• Journal of Advanced Marine Engineering and Technology
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• v.29 no.8
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• pp.883-890
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• 2005

The industrial growth and the raised living quality have led to the massive energy consumption. As a result. the polluted environment and the limited amount of energy resources emerged as serious problems to be resolved in 21st century. Especially, in the case of Korea whose imported energy dependency rate is 98.2$\%$ in 2003 and constantly increasing every rear. more than 24$\%$ of overall energy consumption is for housing and commercial use. In order to cope with the shortage of natural energy resources, it is inevitable to develop alternative sustainable energy resources including seawater heat. so that they can replace existing resources. The heat transfer air velocity 3.5 m/s is proper to consideration with the body the pipe size 200A is more suitable than look due to the air velocity quantify and the ratio of pipe surface area. And the error between experimental data with simulation is below 5.34$\%$ so the suggested equation for calculating heat transfer capacity can be used. Therefore out of many methods utilizing seawater heat. this work Presents the efficiency of using sea water heat as a resource for air-conditioners which can be converted from the outside air through the air-to-heat conversion tube . Consequently. this method provides pretty reasonable energy efficiency.

• Journal of Surface Science and Engineering
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• v.47 no.1
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• pp.39-47
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• 2014

The peculiar feature of cathodic protection in seawater has the capability to form mineral calcareous deposits such as magnesium and calcium on metal surfaces. It is assumed that $OH^-$ ions are generated close to the metal surface as a result of cathodic protection and generated $OH^-$ ions increases the pH of the metal/seawater interface outlined as the following formulae. (1) $O_2+2H_2O+4e{\rightarrow}4OH^-$, or (2) $2H_2O+2e{\rightarrow}H_2+2OH^-$. And high pH causes precipitation of $Mg(OH)_2$ and $CaCO_3$ in accordance with the following formulae. (1) $Mg^{2+}+2OH^-{\rightarrow}Mg(OH)_2$, (2) $Ca^{2+}+CO{_3}^{2-}{\rightarrow}CaCO_3$. The focus of this study was to increase the amount of $CO{_3}^{2-}$ with the injection of $CO_2$ gas to the solution for accelerating process of the following formulae. (1) $H_2O+CO_2{\rightarrow}H_2CO_3$, (2) $HCO^{3-}{\rightarrow}{H^+}+CO{_3}^{2-}$. Electrodeposit films were formed by an electro-deposition technique on steel substrates in solutions of both natural seawater and natural seawater dissolved $CO_2$ gas with different current densities, over different time periods. The contents of films were investigated by scanning electron microscopy(SEM) and X-ray diffraction(XRD). The adhesion and corrosion resistance of the coating films were evaluated by anodic polarization. From an experimental result, only $CaCO_3$ were found in solution where injected $CO_2$ gas regardless of current density. In case of injecting the $CO_2$ gas, weight gain of electrodeposits films hugely increased and it had appropriate physical properties.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.19 no.1
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• pp.88-98
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• 2014

Despite of emerging and increasing concerns to microplastics, no standard methodology has not been proposed for determination of microplastics. This study aims to develop the analysis method for microplastics in seawater by overviewing methodologies proposed by previous studies and by assessing some processes in those methodologies which possibly cause uncertainties in microplastic determination. Furthermore, we present preliminary results of distribution characteristics of microplastics in seawater of Incheon/Kyeonggi coastal region which is based on our new methodology. Microplastics in surface microlayer (SML) and subsurface water (SSW) were collected using mesh screen and planktonic nets (trawl net with $330{\mu}m$ mesh size and hand net with $20{\mu}m$ mesh size), respectively. Microplastics with < $300{\mu}m$ was predominant, indicating hand net as the better collection tool for SSW. As for SML, FT-IR based microplastic concentration was well matched with naked-eye based concentration which has been used in most of previous studies. However, a poor relationship was observed for SSW, indicating that concentration data of previous SSW studies should be corrected. Incheon/Kyeonggi bay seawater contained the similar concentration range with those in coastal region of the Nakdong River. Our methodology can be used as a basic tool for further microplatic studies.

