• Title/Summary/Keyword: surface-coated aggregate

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Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate (CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착)

  • 김학성;정영도;한훈석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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Study on the Modification Effect of Lightweight Aggregate using Blast Furnace Slag (고로슬래그 미분말을 이용한 경량골재의 표면개질 효과에 관한 연구)

  • Kim, Ho-Jin;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.111-116
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    • 2022
  • Recently, building structures tend to be super high-rise and large-scale with the development of concrete technology. When high-rise building is constructed of reinforced concrete structure, it has a disadvantage that its own weight increases. Light weight aggregate(LWA) was developed to compensate for these shortcomings. Manufacturing concrete using these light weight aggregates has the advantage of reducing the self weight of the reinforced concrete structure, but has a disadvantage in that the strength of the concrete is reduced. In this study, an experimental study was conducted to investigate the strength characteristics of hardened cement according to the presence or absence of surface coating of lightweight aggregates. As a result, in terms of compressive strength, the surface-coated lightweight aggregate exhibited higher strength than the uncoated lightweight aggregate. Also, it was considered that this is because the interfacial voids of the surface coated lightweight aggregate mixed cement hardened body were filled with blast furnace slag fine powder particles.

Improvement of Low-quality Local Aggregates Using Coating Materials (코팅재료를 이용한 비쇄석골재의 성능향상)

  • Park Dae-Wook;Kim Min-Gu
    • International Journal of Highway Engineering
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    • v.8 no.3 s.29
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    • pp.39-48
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    • 2006
  • A laboratory investigation was conducted wherein smooth, rounded, siliceous river gravel aggregates were coated with fine-grained polyethylene, carpet co-product, or cement + styrene butadiene rubber latex and used to prepare hot mix asphalt concrete specimens. Only the coarse (+ No.4) aggregates were coated. The concept was that the coatings would enhance surface roughness of the aggregates and, thus, produce asphalt mixtures with superior engineering properties. Hot mix asphalt specimens were prepared and evaluated using several standard and non-standard test procedures. Based on experiences during the coating processes and analyses of these limited test results, the following was concluded: All three aggregate coating materials increased Hveem and Marshall stability, tensile strength, and resilient modulus(stiffness). These findings are indicative of improved resistance to rutting and cracking in hot mix asphalt pavements prepared using coated gravel aggregates in comparison to similar uncoated gravel aggregates.

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Fabrication of Carbon Nanofiber/Cu Composite Powder by Electroless Plating and Microstructural Evolution during Thermal Exposure (무전해 도금에 의한 탄소나노섬유/Cu 복합 분말 제조 및 열적 안정성)

  • Kim In-soo;Lee Sang-Kwan
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.39-42
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    • 2004
  • Carbon nanofiber/Cu composite powder has been fabricated by electroless plating process. Microstructural evolution of the composite powder after heat treatment under vacuum, hydrogen and air environment was investigated. A dispersed carbon nanofiber coated by copper was produced at the as-plated condition. Carbon nanofiber is coated uniformly and densely with the plate shaped copper particles. The copper plates on the carbon nanofiber aggregate during the thermal exposure at elevated temperature in vacuum and hydrogen in order to reduce surface energy. The thermal exposure of the composite powder in air at $400^{\circ}C$ for 3 hours leads to the spherodization of the composite powder owing to oxidation of copper.

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Effects of Mineral Trioxide Aggregate on the Proliferation and Differentiation of Human Dental Pulp Stromal Cells from Permanent and Deciduous Teeth (Mineral trioxide aggregate가 유치 및 영구치의 치수기질세포 증식 및 분화에 미치는 영향)

