• Title/Summary/Keyword: sub-cycle

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Synthesis and Electrochemical Properties of Li[Ni1/3Co1/3Mn1/3]O2 Nanowire by the Electrospinning Method (전기방사법을 이용한 Li[Ni1/3Co1/3Mn1/3]O2 나노 섬유의 합성 및 전기화학적 특성)

  • Kang, Chung-Soo;Son, Jong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.850-854
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    • 2011
  • Nano-fibers of the $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ electrode were synthesized from a metal oxide precursor using the electrospun method. The XRD patterns of all prepared powders showed a hexagonal ${\alpha}$ - $NaFeO_2$ structure (space group: R-3 m, 166). Scanning electron microscopy showed that all the synthesized samples were comprised of nanofibers with a size of 100~800 nm. Among the samples tested, the calcined $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ nanowires in oxygen heating atmosphere showed a high charge and discharge capacity of 239.22 and 172.81 $mAhg^{-1}$ at the $1^{st}$ cycle, respectively. In addition, the charge transfer resistance was also improved significantly compared to the other samples.

Prelithiation of Alpha Phase Nanosheet-Type VOPO4·2H2O Anode for Lithium-Ion Batteries

  • Tron, Artur;Mun, Junyoung
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.90-99
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    • 2022
  • Owing to the rising concern of global warming, lithium-ion batteries have gained immense attention over the past few years for the development of highly efficient electrochemical energy conversion and storage systems. In this study, alpha-phase VOPO4·2H2O with nanosheet morphology was prepared via a facile hydrothermal method for application in high-performance lithium-ion batteries. The X-ray diffraction and scanning electron microscopy (SEM) analyses indicated that the obtained sample had an alpha-2 (αII) phase, and the nanosheet morphology of the sample was confirmed using SEM. The lithium-ion battery with VOPO4·2H2O as the anode exhibited excellent long-term cycle life and a high capacity of 256.7 mAh g-1 at room temperature. Prelithiation effectively improved the specific capacity of pristine VOPO4·2H2O. The underlying electrochemical mechanisms were investigated by carrying out AC impedance, rate capability, and other instrumental analyses.

Simple Synthesis of SiOx by High-Energy Ball Milling as a Promising Anode Material for Li-Ion Batteries

  • Sung Joo, Hong;Seunghoon, Nam
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.445-453
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    • 2022
  • SiOx was prepared from a mixture of Si and SiO2 via high-energy ball milling as a negative electrode material for Li-ion batteries. The molar ratio of Si to SiO2 as precursors and the milling time were varied to identify the synthetic condition that could exhibit desirable anode performances. With an appropriate milling time, the material showed a unique microstructure in which amorphous Si nanoparticles were intimately embedded within the SiO2 matrix. The interface between the Si and SiO2 was composed of silicon suboxides with Si oxidation states from 0 to +4 as proven by X-ray photoelectron spectroscopy and electrochemical analysis. With the addition of a conductive carbon (Super P carbon black) as a coating material, the SiOx/C manifested superior specific capacity to a commercial SiOx/C composite without compromising its cycle-life performance. The simple mechanochemical method described in this study will shed light on cost-effective synthesis of high-capacity silicon oxides as promising anode materials.

A Study on Preparation and Reactivity of Zinc Titanate Sorbents for H2S Removal (아연-티타늄 복합산화물 탈황제의 제조 및 반응특성 연구)

  • Kim, Ki-Seok;Park, No-Kuk;Lee, Tae-Jin
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.122-131
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    • 1997
  • Zinc titanate sorbents for $H_2S$ removal were prepared and their reactivities were studied for high temperature desulfurization of coal gas. Sulfidation of zinc titanates by $H_2S$ sorption was conducted in a packed-bed tubular flow reactor at the temperature range of $550{\sim}750^{\circ}C$, and the results reveal that $650^{\circ}C$ was the optimal sulfidation temperature with respect to desulfurization efficiency and zinc loss. The structural change of sorbent particle was investigated by SEM analysis for the forbents sulfided at $650^{\circ}C$ and subsequently regenerated at $750^{\circ}C$. The stability of desulfurization capability as well as the mechanical stability of the zinc titanates was studied by means of the successive cycles of sulfidation-regeneration of sorbents, and the sorbent samples taken after the 10th cycle were characterized using BET, XRD, and SEM/EDX analyses. Zinc titanate sorbents exhibited nearly constant desulfurization capability in the successive cycle operation.