• Geophysics and Geophysical Exploration
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• v.10 no.4
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• pp.369-376
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• 2007

Electrical resistivity tomography was carried out at seawater intrusion monitoring wells located at watershed in coastal areas. It is difficult to identify the characteristics of resistivity near monitoring well in case of using high signalto-noise ratio array due to the high conductivity condition in coastal aquifer although electrical resistivity survey is well adopted to delineate hydrogeological characteristics with the distribution of electrical resistivity. To improve the quality of electrical resistivity survey for two sites with seawater intrusion monitoring wells, inversion with the results of holeto-surface electrical resistivity tomography using single well was executed. The results of inversion for aquifer near wells were verified with the results of drilling log with the informations of fracture, electrical conductivity logging and normal resistivity logging. The inversion for aquifer near one of two wells was also performed at low and high tide with the same electrodes, respectively. From the inversion result, it is possible to obtain the resistivity images with high resolution and to identify the characteristics of aquifer related to seawater intrusion with tidal fluctuation. From this study, it was demonstrated that the hole-to-surface electrical resistivity tomography method accompanied with drilling log, electrical conductivity logging and normal resistivity logging would be useful to delineate the hydrogeological structures near monitoring wells in coastal areas.

• Economic and Environmental Geology
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• v.55 no.6
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• pp.671-687
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• 2022

It has been reported that about 47% of groundwater wells within 10 km from the coastline in the western/southern coastal areas of Korea were affected by seawater. It has been interpreted that the cause of groundwater salinization is seawater intrusion. The Gilsan stream in the Seocheon area was a tidal stream until the Geumgang estuary dam was constructed and operated. Therefore, it is likely that the Gilsan stream catchment was deposited with sediments containing high-saline formation water prior to the use of landfill farmland at this catchment area. The groundwater in this study area showed EC values ranging from 111 to 21,000 µS/cm, and the water quality types were diverse including Ca(or Na)-HCO₃, Ca(or Na)-HCO₃(Cl), Na-Cl(HCO₃), Na-Cl types. It is believed that this diversity of water quality is due to the mixing of seawater and fresh groundwater generated by infiltration of precipitation and surface water through soil and weathered part. In this study, we discussed whether this water quality diversity and the presence of saline groundwater are due to present seawater intrusion or to remnant high-saline pore water in sediments during flushing out process. For this, rain water, surface water, seawater, and groundwater were compared regarding the water quality characteristics, tritium content, oxygen/hydrogen stable isotopic composition, and ⁸⁷Sr/⁸⁶Sr ratio. The oxygen/hydrogen stable isotopic compositions indicated that water composition of saline groundwaters with large EC values are composed of a mixture of those of fresh groundwater and surface water. Also, the young groundwater estimated by tritium content has generally higher NO₃ content. All these characteristics showed that fresh groundwater and surface water have continued to affect the high-saline groundwater quality in the study area. In addition, considering the deviation pattern in the diagrams of Na/Cl ratio versus Cl content and SAR (sodium adsorption ratio) versus Cl content, in which two end members of fresh surface-ground water and seawater are assumed, it is interpreted that the groundwater in the study area is not experiencing present seawater intrusion, but flush out and retreating from ancient saline formation water.

• Environmental Engineering Research
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• v.19 no.1
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• pp.15-22
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• 2014

In this study, the performances of various adsorbents-red mud, zeolite, limestone, and oyster shell-were investigated for the adsorption of multi-metal ions ($Cr^{3+}$, $Ni^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $As^{3+}$, $Cd^{2+}$, and $Pb^{2+}$) from aqueous solutions. The result of scanning electron microscopy analyses indicated that the some metal ions were adsorbed onto the surface of the media. Moreover, Fourier transform infrared spectroscopy analysis showed that the Si(Al)-O bond (red mud and zeolite) and C-O bond (limestone and oyster shell) might be involved in heavy metal adsorption. The changes in the pH of the aqueous solutions upon applying adsorbents were investigated and the adsorption kinetics of the metal ions on different adsorbents were simulated by pseudo-first-order and pseudo-second-order models. The sorption process was relatively fast and equilibrium was reached after about 60 min of contact (except for $As^{3+}$). From the maximum capacity of the adsorption kinetic model, the removal of $Pb^{2+}$ and $Cu^{2+}$ were higher than for the other metal ions. Meanwhile, the reaction rate constants ($k_{1,2}$) indicated the slowest sorption in $As^{3+}$. The adsorption mechanisms of heavy metal ions were not only surface adsorption and ion exchange, but also surface precipitation. Based on the metal ions' adsorption efficiencies, red mud was found to be the most efficient of all the tested adsorbents. In addition, impurities in seawater did not lead to a significant decrease in the adsorption performance. It is concluded that red mud is a more economic high-performance alternative than the other tested adsorption materials for applying a removal of multi-metal in seawater.