  • Kim, Seunghye;Jeon, Mijeong;Shin, Dong Min;Lee, Jae Ho;Song, Je Seon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.40 no.3
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    • pp.185-193
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    • 2013
  • Mineral trioxide aggregate (MTA) has recently been used as a pulpotomy medicament for primary molars. The aim of this study was to evaluate and compare the proliferation and differentiation potential of dental pulp stromal cells of permanent teeth and deciduous teeth cultured on MTA-coated surface. Human dental pulp stromal cells were obtained from human permanent premolars and deciduous teeth and cultured on MTA-coated culture plates. The cells were subjected to proliferation assay and cell cycle analysis. Their differentiation potential was evaluated by analysing changes in the mRNA expressions of runt-related transcriptional factor 2 (Runx2) and alkaline phosphatase (ALP). Morphological changes of cells in direct contact with MTA were observed using scanning electron microscopy (SEM). The proliferation rates, distribution of cell cycles and mRNA expression patterns of Runx2 and ALP were similar in both types of pulpal cells. SEM observations revealed that both types changed into more dendrite-like cells. On the surface of MTA, human dental pulp stromal cells from deciduous and permanent teeth were able to both proliferate and differentiate into cells that induce mineralization. MTA is suitable as a biocompatible pulpotomy medicament for primary teeth.

Effect of functional group on activity and stability of lipase immobilized on silica-coated magnetite nanoparticles with different functional group (실리카 코팅된 자성 나노입자로의 효소 고정화에 사용된 작용기가 리파아제의 활성과 안정성에 미치는 영향)

  • Lee, Hye Rin;Kim, Moon Il;Hong, Sang Eun;Choi, Jaeyeong;Kim, Young Min;Yoon, Kuk Ro;Lee, Seungho;Ha, Sung Ho
    • Analytical Science and Technology
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    • v.29 no.3
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    • pp.105-113
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    • 2016
  • The present study investigated the immobilization of lipases on silica nanoparticles and silica-coated magnetite nanoparticles as supports with a functional group to enhance the stability of lipase. The influence of functional groups, such as the epoxy group and the amine group, on the activity and stability of immobilized lipase was also studied. The epoxy group and the amino group were introduced onto the surface of nanoparticles by glycidyl methacrylate and aminopropyl triethoxysilane, respectively. Immobilized Candida rugosa lipase on silica nanoparticles and silica-coated magnetite nanoparticles with a functional group showed slightly lower initial enzyme activities than free enzyme; however, the immobilized Candida rugosa lipase retained over 92 % of the initial activity, even after 3 times reuse. Lipase was also immobilized on the silica-coated magnetite nanoparticles by cross-linked enzyme aggregate (CLEA) using glutaraldehyde and covalent binding, respectively, were also studied. Immobilized Candida rugosa lipase on silica nanoparticles and silica-coated magnetite nanoparticles by CLEA and covalent binding showed higher enzyme activities than free enzyme, while immobilized Candida rugosa lipase retained over 73 % of the initial activity after 5 times reuse.

An Experimental Study for Flexural Failure Behavior of Composite Beam with Cast-in-place High Strength Concrete and GFRP Plank Using As a Permanent Formwork and Tensile Reinforcement (유리섬유강화폴리머 판을 영구거푸집 및 인장 보강재로 활용한 현장타설 고강도콘크리트 합성보의 휨 파괴거동에 관한 실험적 연구)

  • Um, Chan Hee;Yoo, Seung Woon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.5
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    • pp.1015-1024
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    • 2015
  • An experiment of composite beam was performed which utilized glass fiber reinforced polymer (GFRP) plank as the permanent formwork with cast-in-place high strength concrete. This research analyzed the flexural failure behavior of composite beam by setting the sand coated at GFRP bottom surface, the perforation and interval of the GFRP plank web, and the width of the top flange as the experimental variables. As a result of the experiments for effectiveness of sand attachment in case of not perforated web, approximately 43% higher ultimate load value was obtained when the sand was coated than not coated case. For effectiveness of perforation and interval of gap, approximately 23% higher maximum load value was seen when interval of the perforation gap was 3 times and the fine aggregate was not coated, and approximately 11% higher value was observed when the perforation gap was 5 times on the coated specimen. For effectiveness of top flange breadth, the ultimate load value was approximately 12% higher in case of 20mm than 40mm width.

