• Journal of Surface Science and Engineering
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• v.50 no.6
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• pp.498-503
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• 2017

The aim of the present study is to evaluate electrochemical corrosion characteristics of base metal and weldment of Al-Mg alloy in seawater solution. The specimen was 5mm thick 5083-H321 Al alloy plate which was butt-welded using gas metal arc welding (GMAW). To identify the types of inclusions in the weldment, the microstructural observation was performed along with Energy dispersive spectrometer (EDS) analysis. The anodic polarization experiments were performed to evaluate the corrosion characteristics. After the anodic polarization test, the corroded surface was observed by SEM(scanning electron microscope) and EDS. The result of the analysis revealed a large number of voids in the weldment, especially coarse grains and inclusions in the heat affected zone. The corrosion current density of the weldment was found to be approximately 13 times higher than that of the base metal, indicating lower corrosion resistance of the weldment due to the defects in the weldment and the heat affected zone.

• Corrosion Science and Technology
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• v.19 no.6
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• pp.310-317
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• 2020

This study investigated the damage to the specimen due to liquid droplet impingement erosion corrosion, which improved the corrosion resistance and durability via hard anodization of 5083-H321 aluminum alloy, which is widely used for small ships and marine structures. The experiment combined liquid droplet impingement erosion and electrochemical equipment with the flow rates in natural seawater solution. Subsequently, Tafel extrapolation of polarization curves was performed to evaluate damage due to the liquid droplet impingement erosion corrosion. The damaged surface was observed using a 3D microscope and a scanning electron microscope. The degree of pitting damage was measured using the Image J program, and the surface hardness was measured using the micro-Vickers hardness tester. The corrosion current density, area, depth, and ratio of the damaged areas increased with the increase in flow rate. The grain size of the damaged area at a flow rate of 20 m s-1 showed fewer and minor differences in height, and a smooth curved shape. The hardness of the damaged surface tended to decrease with increase in flow rate.

• Ocean and Polar Research
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• v.25 no.4
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• pp.459-468
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• 2003

Annual variation of water qualities in the Shihwa Lake were observed 18 times from June 1996 to October 2001. We studied at the station of the upper streams and near the water gate of lake. After the flow of the outer seawater through the water gate, the surface salinity in Shihwa Lake increased to the range of 25-30 psu in both stations after October 1998. Due to the declination of the salinity differences between the surface and the bottom water, the pycnocline in which had existed until 1997 has weakened, and made the water column mix vertically. This led to the improvement of anoxic/hypoxic environment at bottom waters after April 1998. However, despite the continuous flow of the outer seawater, the concentrations of chlorophyll-a at surface layer were varied from $2{\mu}g/l\;to\;60{\mu}g/l$, and these values indicated the eutrophication. The following organic matter load was greatly influencing the surface layer's COD concentration. During the rainy season, the salinity at the surface layer to the below 15 psu resulting in stratification between the surface and bottom layer. Organic matters that were provided from the surface layer to the bottom layer due to active primary production in the year exhausted dissolved oxygen at the bottom layer, and the bulks of organic matters at bottom gave rise to hypoxic or anoxic environment. It was observed that the enrichment of ammonia and phosphate were main factors to worsen the water quality of the Shihwa Lake. The results of examining the annual variations in Shiwha Lake through principal component analysis shown that water characteristics in the rainy season were similar with those before input of outer sea water.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.43-46
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• 2009

The purpose of this study is to enhance durability of concrete structures that uses this surface protecting material by carrying out the performance test of the surface protecting material of concrete, and as s result, we reached out the conclusion as follow. 1. As a result of the test measuring the stability and adhesive power of conductive film against ultraviolet, freezing & thawing, and damage from seawater that deteriorate the surface protecting material, it was turned out to meet the performance criteria specifying in the KS standard enough to gain a good evaluation to use as a surface protecting material. 2. As a result of the test identifying the neutralization-furtherance, it was assessed to be capable of protecting effectively concrete structures from carbonic acid gas by a very low depth of 0.1mm of neutralization. 3. As a result of the test identifying Penetrated Resistance Properties of chloride ion, as it was turned out to have a very low value of 819 Coulombs, it was assessed that even in the environment where the corrosion by chloride such sea environment is very affective, the film can effectively protect the concrete structure. 4. As a result of the test identifying freezing & thawing, as there was no change in reduction of mass after 400 cycle, it was assessed that the film has a good resistance against freezing & thawing. According to the results of study above, it is expected that this technology can extend its durability of concrete structure and be widely used for concrete structure through means (methods) to prevent the neutralization and damage from seawater as original purposes of the surface protecting material.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.42 no.2
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• pp.171-178
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• 2009

