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Rheological Properties of Citrus Pectin Solutions (감귤류 펙틴 용액의 리올리지 특성)

  • Hwang, Jae-Kwan
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.799-806
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    • 1995
  • The steady shear and small amplitude oscillatory dynamic rheological properties of citrus pectin $([\eta]=3.75\;dL/g)$ were characterized for a wide range of pectin concentrations $({\sim}6%)$. The typical power-law flow was observed above 2.0% concentration, and the shear rate dependence of viscosity increased with pectin concentration. The transition from dilute to concentrated regime, determined from the double logarithmic plot of ${\eta_{sp.o}}\;vs\;C[\eta]$, occurred at a critical coil overlap parameter $C^{*}[\eta]\approx4.0$, at which ${\eta_{sp.o}}$ corresponded to approximately 10.0. The slopes of ${\eta_{sp.o}}\;vs\;C[\eta]$, at $C[\eta]\;at\;C[\eta]C^{*}[\eta]$were 1.1 and 4.5, respectively. The steady viscosity $(\eta)$ displayed a good superposition at ${\eta}/{\eta}_o\;vs\;{\gamma}/{\gamma}_{0.8}$ relation with an exception of high concentration (6%), which arised from the significant deviation of flow behavior index (n values of $\eta_{a}=K\gamma^{n-1}$) at high concentration. Dynamic measurements showed that the loss modulus $(G^{\prime\prime})$ was much higher than the storage modulus $(G^\prime)$for all concentrations studied, indicating predominant viscoelastic liquid-like behavior of pectin solutions. The frequency dependence of $G^\prime$ was higher than that of $G^\prime\prime$ at the same concentration, whose trend was more pronounced with decreasing pectin concentration. The shear viscosity $(\eta)$ was almost identical to the complex viscosity $(\eta^{*})$ at low concentration, following the Cox-Merz rule, but they became increasingly different at high concentration.

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A Study on Embrittlement of Fast Neutron-irradiated Nuclear Reactor Pressure Vessel Steels at Room- and Liquid Nitrogen-temperature (상온 및 액체질소 온도에서 고속 중성자 조사된 원자로 압력 용기의 취화 현상에 관한 연구)

  • Kim, H.B.;Kim, H.S.;Kim, S.K.;Shin, D.H.;Yu, Y.B.;Ko, J.D.
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.142-147
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    • 2005
  • The embrittlement of fast neutron-irradiated reactor pressure vessel (RPV) steels was investigated by X-ray diffraction patterns at room temperature and $M\ddot{o}ssbauer$ spectroscopy at room- and liquid nitrogen-temperature. Neutron fluence on the samples were $10^{12},\;10^{13},\;10^{14},\;10^{15},\;10^{16},\;10^{17},\;10^{18}\;n/cm^2$. The X-ray diffraction patterns showed that the structure of the neutron unirradiated sample was bcc type, where as but the neutron irradiated samples with the fluence higher than $10^{17}\;n/{\cal}cm^2$ were so severely damaged, that bcc type structure disappeared. The $M\ddot{o}ssbauer$ spectra of all samples showed superposition of two or more sextets. In this paper all $M\ddot{o}ssbauer$ spectra were fitted by three set of sextet. The isomer shift and quadrupole splitting values were found around zero. At liquid nitrogen temperature, magnetic hyperfine field and absorption area increase rapidly S 1 sextet in the samples of $10^{17}\~10^{18}\;n/{\cal}cm^2$ neutron fluences. And at room temperature, magnetic hyperfine field and absorption increased rapidly at SI sextet in the samples of $10^{17}\~10^{18}\;n/{\cal}cm^2$ neutron fluences. This rapid increase of magnetic hyperfine field and absorption area were inferred to be caused by the change of $^{56}Fe,\;^{55}Mn$ into $^{57}Fe$ due to by neutron irradiation.

Study on the Levitation Stability of Maglev Vehicle considering the Vibration of Steel Switch Track (강재 분기기의 진동을 고려한 자기부상열차 부상안정성 연구)

  • Han, Jong-Boo;Park, Jinwoo;Han, Hyung-Suk;Lee, Jong-Min;Kim, Sung-Soo
    • Journal of the Korean Society for Railway
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    • v.18 no.3
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    • pp.175-185
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    • 2015
  • Generally, in the train area, switch tracks have required high reliability because this system is directly associated with derailment. Especially, switch tracks of Maglev vehicles must be moved in terms of the whole geometric characteristics, in which the bogies are encased in the switch track. For this reason, switch track was constructed with steel lighter than concrete girders. But, the steel switch track was weak because of structural vibration as well as structural deformation. Therefore, it is important to predict the levitation stability when a vehicle passes over flexible switch track. The aims of this paper are to develop a coupled dynamic model to describe the relationship between a Maglev vehicle and switch track and to predict the levitation stability. In order to develop the coupled dynamic model, a three dimensional vehicle model was developed based on multibody dynamics; a switch model was made using the modal superposition method. And, the developed model was verified using comparison measured data.

