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Destruction of 2-Chloriphenol from Wastewater and Investigation of By-products by Ozonation

  • Jeong, O Jin
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.850-856
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    • 2001
  • This study investigates the ozonation kinetics of 2-chlorophenol in wastewater under acidic condition. Intermediates and by-products generated during the process were rigorously identified and quantified. The major by-products are four carboxylic acids: tartaric acid, oxalic acid, maleic acid, and hydroxymalonic acid. The generation of these organic acids is in agreement with theoretical predictions. But hydroxylated compounds are more favorable to produce than their corresponding non-hydroxylated ones. Based on the information concerning the generation of organic acids and other aromatic intermediates, the complete reaction pathways toward mineralization can be proposed and mathematically modeled. The fitted second-order rate constants are in the same order of magnitude with the results from other studies. Using these oxidation pathways and the corresponding kinetic model, by-products generated in ozonation process can be predicted. This can help in optimizing the design and operation of any subsequent treatment processes.

Black Phosphorus Nano Flake Lithium Ion Battery Using Electrophoretic Deposition (전기영동 증착법을 이용한 Black Phosphorus Nano Flake 리튬이온 배터리)

  • Kim, Juyun;Park, Byoungnam
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.3
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    • pp.252-255
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    • 2019
  • Black phosphorus (BP) is a potential candidate for an anode in lithium ion batteries due to its high theoretical capacity and the large interlayer spacing in the monolayered phosphorene form, allowing for lithium intercalation/deintercalation. In this study, large-scale exfoliation of bulk BP was accomplished using a solution of NaOH and N-methyl-2-pyrrolidone (NMP), yielding phosphorene, which can be assembled into nanoflakes using electrophoretic deposition (EPD). Through the systematic addition of NaOH and subsequent sonication, BP nanoflakes were obtained in high yields by EPD, allowing for the integration of these nanoflakes into an anode in the film state. Anodes with a charge/discharge capacity of 172 mAh/g at a rate of 200 mA/g were obtained, which are promising for battery applications through various post-film treatments.

Mn$2^+$ dependent ClpL ATPase in Streptococcus pneumoniae

  • Park, Moo-Hyun;Kwon, Hyog-Young;Jung, Seung-Ha;Pyo, Suhk-Neung;Rhee, Dong-Kwon
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.336.1-336.1
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    • 2002
  • HSP100/Clp family functions as molecular chaperone and ATP dependent protease. The Streptococcus pneumoniae ClpL. a homologue of bacterial ClpB and yeast cytosolic HSP 104. is one of major heat shock proteins but its biochemical properties are unknown. In this study. ClpL in Streptococcus pneumoniaewas characterized using histidine tagged recombinant ClpL. When ATP hydrolysis activity was compared in the presence or absence of a variety of nucleotides or divalent ions. either ATP or Mn$2^+$ ion was found to increase significantly the rate of ATP hydrolysis. Furthermore. glutaraldehyde cross-linking and subsequent native-PAGE analfysis showed that ClpL forms dimer. but in the presence of 4 mM concentration of $Mn^{2+}$ion as a cofactor for ATP hydrolysis and oligormerization in vitro.

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Corona-Cov-2 (COVID-19) and ginseng: Comparison of possible use in COVID-19 and influenza

  • Lee, Won Sik;Rhee, Dong-Kwon
    • Journal of Ginseng Research
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    • v.45 no.4
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    • pp.535-537
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    • 2021
  • In the 1918 influenza pandemic, more than 95% of mortalities were ascribed to bacterial pneumonia. After the primary influenza infection, the innate immune system is attenuated, and the susceptibility to bacteria is increased. Subsequent bacterial pneumonia exacerbates morbidity and increases the mortality rate. Similarly, COVID-19 infection attenuates innate immunity and results in pneumonia. In addition, the current pneumococcal conjugate vaccine may have limited defense against secondary pneumococcal infection after influenza infection. Therefore, until a fully protective vaccine is available, a method of increasing immunity may be helpful. Ginseng has been shown to increase the defense against influenza in clinical trials and animal experiments, as well as the defense against pneumococcal pneumonia in animal experiments. Based on these findings, ginseng is suspected to be helpful for providing immunity against COVID-19.