The purpose of this study was the development of a digital water color measurement system using a CCD optical device. Photographs of the standard medium of Forel and Ule water color scales in the laboratory, and one of sea surface above a Secchi disc (Z=SD/2) immersed in seawater were taken. The colors of these pictures were estimated with the value of CIE $L^*a^*b^*$. Water color assessment was conducted with a digital photo-image. In the case of the Forel scale (No. 1-11), the $b^*$ value was so high that the water color number was large. In the Ule scale (No.11-21), the $a^*$ value became high, which is why the number on the water color scale was large. The color of these pictures showed that the $a^*$ value in the Forel scale and the $b^*$ value in the Ule scale increase with the increase of the F value. The $a^*$ value of seawater color was always lower than the one on the Forel and Ule water color scales. This indicates that the color of the scales differs from actual seawater color. It was concluded that water color number can more effectively be assessed by estimating the ${\Delta}Eab^*$ color difference between the water scales and actual seawater color.

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.28-36
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• 2012

This study carried out several kinds of investigations such as geology, hydrogeology, groundwater level and quality, surface-water quality, and the quantity and quality of groundwater discharge from the subway to identify the causes of groundwater contamination around the subway tunnel at Suyeong District in Busan City. Geostatistical analyses were also conducted to understand the characteristics of groundwater level and quality distributions. There are Kwanganri Beach and Suyeong River in the study area, which are basically influenced by seawater. The total quantities of groundwater utilization and groundwater discharge from the subway tunnel in Suyeong District are 2,282,000 $m^3$/year, which is 2.4 times larger than the sustainable development yield of groundwater. The lowest groundwater level around the subway tunnel is about 32 m below the mean sea-level. The large drawdown of groundwater led to the inflow of seawater and salinized river water toward the subway tunnel, and therefore the quality of groundwater didn't satisfy the criteria of potable, domestic, agricultural and industrial uses. Distribution maps of groundwater level and qualities produced by kriging were very useful for determining the causes of groundwater contamination in the study area. The distribution maps of electrical conductivity, chloride and sulfate showed the extent of seawater intrusion and the forceful infiltration of the salinized Suyeong River. This study revealed that seawater and salinized river water infiltrated into the inland groundwater and contaminated the groundwater around the subway tunnel, because the groundwater level was seriously drawdowned by groundwater discharge from the subway tunnel. The countermeasure for the minimization of groundwater discharge from the subway tunnel is necessary to prevent the groundwater obstacles such as groundwater depletion, groundwater-quality deterioration, and land subsidence.

• Journal of Power System Engineering
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• v.22 no.1
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• pp.34-40
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• 2018

In this paper, Performance of 1MW OTEC system using R32 with varying seawater temperature range is studied. Steady state cycle is designed and its output and generation efficiency were 1,014kW and 2.72%, respectively. Compared to dynamic cycle, system performance and change during long term operation is studied. The simulation is performed by decreasing surface seawater temperature from $29^{\circ}C$ to $25^{\circ}C$ with 20 minute of reaction time. Dynamic cycle with same condition applied to steady state cycle and it showed output and efficiency of 1,020kW and 2.75% respectively. Seawater temperature decreased from $29^{\circ}C$ and the vapor fraction of refrigerant decreased below 1 at $28^{\circ}C$. While the vapor fraction was above 1, the turbine output decreased by 0.017kW per second. After the seawater temperature reached $26.2^{\circ}C$, the turbine output decreased by 1.03kW per second. However, Driving the turbine below the saturation temperature caused the occurrence of surging and the influx of liquid refrigerant. When the liquid separator having a capacity of 1.0 m3 was used, the flow into the turbine was confirmed after 5 minutes from the first liquid refrigerant coming into the separator.