Theoretical Investigation for the Adsorption of Various Gases (COx, NOx, SOx) on the BN and AlN Sheets (N과 AlN 시트에 다양한 기체(COx, NOx, SOx)의 흡착에 관한 이론 연구)

  • Kim, Sung-Hyun;Kim, Baek-Jin;Shin, Chang-Ho;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.61 no.1
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    • pp.16-24
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    • 2017
  • The adsorption of various atmospheric harmful gases ($CO_x$, $NO_x$, $SO_x$) on graphene-like boron nitride(BN) and aluminum nitride(AlN) sheets was theoretically investigated using density functional theory (DFT) and MP2 methods. The structures were fully optimized at the $B3LYP/6-31G^{**}$ and $CAM-B3LYP/6-31G^{**}$ levels of theory and confirmed to be a local minimum by the calculation of the harmonic vibrational frequencies. The MP2 single-point binding energies were computed at the $CAM-B3LYP/6-31G^{**}$ optimized geometries. Also the zero-point vibrational energy (ZPVE) and 50%-basis set superposition error (BSSE) corrections were included. The adsorptions of gases on the BN sheet were predicted to be a physisorption process and the adsorptions of gases on the AlN sheet were predicted to be a physisorption process for $CO_x$ and $NO_x$ but to be a chemisorption process for $SO_x$.

Mossbauer Study Of $Co{1+x}Fe{2-2x}Ti_xO_4$ ferrite Powders (Mossbauer 분광법에 의한 $Co{1+x}Fe{2-2x}Ti_xO_4$ 페라이트 분말의 연구)

  • 채광표;정성근;김원기;이성호;이영배
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.220-224
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    • 2000
  • Ultra-fine $Co_{1+x}$F $e_{2-}$2x/ $Ti_{x}$ $O_4$ferrite powders have been prepared by the sol-gel method. The crystallographic and magnetic properties of the sample have been investigated by means of x-ray diffraction, Mossbauer spetroscopy and vibrating sample magnetometry. The formation of nano crystallized particles is confirmed. The x-ray diffractions of all samples with various compositions clearly indicate the presence of spinel structure. The Mossbauer spectra could be fitted as the superposition of two sextets due to F $e^{3+}$ A-site and B-site. The IS and QS values nearly constant with substituted Co-Ti contents, whereas $H_{hf}$ of B-site decreases with increasing Co-Ti substitution in $Co_{1+x}$F $e_{2-}$2x/ $Ti_{x}$ $O_4$. The magnetic behaviour of powders shows that the saturation magnetization and the coercivity decrease with increasing x in $Co_{1+x}$F $e_{2-}$2x/ $Ti_{x}$ $O_4$.$.X>.

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Mössbauer Study of Al0.2CoFe1.8O4 Ferrite Powders (Mössbauer 분광법에 의한 Al0.2CoFe1.8O4분말의 자기적 특성 연구)

  • Chae, Kwang-Pyo;Lee, Jae-Gwang;Kweon, Hyuck-Su;Lee, Young-Bae
    • Journal of the Korean Magnetics Society
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    • v.13 no.6
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    • pp.231-236
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    • 2003
  • The $Al_{0.2}$CoF $e_{1.8}$ $O_4$ferrite powders have been prepared by the sol-gel method. The crystallographic and magnetic properties of the sample depending on annealing temperature have been investigated by means of x-ray diffraction, FE SEM, Mossbauer spetroscopy and vibrating sample magnetometry. The x-ray diffractions of all samples annealing temperature above 873 K clearly indicate the presence of spinel structure, the lattice constant decrease from 8.425 $\AA$ at 873 K to 8.321 $\AA$ at 1073 K, whereas the particle size rapidly increase from about 39 nm at 673 K to about 108 nm at 1073 K. The Mossbauer spectra annealed above 873 K could be fitted as the superposition of two sextets due to F $e^{3+}$ at A-site and B-site. The isomer shift (IS) and quadruple splitting (QS) values nearly constant with annealing temperature, whereas magnetic hyperfine field ( $H_{hf}$) of A-site slowly in crease and that of B-site fastly increases with increasing annealing temperature. The magnetic behaviour of powders shows that the saturation magnetization increase from 0.7 emu/g at 473 K to 72.1 emu/g at 1073 K while the coercivity decrease from 0.951 kOe at 673 K to 0.374 kOe at 1073 K with increasing annealing temperature.

