• Title/Summary/Keyword: sum-frequency generation

Search Result 29, Processing Time 0.02 seconds

New Research Tool for Understanding of Surfaces - Sum Frequency Generation Vibrational Spectroscopy (표면의 이해를 위한 새로운 연구 방법 - 합 진동수 발생 진동 분광법)

  • Kim, Hak-Jin
    • Journal of the Korean Chemical Society
    • /
    • v.50 no.6
    • /
    • pp.429-439
    • /
    • 2006
  • vibrational spectrum of molecules on surfaces can be measured with high selectivity and sensitivity using sum frequency generation vibrational spectroscopy (SFG-VS). Selectivity and sensitivity of this non-linear spectroscopy have made it an effective experimental tool in surface research. Surface systems studied with SFG_VS are surveyed, and experimental and theoretical background of SFG-VS is briefly reviewed.

Two-Dimensional Correlation Analysis of Sum-Frequency Vibrational Spectra of Langmuir Monolayers

  • Lee, Jonggwan;Sung, Woongmo;Kim, Doseok
    • Journal of the Optical Society of Korea
    • /
    • v.18 no.5
    • /
    • pp.558-563
    • /
    • 2014
  • Sum-frequency generation spectra of a Langmuir monolayer on water surface at varying surface areas were studied with two-dimensional correlation analysis. Upon enlarging the area/molecule of the Langmuir monolayer, the sum-frequency spectra changed reflecting the conformation change of the alkyl chains of the molecules in the monolayer. These changes stood out more clearly by employing two-dimensional correlation analysis of the above sum-frequency spectra. Features not very pronounced in the original spectra such as closely-spaced spectral bands can also be easily distinguished in the two-dimensional correlation spectra.

A Study on the Estimation Technique of Frequency in the Power System using FIR Filter (FIR 필터를 이용한 전력계통 주파수 추정기법에 관한 연구)

  • Nam, S.B.;Lee, H.G.;Park, C.W.;Shin, M.C.
    • Proceedings of the KIEE Conference
    • /
    • 2001.07e
    • /
    • pp.80-85
    • /
    • 2001
  • Frequency is an important operating parameter of a power system. Frequency of a power system remains constant if sum of all the loads plus losses equals total generation in the system. However, the frequency starts to decrease if total generation is less than the sum of loads and tosses. On the other hand, the system frequency increases if total generation exceeds the sum of loads and losses. Electric power systems sustain transient frequency swings whenever the balance between generation and load does not no longer hold. To cope with this Constraints, it requires an accurate and high speedy frequency deviation estimation technique and suitable adjustment to obtain the power system energy balance. The fundamental frequency component of 3-phase signal is first extracted by using an algorithm based on FIR(finite duration impulse response) filter, a phase angle of a voltage. The rate change of the phase angle is used for estimation and speed in its process. Also, to confirm the validity of the proposed algorithm, the simulation results obtained by using EMTP(electro magnetic transients program) are shown.

  • PDF

Polymer surfaces studied by sum-frequency vibrational spectroscopy

  • Kim, D.;J. Sung;H. M. Cheong;C. N. Whang;Y. Ouchi;T. limori;N. Matsuie;K. Seki
    • Journal of the Korean Vacuum Society
    • /
    • v.12 no.S1
    • /
    • pp.70-73
    • /
    • 2003
  • Sum-frequency vibrational spectroscopy has recently been used to investigate the surface of the various polymers and was able to find the chemical compositions and structures specific to the surface. Here we report our studies on two specific polymer samples to demonstrate its capability. Polyimide thin films were made by spin coating on fused quartz and $CaF_2$ substrates. The sum-frequency signal originating mainly from the air/polymer interface showed markedly different spectra, indicating the structural change of the polymer surface depending on the underlying substrate. Various polyethylene surfaces were also investigated by sum-frequency vibrational spectroscopy. The surface of polyethylene samples in the CH-region showed different sum-frequency spectra, presumably due to the trace amount of additives having much higher concentration at the air/polymer interface. These examples demonstrate the surface and interface of the polymer could have different structure and chemical composition from those of a bulk, which can be studied effectively by surface nonlinear optical spectroscopy.

Sum-frequency Generation Using a Mode-locked Pulsed Laser and a Continuous-wave Diode Laser (모드 잠금된 펄스 레이저와 연속 발진하는 반도체 레이저를 이용한 합주파수 생성)

  • Kim, Hyunhak;Park, Nam Hun;Yeom, Dong-Il;Cha, Myoungsik;Moon, Han Seb
    • Korean Journal of Optics and Photonics
    • /
    • v.32 no.2
    • /
    • pp.62-67
    • /
    • 2021
  • We have experimentally demonstrated sum-frequency generation (SFG) in a periodically poled lithium niobate (PPLN) crystal, using a mode-locked picosecond-pulsed fiber laser and a continuous-wave (CW) diode laser with a narrow linewidth. The mode-locked fiber laser had a center wavelength of 1560.7 nm and a spectral width of 1.1 nm, and the CW diode laser had a center wavelength of 1551.0 nm and a spectral width of 6 MHz. To effectively realize SFG, both of the spatial modes of the two lasers were made to overlap in the PPLN crystal by using a single-mode optical fiber. The pulse-mode SFG with pulsed- and CW-mode lasers was successfully observed in the spectral and time domains. These results are expected to be applicable in various ways, such as optical frequency measurement and high-resolution laser spectroscopy studies using optical frequency combs.