Information Aspects of Changes in the Labor Market of the EU and Ukraine in the Context of Ensuring Safety Through COVID-19

  • Andriyiv, Nataliya;Zachepa, Andryi;Petrukha, Nina;Shevchuk, Inna;Berest, Ihor
    • International Journal of Computer Science & Network Security
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    • v.21 no.12spc
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    • pp.657-663
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    • 2021
  • The main purpose of the study is to analyze the information aspects of the impact of COVID-19 on the labor market in the EU and Ukraine. In addition to studying the key parameters of changes in the labor market under the influence of COVID-19, i.e. the unemployment rate and the share of the employed population, a thorough study of gender equality, labor migration and the impact on youth made it possible to characterize the effectiveness of the policy of stabilization and restoration of the labor market in the EU and Ukraine. The results obtained form the necessary information basis for modeling labor market regulation in the event of possible subsequent disturbances, in particular under the influence of global pandemics.

소수력 발전에 대하여

    • Journal of the Korean Professional Engineers Association
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    • v.15 no.1
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    • pp.32-35
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    • 1982
  • The sudden shock of repeated oil crisis and the subsequent violent increases in petroleum prices have given rise to an intensive worldwide effort to develop alternate sources of clean energy. Against this background, a great deal of attention has recently come to be focused on mini-scale hydroelectric power turbine generation. There is now a strong demand for the development of a hydroelectric generator suitable for generating power on a small scale and copable of overcoming the high per kilowatt cost of conventional one's then Francis turbine. Hence was accordingly developed the "Cross flowturbine generator" of 1000kw and less, which we call. This mimi-scale water turbine is reliably and easily handled and also can be economicaly manufactored in a range with effective head of over 3meter's a flow rate of minimum 30 liter per sec and an output of below 1000kw good's.kw good's.

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A Preliminary Assessment on ERVC Performance Depending on Insulation Conditions (단열재 조건에 따른 원자로용기 외벽냉각 성능 예비분석)

  • Dong-Hyeon Choi;Yoon-Suk Chang
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.1
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    • pp.36-43
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    • 2023
  • Lots of researches have been conducted on in-vessel retention (IVR) to prevent or mitigate severe accident in nuclear power plants. Various methodologies were proposed and the external reactor vessel cooling was selected as a part of promising IVR strategy. In this study, the strategy is strengthened by enhancing the natural circulation performance through the adoption of insulation in the reactor cavity. A thermal analysis was carried out based on an assumed accident scenario and its results were used as boundary conditions for subsequent seven flow analysis cases. By comparing the natural circulation performance, effects of annular gaps and insulation shapes on the mass flow rate and flow velocity were quantified. The improvement in cooling performance can be reflected in actual design via detailed assessment.

Severe Diarrhea-induced Acute Kidney Injury and Its Consequence in an Elderly

  • Chang-Gue Son
    • The Journal of Korean Medicine
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    • v.44 no.4
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    • pp.163-169
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    • 2023
  • Methods: This study presents a comprehensive case study of an elderly male diagnosed with acute kidney injury (AKI) resulting from severe dehydration, supported by an extended follow-up with laboratory findings. Results: An 83-year-old male patient experienced severe diarrhea overnight, leading to hospitalization due to symptoms of dehydration and hypotension. His laboratory results displayed a typical AKI pattern, including a significant increase in creatinine levels (5.19 mg/dL) and the presence of hyperkalemia and hyponatremia. Following general treatments, including the administration of an herbal drug (Bulhwangeumjeonggi-san), the estimated glomerular filtration rate (eGFR) improved from 10 ml/min (Stage 5) to 34 ml/min (Stage 3) within five days when he was discharged. Although subsequent eGFR tests, conducted one and two months later as an outpatient, revealed an improvement of 42 ml/min, the patient still experienced mild chronic dysfunction as a consequence. Conclusion: This study presents a noteworthy case of acute kidney injury attributed to severe dehydration, emphasizing the importance of medical awareness regarding diarrhea-induced kidney function impairment, especially in the elderly population.