Nickel Substitution Effects on Nano-sized Co, Mn and MnZn Ferrites Synthesized by Sol-gel Method

  • Choi, Won-Ok;Kwon, Woo Hyun;Chae, Kwang Pyo;Lee, Young Bae
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.40-45
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    • 2016
  • Nickel substituted nano-sized ferrite powders, $Co_{1-x}Ni_xFe_2O_4$, $Mn_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ($0.0{\leq}x{\leq}0.2$), were fabricated using a sol-gel method, and their crystallographic and magnetic properties were subsequently compared. The lattice constants decreased as quantity of nickel substitution increased, while the particle size decreased in $Co_{1-x}Ni_xFe_2O_4$ ferrite but increased for the $Mn_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites. For the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.2$) ferrite powders, the $M{\ddot{o}}ssbauer$ spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. However, the $M{\ddot{o}}ssbauer$ spectrum of $Mn_{0.8}Zn_{0.1}Ni_{0.1}Fe_2O_4$ consisted of two Zeeman sextets and one single quadrupole doublet due to the ferrimagnetic and paramagnetic behavior. The area ratio of the $M{\ddot{o}}ssbauer$ spectra could be used to determine the cation distribution equation, and we also explain the variation in the $M{\ddot{o}}ssbauer$ parameters by using this cation distribution equation, the superexchange interaction and the particle size. The saturation magnetization decreased in the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites but increased in the $Mn_{1-x}Ni_xFe_2O_4$ ferrite with nickel substitution. The coercivity decreased in the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites but increased in the $Mn_{1-x}Ni_xFe_2O_4$ ferrite with nickel substitution. These variations could thus be explained by using the site distribution equations, particle sizes and spin magnetic moments of the substituted ions.

Dynamic Response of PSC I shape girder being used wide upper flange in Railway Bridge (확장된 상부플랜지 PSC I형 거더교의 동특성 및 동적안정성 분석)

  • Park, Jong-Kwon;Jang, Pan-Ki;Cha, Tae-Gweon;Kim, Chan-Woo;Jang, Il-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.4
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    • pp.125-135
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    • 2015
  • The tendency of more longer span length being required economical in railway bridges is studying about PSC I shaped girder. In this case, it is important to analyze and choose the effective girder section for stiffness of bridge. This study investigates the dynamic properties and safety of PSC I shaped girder being used wide upper flange whose selection based on radii and efficiency factor of flexure for railway bridge in different span type. In addition, 40m PSC Box girder bridge adopted in Honam high speed railway is further analyzed to compare dynamic performance of PSC I shaped girder railway bridge with same span length. Time history response is acquired based on the mode superposition method. Static analysis is also analyzed using standard train load combined with the impact factor. Consequently, the result met limit values in every case including vertical displacement, acceleration and distort.

Geometric Scheme Analysis and Region Segmentation for Industrial CR Images (산업용 CR영상의 기하학적 구도분석과 영역분할)

  • Hwang, Jung-Won;Hwang, Jae-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.46 no.4
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    • pp.124-131
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    • 2009
  • A reliable detection of regions in radiography is one of the most important task before the evaluation of defects on welded joints. The extracted features is to be classified into distinctive clusters for each segmented region. But conventional segmentation techniques give unsatisfactory results for this task due to the spatial superposition of intensity and low signal-to-ratio(SNR) in radiographic images. The usage of global or local processes not only provide the necessary noise resistance but also fail in classification of regions. In this paper, we presents an appropriate approach for segmentation of region-based indications in industrial Computed Radiography(CR) images. The geometric differences between welded and non-welded area which is generated on radiography as the representative regions(background, thickness, middle and welded region in steel tube image) have constructed the hierarchical structure. Although this structure is contaminated by noise, the scheme between regions can be selected by the help of local clustering based on distinctive geometric property of each region. Because of the geometric nature of the considered region and so that the region is selected layer by layer, and that the real class represents the boundary between regions, the vertical and horizontal clustering process in each layer must be judicious. In order to show the effectiveness of this approach, a comparative experiment of various segmentation method is performed on industrial steel tube CR images.

Prediction of Optimal Microwave-assisted Extraction Conditions Preserving Valuable Functional Properties of Fluid Cheonggukjang Obtained from Red Ginseng (홍삼 첨가 액상청국장의 기능성에 대한 마이크로웨이브 최적 추출조건 예측)

  • Lee, Bo-Mi;Do, Jeong-Ryong;Kim, Hyun-Ku
    • Food Science and Preservation
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    • v.14 no.5
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    • pp.474-480
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    • 2007
  • Response surface methodology (RSM) was employed to optimize extraction conditions preserving valuable functional properties of fluid Cheonggukjang obtained from red ginseng. Based on a central composite design, the study plan was established using variations in microwave power, ethanol concentration, and extraction time. Regression analysis was applied to obtain a mathematical model. A maximum electron donating ability (EDA) of 99.09% was obtained under the specific extraction conditions of microwave power 135.62 W, ratio of solvent to sample contents. 3.60 g/mL, and an extraction time of 11.79 min. The maximum inhibitory effect on tyrosinase activity was 10.02% at 119.16 W, 4.02 g/mL, and 5.57 min. The maximum superoxide dismutase (SOD)-like activity was 63.83% under the extraction conditions of 125.29 W, 4.04 g/mL, and 11.02 min. Based on superposition of four-dimensional RSM data obtained to optimize electron donating ability, nitrite-scavenging ability, inhibitory effect on tyrosinase activity, and SOD-like activity, the optimum ranges of extraction conditions were found to be a microwave power of $l{\sim}85 W$, a ratio of solvent to sample content of $1.4{\sim}2.8\;g/mL$, and an extraction time of $6.5{\sim}11\;min$.