• Journal of the Korea Institute of Military Science and Technology
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• v.20 no.6
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• pp.767-773
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• 2017

Infrared stealth is an important technology for naval ships. This technology helps improve the anti-detection performance and survivability of naval ships. In general, the infrared signature of naval ships are categorized into internal and external heat source. External signature are generated by ship surface heating by solar flux as well as the complicated heat transfer process with the surrounding weather condition. Modern naval ships are equipped with seawater injection nozzles on the outside for nuclear, biological and, chemical, and these nozzles are used to control external signature. Wide nozzle placement intervals and insufficient injection pressure, however, have reduced seawater dispersion area. To address this problem, nozzle installation standards must be established. In this study, an actual-scale experimental system was implemented to provide the evidence for nozzle installation standards in order to reduce the infrared signature of naval ships. In addition, the environmental conditions of the experiment were set up through computational fluid dynamics considering the ocean climate data and naval ship management conditions of South Korea. The dispersion distance was measured using a high-resolution thermography system. The flow rate, pipe pressure, and dispersion distance were analyzed, and the evidence for the installation of seawater injection nozzles and operation performance standards was suggested.

• 한국해양학회지
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• v.30 no.4
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• pp.341-354
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• 1995

Fluorescence characteristic and amino acids composition of organic matter were determined from extracted seawater samples at eight stations in the East Sea of Korea. Organic compounds have been extracted onto C-18 Sep-Pak cartridges. Three dimensional excitation/emission fluorescence contouring of extracts showed two markedly distinct characterized fluoroscopies representing protein-like biomacromolecule and humic-like geomacromolecule. Protein-like biomacromolecule showing fluorescence maxima at 280 nm/330 nm (excitation/emission) were abundant in the surface mixed layer and then apparently decreased below the thermocline at most stations. It suggests that source of biomacromolecule is comely related with vigorous biological synthetic activity in the surface layer and bacteria decompose its biologically labile components near the thermocline and in the deeper layer. On the other hand, humiliate geomacromolecule showing fluorescence maxima at 330 nm/430 nm (excitation/emission) were low in the surface mixed layer implying photochemical oxidation and then increased below the thermocline at most stations. It suggests that geomacromolecule might be transformed by condensation of bio-refractoryorganic fraction after decomposition of biomacromolecule and particulate organic carbon derived from the surface mixed layer. HPLC measurements of amino acids showed similar composition between seawater and extracted organic macromolecule after hydrolysis. Glycine, serine and alanine were predominant, accounting for more than 50% of total amino acids. Dissolved free amino acids of seawater were more abundant in the surface layer(0.7∼1.8 uM) than the deeper layer (0.2∼0.4 uM). D/L racemic ratio of alanine of extracted organic matter showed lower value in the surface layer than the deeper layer. It suggests that biomacromolecule predominant in the surface layer is relatively young, rapidly recycling and biologically labile.

• Economic and Environmental Geology
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• v.41 no.4
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• pp.383-392
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• 2008

This study aims to evaluate the mechanical-chemical stability of used coal ash blocks, for improving fishing grounds. The surface of weathered ash blocks in seawater showed a decrease in the Ca and an increase in the Mg contents, compared to that of fresh blocks. This result reflects the substitution of Ca by Mg in seawater. The compressive strengths of ash blocks submerged into seawater during 12 months ranged from 235.23 to $447.43\;kgf/cm^2$; this is higher than the standard strength of wave-absorbing blocks($180\;kgf/cm^2)$ that are used for harbor construction. In addition, the compressive strength of ash blocks tends to increase with increasing installation time in seawater. The result of leaching experiments on coal ash blocks by Korean Standard Leaching Test(KSLT) method showed that leached concentrations of most metals except Cr(that leached up to 50 ppb, approaching standard concentration) do not exceed the seawater quality standards. A long-term(112 days) heavy metal leaching test to analyze seawater without mixing-dilution also showed that the concentrations of leached heavy metals, except for Cu, under anaerobic conditions do not exceed the seawater quality standards. Accordingly, the use of coal ash blocks in marine environments appears to be safe from chemical and mechanical factors that decrease the efficiency of concrete. Also, leaching concentration of Cu seems to be stable by decrease of leaching concentration due to dilution of seawater.