THE USE OF DISTRACTION OSTEOGENESIS TO TREAT HEMIFACIAL MICROSOMIA: A CASE REPORT (반안면 왜소증 환자에서의 골신장술: 증례보고)

  • Baik, Sung-Mun;Kim, Su-Gwan;Kim, Hak-Kyun;Moon, Seong-Yong
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.33 no.5
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    • pp.559-566
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    • 2007
  • Distraction osteogenesis(DO) is a surgical method of bone formation that involves an osteotomy and sequential stretching of the healing callus by gradual movement and subsequent remodeling. DO is used to correct facial asymmetry, such as in patients with hemifacial microsomia, maxillary or mandibular retrusion, cleft lip and palate, alveolar defects, and craniofacial deficiency. It is accomplished with the aid of a distraction device, which is secured with screws placed directly into bone, for a predetermined length of time. Hemifacial microsomia is characterized by unilateral facial hypoplasia, often with unilateral shortening of the mandible and subsequent malocclusion. Patients with hemifacial microsomia and facial asymmetry have a vertically short maxilla, tilted occlusal plane, and short mandible. Early treatment is necessary to avoid subsequent impaired midfacial growth. The standard treatment of these malformations consists of the application of bone grafts, which can lead to unpredictable growth. The new bone-lengthening procedure represents a limited surgical intervention and opens up a new perspective for treatment, especially in younger children with severe deformities. This report describes a case of hemifacial microsomia(Type-II left-sided hemifacial microsomia). The patient, a 10-year-old child, visited our clinic for facial asymmetry correction. He had a hypoplastic mandible, displaced ear lobe, 10 mm canting on the right side, and malocclusion. We planned DO to lengthen the left mandible in conjunction with a Le Fort I osteotomy for decanting and then perform a right intraoral vertical ramus osteotomy(IVRO). Progressive distraction at a rate of 0.5 mm/12 hours was initiated 7 days postoperatively. The duration of DO was 17 days. The consolidation period was 3 months. Satisfactory results were obtained in our case, indicating that DO can be used successfully for functional, aesthetic reconstruction of the mandible. We report a case involving DO in conjunction with orthognathic surgery for correcting mandibular hypoplasia with a review of the literature.

Residual Effects of Coal Fly Ashes on the Growth of Rice Crop Subsequent to Malting Barley (맥주보리 후작(後作) 벼의 생육(生育)에 대한 석탄회(石炭灰) 시용잔효(施用殘效))

  • Ha, Ho-Sung;Kang, Ui-Gum
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.373-379
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    • 1998
  • Fly ash application with a rate 0, 50, 100, $150Mg\;ha^{-1}$ in clay loam paddy, which had properties of pH 5.3 and low contents of silicate, gave a positively residual effects on the growth of rice crop subsequent to malting barley. The responses of rice yields to fly ash application were in the order of bituminous coal fly ash(BCFA) 100 > 150 > 50 > anthracite fly ash(AFA) 50 > 100 > none > AFA $150Mg\;ha^{-1}$. As a result, yields responses of milled rice were ranged from $6.2(50Mg\;ha^{-1}){\sim}14.4%(100Mg\;ha^{-1})$ by BCFA and from $-0.6(150Mg\;ha^{-1}){\sim}6.6%(50Mg\;ha^{-1})$ by AFA showing maximum yields of 5.084 and $4.738Mg\;ha^{-1}$ by the former and the latter, respectively. Rice plant showed lodging indices ranging from $20(50Mg\;ha^{-1}){\sim}40%(150Mg\;ha^{-1})$ by BCFA and from $1.3(150Mg\;ha^{-1}){\sim}15%(50Mg\;ha^{-1})$ by AFA at harvesting stage. In especial, soils applicated with BCFA contained a good fertility in terms of pH, available $P_2O_5$ and $SiO_2$, and exchangeable Ca and Mg etc. so that possibly harbored 3yr-residual effects of the fly ash on crop subsequent to this rice.

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