• Title/Summary/Keyword: sub-cycle

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Crystal Structure and Electrochemical Properties of LiMn2-yMyO4 Cathode Material by Complex Substitution of Mg and Zn (Mg와 Zn의 복합치환에 따른 LiMn2-yMyO4 정극 활물질의 결정 구조 및 전기화학적 특성)

  • 정인성;정해덕;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.361-366
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    • 2002
  • Spinel $LiMn_{2-y}M_yO_4$ and $LiMn_{2-y}M_yO_4$ (M=Mg, Zn) powders were synthesized by solid-state method at $800^{\circ}C$ for 37h. Crystal structure and electrochemical properties were analyzed by X-ray diffraction, charge-discharge test, cyclic voltammetry and ac impedance to $LiMn_{2-y}M_yO_4$. All cathode material showed spinel structure in X-ray diffraction. Ununiform distortion which calculated by (111) face and (222) face was almost constant in spite of the change of the kind and the substituting ratio of the metal cation in $LiMn_{2-y}M_yO_4$ (M=Mg, Zn). $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cell substituted $Mg^{+2}$ and $Zn^{+2}$ showed excellent discharge capacities than other cells, which it presented about 120mAh/g at the 1st cycle and about 73mAh/g at the 250th cycle, respectively. AC impedance of $LiMn_{2-y}M_yO_4/Li$ cells showed the similar resistance of about 65~110$\Omega$ before cycling.

Electrical Properties of Al2O3 Films Grown by the Electron Cyclotron Resonance Plasma-Enhanced Atomic Layer Deposition (ECR-PEALD) and Thermal ALD Methods (전자 사이클로트론 공명 플라즈마와 열 원자층 증착법으로 제조된 Al2O3 박막의 물리적·전기적 특성 비교)

  • Yang, Dae-Gyu;Kim, Yang-Soo;Kim, Jong-Heon;Kim, Hyoung-Do;Kim, Hyun-Suk
    • Korean Journal of Materials Research
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    • v.27 no.6
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    • pp.295-300
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    • 2017
  • Aluminum-oxide($Al_2O_3$) thin films were deposited by electron cyclotron resonance plasma-enhanced atomic layer deposition at room temperature using trimethylaluminum(TMA) as the Al source and $O_2$ plasma as the oxidant. In order to compare our results with those obtained using the conventional thermal ALD method, $Al_2O_3$ films were also deposited with TMA and $H_2O$ as reactants at $280^{\circ}C$. The chemical composition and microstructure of the as-deposited $Al_2O_3$ films were characterized by X-ray diffraction(XRD), X-ray photo-electric spectroscopy(XPS), atomic force microscopy(AFM) and transmission electron microscopy(TEM). Optical properties of the $Al_2O_3$ films were characterized using UV-vis and ellipsometry measurements. Electrical properties were characterized by capacitance-frequency and current-voltage measurements. Using the ECR method, a growth rate of 0.18 nm/cycle was achieved, which is much higher than the growth rate of 0.14 nm/cycle obtained using thermal ALD. Excellent dielectric and insulating properties were demonstrated for both $Al_2O_3$ films.

Fe3O4 Nanoparticles on MWCNTs Backbone for Lithium Ion Batteries

  • Lee, Kangsoo;Shin, Seo Yoon;Yoon, Young Soo
    • Journal of the Korean Ceramic Society
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    • v.53 no.3
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    • pp.376-380
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    • 2016
  • A composite electrode made of iron oxide nanoparticles/multi-wall carbon nanotube (iNPs/M) delivers high specific capacity and cycle durability. At a rate of $200mAg^{-1}$, the electrode shows a high discharge capacity of ${\sim}664mAhg^{-1}$ after 100 cycles, which is ~ 70% of the theoretical capacity of $Fe_3O_4$. Carbon black, carbon nanotube, and graphene as anode materials have been explored to improve the electrical conductivity and cycle stability in Li ion batteries. Herein, iron oxide nanoparticles on acid treated MWCNTs as a conductive platform are combined to enhance the drawbacks of $Fe_3O_4$ such as low electrical conductivity and volume expansion during the alloying/dealloying process. Enhanced performance was achieved due to a synergistic effect between electrically 3D networks of conductive MWCNTs and the high Li ion storage ability of $Fe_3O_4$ nanoparticles (iNPs).

