• Title/Summary/Keyword: structure of charcoal

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Characteristics of Physical and Adsorption of Korean Traditional Charcoal (우리나라 전통 숯의 물리.화학적 특성)

  • Kim, Joon-Tae;Kim, Sun-Hwa;Kim, Hae-Jin
    • Journal of environmental and Sanitary engineering
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    • v.21 no.4 s.62
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    • pp.77-86
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    • 2006
  • The water purification was very important in Korea which has not sufficient water resource and while adsorption method among the various methods to eliminate the water pollutants has been widely used by activated carbon. This study was conducted the basic experiment for hall distribution, pH, conductivity, electronic microscope, cation exchange and inorganic materials the adsorption capacity of Korean traditional charcoal which has similar characteristics to activated carbon of organic pollutants. As a result of observing Korean traditional charcoal with electronic microscope, it was found that it has porous structure, oak charcoal has circular structure, pine charcoal has square structure and bamboo charcoal has hexagonal structure, which has high void fraction per unit area because of its thin cell wall structure. As a result of experimenting hall distribution, hall distribution of bamboo high temperature charcoal is high as 0.269cc/g and has the greatest inorganic contents and cation exchange capacity(CEC) which are the important factor of chemical adsorption.

Association Analysis of Charcoal Rot Disease Resistance in Soybean

  • Ghorbanipour, Ali;Rabiei, Babak;Rahmanpour, Siamak;Khodaparast, Seyed Akbar
    • The Plant Pathology Journal
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    • v.35 no.3
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    • pp.189-199
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    • 2019
  • In this research, the relationships among the 31 microsatellite markers with charcoal rot disease resistance related indices in 130 different soybean cultivars and lines were evaluated using association analysis based on the general linear model (GLM) and the mixed linear model (MLM) by the Structure and Tassel software. The results of microsatellite markers showed that the genetic structure of the studied population has three subpopulations (K=3) which the results of bar plat also confirmed it. In association analysis based on GLM and MLM models, 31 and 35 loci showed significant relationships with the evaluated traits, respectively, and confirmed considerable variation of the studied traits. The identified markers related to some of the studied traits were the same which can probably be due to pleiotropic effects or tight linkage among the genomic regions controlling these traits. Some of these relationships were including, the relationship between Sat_252 marker with amount of charcoal rot disease, Satt359, Satt190 and Sat_169 markers with number of microsclerota in stem, amount of charcoal rot disease and severity of charcoal rot disease, Sat_416 marker with number of microsclerota in stem and amount of charcoal rot disease and the Satt460 marker with number of microsclerota in stem and severity of charcoal rot disease. The results of this research and the linked microsatellite markers with the charcoal rot disease-related characteristics can be used to identify the suitable parents and to improve the soybean population in future breeding programs.

Characteristics of White Charcoal Produced from the Charcoal Kiln for Thermotherapy (온열욕 겸용 숯가마에서 생산된 백탄의 특성)

  • Kwon, Gu Joong;Kim, Ah Ran;Lee, Hee Soo;Lee, Seung Hwan;Hidayat, Wahyu;Febrianto, Fauzi;Kim, Nam Hun
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.527-540
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    • 2018
  • In this study, the characteristics of the white charcoal from charcoal kilns made for both charcoal production and thermotherapy and from the traditional charcoal kiln were compared and examined. A charcoal kiln for thermotherapy as a secondary purpose was made to minimize environmental problems such as fine dust and harmful gas generated from sealed charcoal kiln in consideration of comfort and safety. White Charcoal produced from the charcoal kiln for both charcoal production and thermotherapy had higher ash and volatile matter and lower fixed carbon than that from the traditional charcoal kiln. The density of the white charcoal produced from the charcoal kiln for both charcoal production and thermotherapy was slightly higher than that of the traditional one, but the equilibrium moisture content and pH were not significantly different. The calorific value, refinement degree, hardness and anatomical structure were not different between the two. It was concluded that the white charcoal produced from the advanced charcoal kiln for thermotherapy as a secondary purpose meets the quality certification standards of Korea Forest Research Institute.

Breakthrough behaviour of activated charcoal cloth samples against oxygen analogue of sulphur mustard

  • Prasad, G.K.;Kumar, J. Praveen;Ramacharyulu, P.V.R.K.;Singh, Beer
    • Carbon letters
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    • v.16 no.1
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    • pp.19-24
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    • 2015
  • The breakthrough behaviour of activated charcoal cloth samples against an oxygen analogue (OA) of sulphur mustard has been studied using the modified Wheeler equation. Activated charcoal cloth samples having different surface area values in the range of 481 to $1290m^2/g$ were used for this purpose. Breakthrough behaviour was found to depend on the properties of the activated charcoal cloth, properties of the OA and the adsorption conditions. Activated charcoal cloth with a high surface area of $1290m^2/g$, relatively large surface density of $160g/m^2$ and coarser fiber structure exhibited better kinetic saturation capacity value, 0.19 g/g, against OA vapours when compared to others, thus confirming its potential use in foldable masks for protection against chemical warfare agents.