Compressive Strength Properties Surface Coating Lightweight Aggregate ITZ using Inorganic Materials (무기 재료를 이용한 표면코팅 경량골재 계면 압축강도 특성)

  • Kim, Ho-Jin;Jeong, Su-Mi;Pyeon, Myeong-Jang;Kim, Ju-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.109-110
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    • 2022
  • Recently, it tend to increase the high-rise and large-scale of buildings and the developtment of construction technology can to be applied reinforced concrete structures to high-rise buildings. However, when a high-rise buildings is constructed with reinforced concrete, it has a disadvantage that buildings weight increases. In order to resolve the weight of reinforced concrete structures, various types of lightweight aggregates become development and research. Although lightweight aggregates can be reduced the weight of concrete, the strength of ITZ(Interfacial Transition Zone) is lowered due to its less strength than natural aggregates. In this study, an experimental study was conducted to coat the surface of lightweight aggregates with GGBFS(ground granulated blast furnace slag) to improve the strength of cement matrix mixed with lightweight aggregates. Result of this experimental study shows that the compressive strnegth of the surface coating lightweight aggregates was higher than general lightweight aggregates. Also, it was considered that this is because the pore at the ITZ of the surface-coated lightweight aggregates mixed cement matrix are filled with GGBFS fine particle.

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The Dispersion Stability of Multi-Walled Carbon Nanotubes in the Presence of Poly(styrene/$\alpha-methyl$ styrene/acrylic acid) Random Terpolymer

  • Chang, Woo-Hyuck;Cheong, In-Woo;Shim, Sang-Eun;Choe, Soon-Ja
    • Macromolecular Research
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    • v.14 no.5
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    • pp.545-551
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    • 2006
  • Aqueous dispersions of pristine and functionalized (COOH- and $NH_2$-) multi-walled, carbon nanotubes (MWNTs) were prepared by using three types of surf act ants: sodium dodecyl sulfate (SDS, anionic), PEO-PPO-PEO (Pluronic P84, non-ionic), and poly(styrene/$\alpha-methyl$ styrene/acrylic acid) random terpolymer, i.e., alkali-soluble resin (ASR). The aggregate size, $\zeta-potential$, and storage stability of the MWNT aqueous dispersions were investigated by using dynamic light scattering and the turbidity method at room temperature. The exfoliation of the MWNT aggregates was determined by a UV-visible spectrophotometer and the morphology of the surfactant-coated MWNTs was observed by transmission electron microscopy (TEM). In all cases, ASR showed better dispersion stability with the smallest aggregate size, compared with the other surfactants, because of its unique molecular structure, i.e., randomly incorporated carboxylic acid groups and planar phenyl groups that can be irreversibly and effectively adsorbed on the MWNT surface. A predominantly-exfoliated morphology of MWNTs was observed in the presence of ASR from the strong intensity of the UV-vis spectrum at 263 nm.

Effect of Heat Treatment on the Morphology and Transparency of Thick Inorganic-Organic Hybrid Films Prepared by the Electrophoretic Sol-Gel Deposition of Polyphenylsilsesquioxane Particles

  • Hasegawa, Koichi;Katagiri, Kiyofumi;Matsuda, Astunori;Tatsumisago, Masahiro;Minami, Tsutomu
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.15-20
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    • 2000
  • Thick inorganic-organic hybrid films were prepared on ITO-coated glass substrates by the electrophoretic sol-gel deposition of polyphenylsilsesquioxane particles. The morphology of the deposited films changed from the aggregate of the spherical particles to monolith by heat treatment at temperatures higher than $200^{\circ}C$. Transparency of the films was significantly improved accompanied by the morphological change of the particles. The degree of the morphological change was governed by two factors; maximum heat treatment temperature and heating rate. Transparent thick films of ca. 3$\mu\textrm{m}$ in thickness were obtained only by heat treatment at $400^{\circ}C$ for 2h with rapid heating from room temperature to $400^{\circ}C$. These films obtained were strongly adhered to the ITO-coated glass substrates and has a very smooth surface.

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