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Cell Cycle Modulation of MCF-7 and MDA-MB-231 by a Sub-Fraction of Strobilanthes crispus and its Combination with Tamoxifen

  • Yaacob, Nik Soriani;Kamal, Nik Nursyazni Nik Mohamed;Wong, Kah Keng;Norazmi, Mohd Nor
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.18
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    • pp.8135-8140
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    • 2016
  • Background: Cell cycle regulatory proteins are suitable targets for cancer therapeutic development since genetic alterations in many cancers also affect the functions of these molecules. Strobilanthes crispus (S. crispus) is traditionally known for its potential benefits in treating various ailments. We recently reported that an active sub-fraction of S. crispus leaves (SCS) caused caspase-dependent apoptosis of human breast cancer MCF-7 and MDA-MB-231 cells. Materials and Methods: Considering the ability of SCS to also promote the activity of the antiestrogen, tamoxifen, we further examined the effect of SCS in modulating cell cycle progression and related proteins in MCF-7 and MDA-MB-231 cells alone and in combination with tamoxifen. Expression of cell cycle-related transcripts was analysed based on a previous microarray dataset. Results: SCS significantly caused G1 arrest of both types of cells, similar to tamoxifen and this was associated with modulation of cyclin D1, p21 and p53. In combination with tamoxifen, the anticancer effects involved downregulation of $ER{\alpha}$ protein in MCF-7 cells but appeared independent of an ER-mediated mechanism in MDA-MB-231 cells. Microarray data analysis confirmed the clinical relevance of the proteins studied. Conclusions: The current data suggest that SCS growth inhibitory effects are similar to that of the antiestrogen, tamoxifen, further supporting the previously demonstrated cytotoxic and apoptotic actions of both agents.

Optimal Preventive Maintenance Period in Complex Systems in Considering Components Reliability Characteristic (하부 구성품의 신뢰도 특성을 고려한 복합 시스템의 최적 예방정비 주기 산출)

  • Lee, Youn-Ho;Lee, Ik-Do;Lee, Dong-Woo;Sohn, Ki-Hong
    • Journal of Korean Institute of Industrial Engineers
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    • v.37 no.4
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    • pp.390-399
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    • 2011
  • Generally the life-cycle cost of complex systems composed of several sub systems or equipments such as train, aircraft weapon systems is spent much more during operation and maintenance phase than development phase. The maintenance cost for maintaining the availability and extending the life span of systems comprise a large proportion of systems operation cost. The cycle of preventive maintenance affects operation and maintenance cost a lot. In this study we introduce a way minimizing life-cycle cost of systems by calculating more reliable preventive maintenance period than the results of previous study using systems reliability data considered the reliability and failure effect ratio of sub-systems or components. We can solve the preventive maintenance period problem known as NP-Hard as quick as possible by using modified genetic algorithm than using other models introduced in previous study.

Flow Cytometric Analysis of the Effect of Silkworm Hemolymph on the Baculovirus-Induced Insect Cell Apoptosis

  • Rhee, Won-Jong;Park, Tai-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.11 no.5
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    • pp.853-857
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    • 2001
  • The effect of silkworm hemolymph on the inhibition of baculovirus-induced insect cell apoptosis was quantitatively investigated using a flow cytometric analysis. Spodoptera frugiperda (Sf9) cell and Autographa californica nuclear polyhedrous virus (AcNPV) were used as a model for insect cell and baculovirus in this study, respectively. Compared with a mammalian cell cycle, the fraction of G1 cells was relatively small in the Sf9 cell cycle. Silkworm hemolymph did not affect the Sf9 cell-cycle distribution before the baculovirus infection. However, the fraction of cells which are not in the sub-G1 phase remained at a high level for 3 days after the infection in the medium without silkworm hemolymph, while it remained at a high level for 7 days after the infection in the medium supplemented with silkworm hemolymph. The fractions of apoptotic cells in the sub-G1 phase were $4.7\%$, and 4 days after infection, $22.7\%$, in the media with and without silkworm hemolymph, respectively.