PM10 Emission Estimation from LNG G/T Power Plants and Its Important Analysis on Air Quality in Incheon Area (인천 지역 LNG G/T발전소의 미세먼지 (PM10) 배출량 평가 및 주변 대기질 영향 분석)

  • Gong, Bu-Ju;Park, Poong-Mo;Dong, Jong-In
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.5
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    • pp.461-471
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    • 2015
  • Base on emission factors derived from National Institute of Environmental Research, Particulate matter from combined cycle power plants (CCPPs) has been estimated to be a important source of $PM_{10}$. Generally there is no serious emission of particulate matter in CCPPs. because the fuel of them is natural gas. But emission gas after long shut down season has very high dust content. Therefore $PM_{10}$ emission rate is dependent on its operation mode. In this study, particulate dispersion study for new city near CCPPs complex has performed using CALPUFF model for three case. $PM_{10}$ concentration has big difference between normal operation and 2 case start-up condition after long shutdown. In normal operating conditions, daily $0.32{\sim}0.50{\mu}g/m^3$ influence on of the surrounding area. But when 1~2 aerobic high concentration discharged conditions, average concentration is higher about $9.2{\sim}34.1{\mu}g/m^3$ than normal operating conditions.

An Experimental Study on the Factors that Affect Fatigue Crack Growth Retardation Behavior in S45C Steel (S45C 강의 피로균열전파 지연거동의 영향인자에 관한 실험적 연구)

  • Kim, Seon-Jin;An, Seok-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.3
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    • pp.470-477
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    • 2001
  • Constant ΔK fatigue crack growth tests were performed by applying an intermediate multiple overload for S45C steel. The purpose of the present study is to investigate effects of specimen thickness at various baseline stress intensity factor range levels (ΔK(sub)b), overload application position (a/W) and overload application frequency (OL(sub)HZ) on fatigue crack growth retardation behavior. The principal results are summarized as follows. The amount of retardation for a given ΔK(sub)b level is increased with increasing the baseline stress intensity factor range level for all specimen thickness. The normalized minimum crack growth rate is increased with increasing the specimen thickness, except for ΔK=45MPa√m. The retardation cycle is decreased with increasing a/W and increased with OL(sub)HZ.

A Proposal of Life Cycle CO2 Assessment Techniques for Building in Construction Stage by BIM LOD (건설단계 BIM을 이용한 건축물의 전 과정 CO2 평가 기법 제안에 관한 연구)

  • Bang, Jun-Sik;Tae, Sung-Ho;Roh, Seung-Jun;Keum, Won-Seok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.53-54
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    • 2012
  • This study is aimed at utilizing LCA processor with BIM LOD, eliciting the problems of the existing environmental assessment by constructing the database for environmental values of green buildings. For these objects, environmental load database of BIM construction material and evaluation process are presented, after matching BIM family based environmental load database which is available during evaluation stage, input-output tables and Korea LCI database to standard item code of public procurement service. It is a important factor in environmental assessment of building to develop database unit of standard item code for BIM and construction material. Thus, the results of this study are expected to provide basic data for improving effectiveness of construction through BIM based environmental load evaluation database. Furthermore, the provided environmental load database unit for construction material is considered to be available as basic information for BIM study by suggesting a processor connecting BIM with LCA and along with this, continuous examination on the connection process is needed.

