• Title/Summary/Keyword: surface-modification technology

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Gas transport properties of alumina composite membranes

  • Lee, Hong-Joo;Hiroyuki Yamauchi;Hiroyuki Suda;Kenji Haraya
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.128-131
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    • 2004
  • The composite mesoporous ceramic membranes were prepared with ${\gamma}$-alumina and poly (2, 6-dimethyl-l, 4-pyphenylene oxide) (PPO) on the surface of the macroporous $\alpha$-alumina ceramic membranes and the permeation results were compared with those of the $\alpha$-alumina membrane for large-scale applications. In the results of the transport experiments, the ceramic membranes gave high gas permeances mainly due to Knudsen diffusion and surface diffusion as an additional mechanism. And, the polymer modification increased the permeances of the strongly adsorbing gas components. In this study the modifications of alumina ceramic membranes could increase the gas permeation performances especially for the strongly absorbing gas components.

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Sur face Modification of Ultra High Molecular Weight Polyethylene Films by UV/ozone Ir radiation

  • Yun, Deuk-Won;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.76-82
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    • 2011
  • Ultra High molecular weight polyethylene(UHMWPE) films were photooxidized by UV/ozone irradiation. Reflectance of the irradiated films decreased in the low wavelength regions of visible light, indicating destructive interference of visible light due to roughened surface. The UV treatment developed the nano-scale roughness on the UHMWPE films surface, which increased by two-fold from 82.6 to 156.6nm in terms of peak-valley roughness. The UV irradiation caused the oxygen content of the UHMWPE film surface to increase. Water contact angle decreased from $83.2^{\circ}$ to $72.9^{\circ}$ and surface energy increased from 37.8 to 42.6mJ/$m^2$ with increasing UV energy. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of UHMWPE films. The increased dyeability to cationic dyes may be due to the photochemically introduced anionic and dipolar dyeing sites on the film surfaces.

Formation of Cerium Conversion Coatings on AZ31 Magnesium Alloy

  • Fazal, Basit Raza;Moon, Sungmo
    • Journal of Surface Science and Engineering
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    • v.49 no.1
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    • pp.1-13
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    • 2016
  • This review deals with one of the surface modification techniques, chemical conversion coating and particularly cerium-based conversion coatings (CeCC) as a promising substitute for chromium and phosphate conversion coating on magnesium and its alloys. The CeCCs are commonly considered environmentally friendly. The effects of surface preparation, coating thickness, bath composition, and e-paint on the corrosion behavior of CeCCs have been studied on the AZ31 magnesium alloy. This review also correlates the coating microstructural, morphological, and chemical characteristics with the processing parameters and corrosion protection. Results showed that the as-deposited coating system consists of a three layer structure (1) a nanocrystalline MgO transition layer in contact with the Mg substrate, (2) a nanocrystalline CeCC layer, and (3) an outer amorphous CeCC layer. The nanocrystalline CeCC layer thickness is a function of immersion time and cerium salt used. The overall corrosion protection was crucially dependent on the presence of coating defects. The corrosion resistance of AZ31 magnesium alloy was better for thinner CeCCs, which can be explained by the presence of fewer and smaller cracks. On the other hand, maximum corrosion protection was achieved when AZ31 magnesium samples with thin CeCCs are e-painted. The e-paint layer further restricts and hinders the movement of chloride and other aggressive ions present in the environment from reaching the magnesium surface.

