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http://dx.doi.org/10.3807/JOSK.2013.17.1.010

Different Adsorption Behavior of Rare Earth and Metallic Ion Complexes on Langmuir Monolayers Probed by Sum-Frequency Generation Spectroscopy  

Sung, Woongmo (Department of Physics, Sogang University)
Vaknin, David (Ames Laboratory and Department of Physics, Iowa State University)
Kim, Doseok (Department of Physics, Sogang University)
Publication Information
Journal of the Optical Society of Korea / v.17, no.1, 2013 , pp. 10-15 More about this Journal
Abstract
Adsorption behavior of counterions under a Langmuir monolayer was investigated by sum-frequency generation (SFG) spectroscopy. By comparing SFG spectra of arachidic acid (AA) Langmuir monolayer/water interface with and without added salt, it was found that the simple trivalent cation $La^{3+}$ adsorbed on AA monolayer only when the carboxylic headgroups are charged (deprotonated), implying that counterion adsorption is induced by Coulomb interaction. On the other hand, metal hydroxide complex $Fe(OH)_3$ adsorbed even on a charge-neutral AA monolayer, indicating that the adsorption of iron hydroxide is due to chemical interaction such as covalent or hydrogen bonding to the headgroup of the molecules at the monolayer.
Keywords
Langmuir monolayer; Interfacial structure; Nonlinear optical spectroscopy;
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