• ALGAE
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• v.35 no.2
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• pp.167-176
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• 2020

Iodine exists as a trace element in seawater, with total iodine being generally constant at about 0.45-0.55 μM. Almost all of this iodine occurs in two main forms: iodate and iodide. Iodate is the thermodynamically stable form under normal seawater conditions, and thus should be the only iodine-containing species in the water column. However, iodate concentrations are found to vary considerably, being generally greater at depth and lower at the surface, while iodide concentrations follow the reverse pattern, being anomalously accumulated in the euphotic zone and decreasing with depth. The fact that iodide concentrations follow a depth dependence corresponding to the euphotic zone suggests that biological activity is the source of the reduced iodine. Nonetheless, the nature and source of iodate reduction activity remains controversial. Here, using a combination of field and laboratory studies, we examine some of the questions raised in our and other previous studies, and seek further correlations between changes in iodine speciation and the presence of marine macro- and microalgae. The present results indicate that microalgal growth per se does not seem to be responsible for the reduction of iodate to iodide. However, there is some support for the hypothesis that iodate reduction can occur due to release of cellular reducing agents that accompany cell senescence during phytoplankton bloom declines. In addition, support is given to the concept that macroalgal species such as giant kelp (Macrocystis pyrifera) can take up both iodide and iodate from seawater (albeit on a slower time scale). We propose a mechanism whereby iodate is reduced to iodide at the cell surface by cell surface reductases and is taken up directly as such without reentering the bulk solution.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.149-149
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• 2017

Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the seawater upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification showed a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

• Corrosion Science and Technology
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• v.14 no.3
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• pp.140-146
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• 2015

The commercialization of aluminum had been delayed than other metals because of its high oxygen affinity. Anodizing is a process in which oxide film is formed on the surface of a valve metal in an electrolyte solution by anodic oxidation reaction. Aluminum has thin oxide film on surface but the oxide film is inhomogeneous having a thickness only in the range of several nanometers. Anodizing process increases the thickness of the oxide film significantly. In this study, porous type oxide film was produced on the surface of aluminum in sulfuric acid as a function of electrolyte temperature, and the optimum condition were determined for anodizing film to exhibit excellent cavitation resistance in seawater environment. The result revealed that the oxide film formed at $10^{\circ}C$ represented the highest cavitation resistance, while the oxide film formed at $15^{\circ}C$ showed the lowest resistance to cavitation in spite of its high hardness.

• Ocean and Polar Research
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• v.24 no.4
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• pp.399-406
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• 2002

Trace metals were investigated for the surface seawaters and mussels collected in adjacent sea to the Dokdo during 1999-2000. This study reports the temporal and spatial distributions of trace metals in seawaters and mussels of the Dokdo coastal areas. Clean technique for trace metal analyses was employed in all manipulations including the sampling and pretreatment procedures. The concentrations of dissolved Cu, Cd and Pb in the surface seawaters were similar to those of the previous data in the East Sea. Contents of particulate Al, Fe, Mn and Co were influenced by input of detrital materials from the Dokdo. The average EFs of particulate metals were to the order of Cd > Zn > Pb > Cu > Ni > Mn > Co > Fe, and the high values in Cd and Zn may be closely related to the preferential uptake of biogenic particles. With the exception of Cd, all metal contents in the mussels were in the same ranges with those from other world coastal areas. The Cd accumulation factor of mussel/seawater in this study was abnormally much higher than previous data from the Korean coasts.