및 팽윤 속도론 (Synthesis and Swelling Kinetics of a Cross-Linked pH-Sensitive Ternary Copolymer Gel System)

  • Zafar, Zafar Iqbal;Malana, M.A.;Pervez, H.;Shad, M.A.;Momma, K.
    • 폴리머
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    • 제32권3호
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    • pp.219-229
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    • 2008
  • A pH sensitive ternary copolymer gel was synthesized in the presence of ethylene glycol dimethacrylate (EGDMA) as a crosslinking agent through radical polymerization of vinyl acetate (VA), acrylic acid (AA) and methyl acrylate(MA) with a weight ratio of 1 : 1.3 : 1. A number of experiments were carried out to determine the swelling behavior of the gel under a variety of pH conditions of the swelling medium. As the pH of the swelling medium was changed from 1.0 to 8.0 at $37^{\circ}C$, the gel showed a shift in the pH-dependent swelling behavior from Fickian (n=0.3447) to non-Fickian (n=0.9125). The resulting swelling parameters were analyzed using graphical and statistical methods. The results showed that the swelling of the gel was controlled by the pH of the medium, i.e. $n=n_o{\exp}(S_{C}pH)$, where n is the diffusion exponent, $n_o(=28.9645{\times}10^{-2})$ is the pre-exponential factor and $S_C$(=0.1417) is pH sensitivity coefficient. The swelling behavior of the gel was also examined in aliphatic alcohols. The results showed that the rate of swelling increased with increasing number of carbon atoms in the alcoholic molecular chain.

팽창성 혼화재를 병용한 에폭시수지 혼입 자기치유 모르타르의 건조수축 및 세공구조 (Drying Shrinkage and Pore Structure of Self-Healing Epoxy-Modified Mortars Using Expansive Admixtures)

  • 함성민;김완기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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    • pp.166-167
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    • 2015
  • The purpose of this study is to examine the effect on drying shrinkage of self-healing epoxy-modified mortars(EPMMs) using expansive admixtures. The EPMMs are prepared with polymer-binder ratios of 0 and 10%, and tested for drying shrinkage and pore structure analysis. As a result, regardless of the expansion and swelling agent content, the drying shrinkage of the EPMMs is remarkably decreased than that of unmodified mortars. Also, the pore size distribution of the EPMMs is moved to smaller size in comparison with unmodified mortars. In this study, the EPMM with expansive agent 7.5% and swelling agent 2.5% is recommended as a optimal mix proportion for reduction of drying shrinkage.

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시판중인 메트릭스 정제의 팽윤력 비교 연구 (Swelling of Commercial Matrix Tablets Based on Carboxymethyl Cellulose Sodium and Alginic Acid)

  • 김기택;김지수;박주환;이재영;조영우;양재권;장준희;최은선;김대덕
    • 약학회지
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    • 제60권2호
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    • pp.73-77
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    • 2016
  • Alginic acid and carboxymethyl cellulose sodium are dietary fibers from plants. They have a swelling property and delay the gastric emptying time, thereby resulting in feeling satiated after oral administration, which may eventually contribute to loss of body weight. The goal of this study was to compare swelling property of three commercial matrix tablets based on alginic acid and carboxymethyl cellulose sodium. When the swelling was determined by the Korean Ministry of Food and Drug Safety (MFDS) guideline, the tablet prepared by direct compression method with highly viscous swelling agent showed the highest swelling in acidic conditions. Water uptake of these tablets was rapid and completed within 30 min. Moreover, when the pH was changed from 2.5 to 6.8 buffer, the water uptake was not significantly changed in all tablets.

생물고분자로 이루어진 저독성 흡수제의 팽윤거동 (Swelling Behavior of Low Toxic Absorbent Based on Biopolymer)

  • 정진희;김진;이기영
    • 폴리머
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    • 제37권4호
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    • pp.478-485
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    • 2013
  • 본 연구에서는 식품첨가물로 승인되어 있는 생물고분자 물질을 이용하여 신속팽윤성과 고흡수성을 갖는 하이드로젤을 제조하고 팽윤특성을 분석하였다. 하이드로젤을 제조하는 과정에서 기포발생제를 이용하여 기공을 형성시켜 기존 하이드로젤의 팽윤성 향상을 시도하였고 각 하이드로젤의 평형 팽윤도, 팽윤속도 및 세포독성을 비교하였다. Alginate hydrogel에서는 digital microscope 관찰을 통해 수백 ${\mu}m$ 크기의 열린 채널로 다공성 구조를 관찰하였으며 제조된 모든 하이드로젤들은 poly(acrylic acid)에 비해 높은 세포생존율을 보였다.

위내체류를 목적으로 한 알부민 가교 PVP 하이드로겔의 팽윤특성 (Albumin-Crosslinked PVP Hydrogel as a Gastric Retention Platform)

  • 심창구;여소현
    • Journal of Pharmaceutical Investigation
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    • 제23권3호
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    • pp.145-153
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    • 1993
  • Retaining a drug in the stomach by some means is sometimes necessary to extend the G1 absorption time of the drug more than 6-8 hrs. Hydrogel has often been examined for its feasibility as a dosage form, so called platform, that could be retained in the stomach due to its excellent swelling properties in the gastric fluid. In this study, polyvinylpyrrolidone (PVP) hydrogel crosslinked by albumin or acrylated albumin was synthesized in a tablet form and evaluated for its possibility as the platform. The synthesis of the hydrogel was performed by $^{60}Co\;{\gamma}-ray$ irradiation of N-vinyl-2-pyrrolidone (monomer) in the presence of a crosslinking agent: aqueous solution of albumin or acrylated albumin. Synthetic conditions such as radiation dose, dose rate and concentration of crosslinking agent were varied in order to optimize the swelling and mechanical properties of the hydrogels. Degree of swelling of albumin-crosslinked PVP (Al-PVP) was highly dependent on radiation dose, dose rate and albumin concentration: it was decreased as they increased. On the other hand, that of acrylated albumin-crosslinked PVP (Acryl-PVP) was almost independent on them except dose rate: it was decreased as the radiation dose rate increased. The compressive strength of the two hydrogels was decreased as the dose rate increased. Digestion of both PVP in artificial gastric fluid containing pepsin was delayed by the ${\gamma}-ray$ irradiation. In conclusion, Al-PVP and Acry-PVP with diverse swelling and mechanical properties could be obtained by controlling synthetic conditions, mainly the irradiation dose rate.

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아라미드 소재의 침염 및 날염 (Dyeing and Printing on Aramid Materials)

  • 홍진표;김미경;윤석한;최우혁
    • 한국염색가공학회지
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    • 제23권4호
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    • pp.298-303
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    • 2011
  • Aramid fibers have been widely used as the reinforcement for composites due to their high modulus and strength. Nowadays the safety measures is required to improve the personal protection. The dyeing of aramid fibers is considered to be very difficult and their dyeing mechanism is not well illucidated. Therefore, this study is to establish the dyeing & printing technology for aramid fibers. The effects of swelling agent and neutral salt in the dye bath on the obtained colors were studied. Also dyeing method of aramid fibers depending on dyeing temperature and dye concentration were established. Color fastness of the dyed aramid fabric with cationic dyes were acceptable excluding light fastness.