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Comparative Analysis of SOx Emission-Compliant Options for Marine Vessels from Environmental Perspective

  • Jeong, Byongug
    • Journal of Power System Engineering
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    • v.22 no.1
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    • pp.72-78
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    • 2018
  • With growing concerns over air pollutions attributed to shipping activities, the international maritime organization has enacted a series of stringent regulations. In particular, MARPOL Annex IV Reg. 16 requires sulfur contents from exhaust gases of marine engines to be progressively reduced. To comply with this regulation, three feasible options have been introduced: using LNG as a marine fuel, using heavy fuel oil with the scrubber system, and using the marine gas oil (a type of low sulfur fuel oil). For the objectives of this paper, the holistic environmental impacts pertinent to these options were investigated and compared in ways that the flows of energy and emission were tracked and quantified through the life cycle of the ship. Research findings obtained from a case study with a large bulk carrier showed that the use of the scrubber system to purify heavy fuel oil would produce relatively fewer amounts of emissions attributing to global warming than other two options. On the other than, the use of LNG would be the way to operate the ship in a cleaner way in terms of reducing the acidification, eutrophication, and photochemical effects. Throughout the analysis, the excellence of life cycle assessment was proven to shift the environmental impact of marine systems from the short-term view to the long-term one.

Diffraction-Limited High-Power Single-Cycle Terahertz Pulse Generation in Prism-Cut LiNbO3 for Precise Terahertz Applications

  • Baek, In Hyung;Kang, Bong Joo;Jeong, Young Uk;Rotermund, Fabian
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.60-64
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    • 2014
  • We report the generation of 3.3-mW single-cycle terahertz (THz) pulses at 1-kHz repetition rate via optical rectification in MgO-doped prism-cut stoichiometric LiNbO3. Efficient pulse-front tilting of 800-nm pulses was realized by an optimized single-lens focusing scheme for radially-symmetric propagation of THz beams. In this geometry, nearly-diffraction-limited THz Gaussian beams with electric field strength as high as 350 kV/cm were generated. The pump-to-THz energy conversion efficiency of $1.36{\times}10^{-3}$ and the extremely high signal-to-noise ratio of ~1:15000 achieved are among the best results for 1-kHz single-cycle terahertz pulse generation ever demonstrated in room temperature operation.

Comparative Life Cycle Assessment of Reusable and Disposable Distribution Packaging for Fresh Food (신선식품용 재사용 EPE박스와 EPS박스에 대한 전과정 환경영향평가)

  • SY Kim;Charoensri Korakot;YJ Shin;HJ Park
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.181-193
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    • 2023
  • In this study, we conducted a comparative life cycle assessment (LCA) of two different products, considering reusable and single-use packaging for fresh food distribution. For reusable packaging, we utilized expanded polyethylene (EPE), while for comparison, a disposable box made of widely used expanded polystyrene (EPS) was selected. We comprehensively analyzed the environmental impacts of production, transportation, reprocessing (for reused boxes), and disposal across 18 impact categories. Upon analyzing the actual reuse of 300 rounds of fresh food, the cumulative global warming potential (GWP) values for the EPE box were found to be 280.21 kg carbon dioxide (CO2) eq, demonstrating a significant 75% reduction compared to those of the EPS box. Furthermore, it was observed that the GWP values for the EPE boxes became equivalent to those of the EPS boxes after 12 rounds of reuse. In conclusion, reusable packaging shows substantial potential to contribute to the reduction of environmental burdens, aligning well with global environmental requirements for sustainable food distribution and related industries.