Bicomponent Finishing of Cotton Fabrics(II) - Chitosan and Charcoal - (면직물의 복합가공(II) - 키토산과 숯 -)

  • Bae, Ki-Hyun;Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.10 no.5
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    • pp.748-755
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    • 2008
  • The purpose of this study is to investigate the effect of chitosan treatment on the dyeing of cotton fabric using charcoal as colorants. Particle size of charcoal, dyeability(K/S), SEM morphology of dyed fabrics and color fastness were also investigated. In this study, cotton fabrics were treated with a crosslinking agent epichlorohydrin in the presence of chitosan to provide the cotton fabrics the dyeing properties of natural dye by the chemical linking of chitosan to the cellulose structure. The results obtained were as follows; Mean average diameter of charcoal was 1.44 ${\mu}m$. According to various conditions, the dyeing effects of 1% chitosan treatment on the dyeing of cotton fabrics using charcoal were the highest with 10%(owb) of charcoal at $90^{\circ}C$ for 120minutes and non-treatment of cotton fabrics were the highest with 15%(owb) of charcoal at $90^{\circ}C$ for 150minutes. Overall, K/S value of 1% chitosan treatment of cotton fabrics on the natural dyeing using charcoal was higher than non-treatment of cotton fabrics. It was observed the surfaces of cotton fabrics treated with chitosan were adsorbed with charcoal powders of particle size more than a non-treated chitosan fabric by SEM. The cotton fabrics were dyed with blackish gray color by charcoal gradually according to treating chitosan. The K/S value, that is indicative of dye affinity, became higher as the increase of treated chitosan concentration. The color fastness of charcoal, washing and light fastness was excellent as 4-5 grade.

Adsorption Characteristics of Heavy Metals in Wastewater on Bone Charcoal (Bone Charcoal에 의한 폐수증의 중금속 흡착특성)

  • Chung, Paul-Gene;Kwak, Dong-Heui;Lee, Jae-Wook
    • Journal of Korean Society on Water Environment
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    • v.16 no.4
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    • pp.555-563
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    • 2000
  • The study was conducted to evaluate the adsorption equilibrium of heavy metals on bone charcoal made of livestock bone which was sintered at $550{\sim}600^{\circ}C$. Analysis of bone charcoal by XRD and FT-IR showed that crystal structure was similar to that of synthetic hydroxyapatite. Adsorption equilibrium capacity of single component (Pb, Cd, and Zn) on bone charcoal could be expressed as Langmuir, Freundlich, and Sips equations. Sips isotherm was best among the three isotherms. The values predicted by IAST(ideal adsorbed solution theory) showed good relationship to the experimental data in multicomponent adsorption equilibrium. Adsorption affinity was in order of Pb, Cd, and Zn. The order was same in case of activated carbon or synthetic hydroxyapatite. Through the study results. it would be expected that bone charcoal made of livestock could be used in field of wastewater treatment plants as adsorbent to remove heavy metal.

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A Study on the Chemical Composition and Structure of Sludge, Compost and Charcoal (폐수처리 슬럿지와 퇴비 및 목탄의 화학적 특성과 구조에 관한 연구)

  • 임기표;위승곤
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.27-32
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    • 2003
  • To understand the chemical structure of sewer sludge in comparison with commercial compost and charcoal used as a soil improver, it was carried out to analyse their ash contents and metal ions, and to elucidate the chemical structure of their residuals after a sequential treatment of alcohol-benzene(1:2) extraction in Soxhlet, 3% HCl reflux and 79% H₂SO₄ hydrolysis, using CHNS analyzer and solid C-13 NMR spectrometer. The results obtained were as follows: 1. Ash content of sludge was about 46% that is higher than those of compost (17%) and charcoal (4%). 2. The residual of sludge after a sequential treatment of HCl and H₂SO₄ hydrolyses had high ash content about 23%, too. 3. The sludge seems to be suitable to the soil improver because the content of heavy metal ions in sludge was near the compost and below the organic fertilizer standard. 4. Elemental composition of sludge residual after HCl-H₂SO₄ hydrolyes was C/sub 56/H/sub 91/O/sub 12/N₂S = (C/sub 6/H/sub 10/O/sub 5/)/sub 7/(C/sub 6/H₄)/sub 7/C₂H/sub 43/O₂N₂S, similar to C/sub 103/H/sub 122/O/sub 33/N/sub 6/S = (C/sub 6/H/sub 10/O/sub 5/)/sub 6/(C/sub 6/H₄)/sub 10/C/sub 7/H/sub 22/O₃N/sub 6/S of compost. 5. The sludge residual had proved to have both considerable aliphatic and aromatic groups, but the compost residual to have mainly aliphatic groups and the charcoal to have mainly aromatic groups, through the peak analysis of solid C-13 NMR charts. 6. So, the sewer sludge is proved to have a considerable amount of aromaticity like in woody biomass containing lignin.