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Effect of Non-Idealities on the Design and Performance of a DC-DC Buck Converter

  • Garg, Man Mohan;Pathak, Mukesh Kumar;Hote, Yogesh Vijay
    • Journal of Power Electronics
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    • v.16 no.3
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    • pp.832-839
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    • 2016
  • In this study, the performance of a direct current (DC)-DC buck converter is analyzed in the presence of non-idealities in passive components and semiconductor devices. The effect of these non-idealities on the various design issues of a DC-DC buck converter is studied. An improved expression for duty cycle is developed to compensate the losses that occur because of the non-idealities. The design equations for inductor and capacitor calculation are modified based on this improved expression. The effect of the variation in capacitor equivalent series resistance (ESR) on output voltage ripple (OVR) is analyzed in detail. It is observed that the value of required capacitance increases with ESR. However, beyond a maximum value of ESR (rc,max), the capacitor is unable to maintain OVR within a specified limit. The expression of rc,max is derived in terms of specified OVR and inductor current ripple. Finally, these theoretical studies are validated through MATLAB simulation and experimental results.

Experimental Study on the Performance Characteristics of a CO2 Air-conditioning System for Vehicles (자동차용 CO2 에어컨 시스템의 성능 특성에 관한 실험적 연구)

  • Lee, Daewoong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.1
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    • pp.18-24
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    • 2015
  • In this study, a $CO_2$ air-conditioning system was investigated with different types of electrically driven compressors, parallel flow type gas cooler, four-pass type evaporator, internal heat exchanger integrated with accumulator, and electric expansion valve. The experimental study was conducted under various operating conditions (ie., different rotational compressor speeds, air inlet temperatures and air velocity coming into heat exchangers). The experimental results showed the cooling capacity was 3.5kW at $35^{\circ}C$ ambient temperature when the vehicle was idle (ie., the worst condition for cooling off the gas cooler). In terms of performance effect of the compressor, the e-RP model had a slightly better cooling capacity and coefficient of performance than the e-GR model under the same test conditions. An experimental equation for optimum cooling-performance control was also suggested based on the results. A high-pressure control algorithm for the super critical cycle was determined to achieve both maximum cooling performance and efficient energy consumption. The results from the experimental equation coincided with those of previous experimental studies.

A study on the fabrication of periodically poled Ti:LiNbO3 (PPLN) by the control of charge (전하량제어에 의한 주기적 분극반전 Ti:LiNbO3 (PPLN) 제작 공정에 관한 연구)

  • Kim, Won-Joung;Jung, Hong-Sik;Lee, Han-Young
    • Korean Journal of Optics and Photonics
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    • v.16 no.4
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    • pp.366-375
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    • 2005
  • A fabrication process of periodic electric field assisted poling of Ti-diffused channel waveguides in LiNbO3 (Ti:PPLN) has been developed and improved using a periodic 180o phase inversion along the z-axis. The zig for poling inversion and the Labview program of charge control have been devised. Pulse high voltage and duty cycle were adjusted based on the estimated charge required for poling inversion. Monitoring the change of leakage current under applied voltage less than the coercive voltage also minimized a breakdown.

The optimization for the straight-channel PCHE size for supercritical CO2 Brayton cycle

  • Xu, Hong;Duan, Chengjie;Ding, Hao;Li, Wenhuai;Zhang, Yaoli;Hong, Gang;Gong, Houjun
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1786-1795
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    • 2021
  • Printed Circuit Heat Exchanger (PCHE) is a widely used heat exchanger in the supercritical carbon dioxide (sCO2) Brayton cycle because it can work under high temperature and pressure, and has been a hot topic in Next Generation Nuclear Plant (NGNP) projects for use as recuperators and condensers. Most previous studies focused on channel structures or shapes. However, no clear advancement has so far been seen in the allover size of the PCHE. In this paper, we proposed an optimal size of the PCHE with a fixed volume. Two boundary conditions of PCHE were simulated, respectively. When the volume of PCHE was fixed, the heat transfer rate and pressure loss were picked as the optimization objectives. The Pareto front was obtained by the Multi-objective optimization procedure. We got the optimized number of PCHE channels under two different boundary conditions from the Pareto front. The comprehensive performance can be increased by 5.3% while holding in the same volume. The numerical results from this study can be used to improve the design of PCHE with straight channels.