Effect of Electron Irradiation on the Titanium Aluminium Nitride Thick Films (Titanium Aluminium Nitride 후막의 전자-빔 조사 효과)

  • Choe, Su-Hyeon;Heo, Sung-Bo;Kong, Young-Min;Kim, Daeil
    • Journal of Surface Science and Engineering
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    • v.53 no.6
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    • pp.280-284
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    • 2020
  • Electron beam irradiation is widely used as a type of surface modification technology to advance surface properties. In this study, the effect of electron beam irradiation on properties, such as surface hardness, wear resistance, roughness, and critical load of Titanium Aluminium nitride (TiAlN) films was investigated. TiAlN films were deposited on the SKD-61 substrate by using cathode arc ion plating. After deposition, the films were bombarded with intense electron beam for 10 minutes. The surface hardness was increased up to 4520 HV at electron irradiation energy of 1500 eV. In addition, surface root mean square (RMS) roughness of the films irradiated at 1500 eV shows the lowest roughness of 484 nm in this study.

Development of The Magnetic -Electrolytic-Abrasive Polishing (MEAP) (1st) -Effect of magnetic field on electrolytic finishing process- (자기전해복합경면가공의 개발에 관한 연구(제 1보) -전해공정에 미치는 자기장의 영향-)

  • 김정두
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.4 no.3
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    • pp.25-30
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    • 1995
  • A new finishing process, magnetic-electrolytic-abrasive polishing(MEAP), combining Lorentz' force effect in the traditional electrolytic finishing process was developed to realize the high efficiency as well as high surface quality of finishing . The paper describes the theoretical basis about the modification of electrolytic ions motion by the magnetic field. The effect of magnetic field on the electrolytic process was discussed was and analyzed from the result of model test.

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Polyamine Group Assembled Silica Coated Ferrite Nanoparticle for Lambda DNA Detection

  • Park, Moo-Eon;Chang, Jeong-Ho
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1193-1194
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    • 2006
  • The magnetic ferrite nanoparticles were synthesized and coated by silica precursor in controlling the coating thicknesses and sizeses. The surface modification was performed with amino-functionalized organic silanes on silica coated magnetic nanoparticles. The use of functionalized self-assembled magnetic ferrite nanoparticles for nucleic acid separation process give a lot of advantages rather than the conventional silica based process.

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Studies on the Development of Rosin Sizing Effect by means of ESCA - Difference in the Fixing of Soap Type Rosin Sizing and Emulsion Type Rosin Sizing -

  • Yasushi Ozaki;Atsushi Sawatari
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.338-342
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    • 1999
  • It has been proven in previous work that rosin sizing agents are distributed relatively homogeneously on the outer surface of paper. Therefore, rosin sizing agents on paper surfaces can be characterized by macro domain measurement techniques with very thin layer from the surface. In this work, the role of rosin sizing agents on paper surface was investigated by comparing wettability from contact angle measurement with the chemical state of the outermost surface by the ESCA. Furthermore, the role of rosin on the surface of paper was discussed by the quantity of hydroxyl groups obtained from chemical modification with the TFAA-ESCA technique. It was found from the ESCA data that the fixing mechanism with soap-type rosin sizing is different from that with emulsion-type rosin sizing.

THE EFFECT OF MICRO/NANOSCALE STRUCTURES ON CHF ENHANCEMENT

  • Ahn, Ho-Seon;Kim, Moo-Hwan
    • Nuclear Engineering and Technology
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    • v.43 no.3
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    • pp.205-216
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    • 2011
  • Recently, many research studies have investigated the enormous critical heat flux (CHF) enhancement caused by nanofluids during pool boiling and flow boiling. One of the main reasons for this enhancement is nanoparticle deposition on the heated surface. However, in real applications, nanofluids create many problems when used as working fluids because of sedimentation and aggregation. Therefore, artificial surfaces on silicon and metal have been developed to create an effect similar to that of nanoparticle deposition. These modified surfaces have proved capable of greatly increasing the CHF during pool boiling, and good results have also been observed during flow boiling. In this study, we demonstrate that the wetting ability of a surface, i.e., wettability, and the liquid spreading ability (hydrophilic surface property), are key parameters for increasing the CHF during both pool and flow boiling. We also demonstrate that when the fuel surface in nuclear power plants is modified in a similar manner, it has the same effect, producing a large CHF enhancement.