A Study on the Properties and Friendly Environment Efficiency Charcoal Concrete Bricks (숯 첨가 콘크리트벽돌의 물성특성과 친환경 성능에 관한 연구)

  • Kim Young-Min;Choi Hee-Yong;Chung Yu-Gun;Ryu Hyun-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.6 no.1 s.19
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    • pp.123-130
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    • 2006
  • After the new house symptoms recently, room environment pollution problem of building syndrome and so on is becoming research about ways to solve this being risen. Is taking advantage of nature data by building materials by one of this way, but Friendly Environmental performance examination for structure material is insufficient misgovernment being real condition that put emphasis in ability as most embellishment and in finish. Environmental examination is insufficient misgovernment on factor itself as structure material. Also, being real condition that radon that is responsible for lung cancer occurrence next to smoke in building materials such as concrete and so on is happened, the danger is reported much through mass communications and research paper etc. Therefore, this research measured radon release amount and the carbon dioxide adsorption rate for physical special quality measuring and Friendly Environment Efficiency that follow to 'KS F 4004 Concrete bricks' regulation after manufacture Concrete Bricks utilizing charcoal that is nature material by sand. This study finding carbon dioxide density appeared and displayed effect that charcoal Controls radon release that happen in Concrete Bricks to maximum 74% that decrease to best 95% though decreased the charcoal addition rate increases.

Anatomy of Quercus variabilis Charcoal Manufactured at Various Temperatures (제조 온도에 따른 굴참나무 목탄의 해부학적 특성)

  • Kim, Nam-Hun;Hwang, Won-Joong;Kwon, Sung-Min;Kwon, Goo-Joong;Lee, Seong-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.1-8
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    • 2006
  • Anatomy of Quercus variabilis charcoal was investigated by scanning electron microscopy. Charcoal was prepared in an electric furnace under nitrogen gas atmosphere at $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$, and $1000^{\circ}C$ for 10 min. The structure of charcoal was significantly affected by charring temperature. In cross section, charcoal prepared at $400^{\circ}C$ exhibited a smooth clean surface. As the charring temperature increased, the surface became more rough and increasingly disrupted. The cell walls appeared homogeneous and glass-like. Ray parenchyma cells showed very little separation from each other in radial section at $400^{\circ}C$. At $600^{\circ}C$ and above there is an apparent disintegration of the middle lamella, resulting in a separation of the ray cells. The $2{\sim}4{\mu}m$ wart-like protuberances were observed on the surfaces of the parenchyma cells. These structures were seen in charcoal prepared at all temperatures. Distinctive features can be seen in multiseriate rays as large crack and split. Rhomboidal crystals in crystalliferous cells had a smooth surface at $400^{\circ}C$ and $600^{\circ}C$, but the crystals had a sponge like appearance at $800^{\circ}C$ and $1000^{\circ}C$.

Analysis of Structure and Physical and Chemical Properties of the Carbonized Pine Wood (Pinus densiflora Sieb. et Zucc.) Materials - Pyrolytic Behavior of Pine Wood Dust - (가열처리 및 탄화처리 소나무재(Pinus densiflora Sieb. et Zucc.)의 구조 및 물리·화학적 특성(III) - 소나무재 톱밥의 열분해 반응 -)

  • Lee, In-Ja;Lee, Won-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.3
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    • pp.266-274
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    • 2014
  • To extend the understanding of the pyrolysis mechanism of wood, we have investigated wood dust charcoal and condensate of volatile organic compounds (VOC) obtained during the pyrolysis of red pine (Pinus densiflora Sieb. et Zucc.) at $180{\sim}450^{\circ}C$ using elemental analysis, IR and GC/Mass. The effect of activation process on the charcoal structure also has been studied by comparing elemental analysis and IR data of charcoal carbonated at $600^{\circ}C$ and charcoals activated at $750^{\circ}C$. The results show that pyrolysis of wood has mainly started near at $240^{\circ}C$ and its chemical components did not changed much up to $270^{\circ}C$. However, the element contents and IR spectra drastically changed at $300^{\circ}C$. The fact that IR peaks related to the aromatic ring of lignin are observed in the charcoal pyrolized at $450^{\circ}C$ indicates that a small part of lignin still remains at this temperature. The chemical structure of the activated charcoal seems almost unaffected by the activation time.