Tunable All-Optical Wavelength Conversion in a Ti:PPLN Channel Waveguide Using Cascaded Sum and Difference Frequency Generation (티타늄 확산 주기적 분극반전 채널 광도파로에서 연속적으로 일어나는 합주파수/차주파수 생성을 이용한 가변 파장 변환기)

  • Lee Ji Hyeon;Sin Sang Yeong;Lee Yeong Rak;Min Yu Hong;Werner Grundkoetter;Victor Goring;Wolfgang Sohelr
    • Proceedings of the Optical Society of Korea Conference
    • /
    • 2003.02a
    • /
    • pp.156-157
    • /
    • 2003
  • The wavelength converter is considered to be a key element of future dense WDM optical networks. It enables wavelength reuse and resolves contention problem. Moreover, the tunability of the wavelength converter enhance the flexibility of network systems by facilitating reconfigurable dynamic wavelength routing. In order to achieve optically tunable wavelength conversion, we recently proposed and experimentally demonstrated wavelength conversion and tuning based on cascaded sum and difference frequency generation in a Ti:PPLN channel waveguide. (omitted)

  • PDF

Blue Laser Generated by Sum Frequency (합주파에 의한 청색레이저 발생)

  • Lee Young-Woo
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.10 no.2
    • /
    • pp.224-227
    • /
    • 2006
  • We have chained 459nm blue laser radiation generated by intracavity sum frequency generation( SFG ) due to the mixing of the 1064 nm laser output of a Nd:YVO4 pumped by diode and the 809nm radiation from higg-power semiconductor laser(500mW). The maximum blue output power of 0.95 mW was obtained using 400 mW input power of semiconductor laser at the type II phase matching condition (${\psi}=90^{\circ}\;{\theta}=90^{\circ}$). The threshold input power of blue laser generation was 120 mW.

Different Adsorption Behavior of Rare Earth and Metallic Ion Complexes on Langmuir Monolayers Probed by Sum-Frequency Generation Spectroscopy

  • Sung, Woongmo;Vaknin, David;Kim, Doseok
    • Journal of the Optical Society of Korea
    • /
    • v.17 no.1
    • /
    • pp.10-15
    • /
    • 2013
  • Adsorption behavior of counterions under a Langmuir monolayer was investigated by sum-frequency generation (SFG) spectroscopy. By comparing SFG spectra of arachidic acid (AA) Langmuir monolayer/water interface with and without added salt, it was found that the simple trivalent cation $La^{3+}$ adsorbed on AA monolayer only when the carboxylic headgroups are charged (deprotonated), implying that counterion adsorption is induced by Coulomb interaction. On the other hand, metal hydroxide complex $Fe(OH)_3$ adsorbed even on a charge-neutral AA monolayer, indicating that the adsorption of iron hydroxide is due to chemical interaction such as covalent or hydrogen bonding to the headgroup of the molecules at the monolayer.

Composite Differential Evolution Aided Channel Allocation in OFDMA Systems with Proportional Rate Constraints

  • Sharma, Nitin;Anpalagan, Alagan
    • Journal of Communications and Networks
    • /
    • v.16 no.5
    • /
    • pp.523-533
    • /
    • 2014
  • Orthogonal frequency division multiple access (OFDMA) is a promising technique, which can provide high downlink capacity for the future wireless systems. The total capacity of OFDMA can be maximized by adaptively assigning subchannels to the user with the best gain for that subchannel, with power subsequently distributed by water-filling. In this paper, we propose the use of composite differential evolution (CoDE) algorithm to allocate the subchannels. The CoDE algorithm is population-based where a set of potential solutions evolves to approach a near-optimal solution for the problem under study. CoDE uses three trial vector generation strategies and three control parameter settings. It randomly combines them to generate trial vectors. In CoDE, three trial vectors are generated for each target vector unlike other differential evolution (DE) techniques where only a single trial vector is generated. Then the best one enters the next generation if it is better than its target vector. It is shown that the proposed method obtains higher sum capacities as compared to that obtained by previous works, with comparable computational complexity.

Linewidth Reduction of a Yellow Laser by a Super-cavity and the Measurement of the Cavity Finesse (초공진기를 이용한 노란색 레이저의 선폭 축소 및 초공진기의 예리도 측정)

  • Lee, Won-Kyu;Park, Chang-Yong;Park, Sang-Eon;Ryu, Han-Young;Yu, Dai-Hyuk;Mun, Jong-Chul;Suh, Ho-Suhng
    • Korean Journal of Optics and Photonics
    • /
    • v.21 no.3
    • /
    • pp.123-128
    • /
    • 2010
  • Sum frequency generation was utilized to obtain a yellow laser with the wavelength of 578.4 nm for a probe laser of an Yb lattice clock. The output of an Nd:YAG laser with wavelength of 1319 nm and that of an Yb-fiber laser with wavelength of 1030 nm were passed through a waveguided periodically-poled lithium niobate (WG-PPLN) for sum frequency generation. It is required that the probe laser has a linewidth of the order of 1 Hz to fully resolve the Yb lattice clock transition. Thus, the linewidth of the probe laser was reduced by stabilizing the frequency to a super-cavity. This was made of ULE with a low thermal expansion coefficient, and was mounted on an active vibration-isolation table at the optimal point for the reduced sensitivity to vibration. Also, this was installed in a vacuum chamber, and the temperature was stabilized to 1 mK level. This system was installed in an acoustic enclosure to block acoustic noise. The finesse of the super-cavity was measured to be 380 000 from the photon life time of the cavity.