• Polymer(Korea)
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• v.37 no.2
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• pp.232-239
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• 2013

A series of novel imidazole-blocked diisocyanate bioadhesives (IBAs) were synthesized from reaction of toluene 2, 4-diisocyanate (TDI), isophorone diisocyanate (IPDI), hydroxyl-terminated polylactide (HO-PLA-OH), 1,1,1-trimethylolpropane (TMP), and imidazole. Synthesis of IBAs was confirmed by Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC). Differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) revealed that the TDI-based IBA had lower thermal dissociation temperature and a faster deblocking rate than IBA based on IPDI. Hydroxyl-terminated polyurethane (HPU) was introduced to study the adhesive effect of the synthesized IBAs. Improvement on elastic modulus, tensile strength and water resistance of IBA-modified HPU in comparison with neat HPU suggested the good adhesive effect of IBA due to the strong chemical reaction between released NCO groups from IBA and hydroxyl groups from HPU.

• Journal of Radiation Industry
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• v.5 no.1
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• pp.41-46
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• 2011

Polyacrylonitrile (PAN) fibers are the most widely used precursor of the materials for carbon fibers. The conventional process of carbon fibers from PAN precursor fiber includes two step; stabilization at low temperature and carbonization at high temperature. Compared to thermal stabilization, the stabilization process by electron beam (E-beam) irradiation is a advanced and brief method. However, a stabilization by E-beam irradiation was required a high dose (over 5,000 kGy) and spend over 1.5 hr (1.14 MeV, 1 mA). In the present work the main goal is exploring a quick stabilization process by cotrolling E-beam currents. The effect of various E-beam currents on stabilization of PAN precursor fiber was studied by gel fraction test, thermo gravimertic analysis (TGA), differential scanning calorimetry (DSC), tensile strength, and scanning electron microscopy (SEM) images.

• Advances in nano research
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• v.10 no.5
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• pp.423-435
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• 2021

This paper examines the thermal post-buckling behaviors of graphene-reinforced metal matrix composite (GRMMC) laminated cylindrical panels which possess in-plane negative Poisson's ratio (NPR) and rest on an elastic foundation. A panel consists of GRMMC layers of piece-wise varying graphene volume fractions to obtain functionally graded (FG) patterns. Based on the MD simulation results, the GRMMCs exhibit in-plane NPR as well as temperature-dependent material properties. The governing equations for the thermal post-buckling of panels are based on the Reddy's third order shear deformation shell theory. The von Karman nonlinear strain-displacement relationship and the elastic foundation are also included. The nonlinear partial differential equations for GRMMC laminated cylindrical panels are solved by means of a singular perturbation technique in associate with a two-step perturbation approach and in the solution process the boundary layer effect is considered. The results of numerical investigations reveal that the thermal post-buckling strength for (0/90)_5T GRMMC laminated cylindrical panels can be enhanced with an FG-X pattern. The thermal post-buckling load-deflection curve of 6-layer (0/90/0)_S and (0/90)_3T panels of FG-X pattern are higher than those of 10-layer (0/90/0/90/0)_S and (0/90)_5T panels of FG-X pattern.

• Composites Research
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• v.32 no.5
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• pp.229-236
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• 2019

In this study, the effects of the additional processing parameters on the mechanical properties of thermoplastic composites fabricated with automated fiber placement (AFP) were evaluated. Annealing and vacuum bag only processes were then performed on the manufactured thermoplastic composites, respectively. For verification, the crystallinity was measured by differential scanning calorimetry (DSC), confirming the variation of semi-crystalline thermoplastic composite according to the process conditions. The void content of thermoplastic composites was evaluated by matrix digestion method while microscopic examination confirmed the porosity distribution. The interlaminar shear strength test was conducted for three different process parameters (VBO, annealing, and no treatment). A comparison of the three tested strengths was made, revealing that the porosity value had larger effect on the mechanical properties of the thermoplastic composite compared to the degree of crystallinity. Additionally, when thermoplastic composite melted up, the pores were continuously removed under vacuum process; the removal of the pores resulted in an increase of the interlaminar shear strength.

• Tunnel and Underground Space
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• v.19 no.3
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• pp.213-225
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• 2009

The purpose of the study is to evaluate the effects of chemical weathering on the granite and orthogneiss in Wonju area based on accelerated artificial chemical weathering. The rock samples were scrutinized the variation of index properties and ion exchanges caused by artificial chemical weathering which was implemented with leaching test for 170 days using double soxhlet extractor. The differential weathering and decrease of p wave velocity were obtained by weathering process without significant changes of porosity. In case of granite samples, the uniaxial compression strength was reduced by 20% and 16% for the F-grade and SW-grade, respectively. For MW-grade granite, however, was not able to examine the effect of strength reduction due to lack of sample number. Also, for orthogneiss, it is difficult to compare the values of uniaxial compressive strength between before and after the test because of its strong anisotropy.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.8
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• pp.449-455
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• 2016

This study is a part of research to develop a steel-concrete hybrid girder using ultra high-performance concrete with a compressive strength of 80 MPa. To this end, the Eurocode design formula for the shear resistance developed in a concrete-to-concrete interface was examined for the interface between concrete layers of different strengths. To examine the effect of the surface roughness on the shear resistance, a push-out test was conducted on specimens while considering the parameters of the Eurocode design equation. The actual behavior was evaluated with respect to the compressive strength of the concrete, the reinforcement ratio of the shear rebar, and the interfacial surface condition. The specimen with a rough interface shows 20-50% higher shear strength than that estimated by the design equation. In the case of failure mode, abrupt failure tends to occur at the interface of the concrete layer for the specimen with a low reinforcement ratio. It is expected that the shear strength of the concrete layer will increase according to the strength differential in the concrete layers.

• Journal of the Korean Geosynthetics Society
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• v.4 no.2
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• pp.11-18
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• 2005

A pilot scale filed model test and 2-D numerical analysis was conducted to evaluate the effectiveness of constructing a geogrid-reinforced and pile-supported embankment system over soft ground to reduce differential settlement, and the results are presented hearin. Three-by-three pile groups with varying the space between pile were driven into a layer of soft marine clay and a layer of geogrid was used as reinforcement over each pile group. 2-D numerical analysis has been conducted by using the FLAC-2D(Fast Lagrangian Analysis of Continua) program for same condition of field model test. The settlement, vertical stress, and strain of geogrid due to the construction of embankment were measured at various locations. Based on the field model test and numerical analysis results, pile reinforcement generated the soil arching at the midspan of pile cap and the geogrid reinforcement helps reduce the differential settlement of the soft ground by tensile strength of geogrid. Also for $D/b{\geq}6.0$, the effectiveness of geogrid reinforcement in reducing settlement is negligible.

• Applied Chemistry for Engineering
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• v.20 no.4
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• pp.459-463
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• 2009

In this study, physical properties of poly(vinyl acetate-co-ethylene) (VAE) emulsion were investigated by adding different amounts of di-butyl phthalate (DBP) which is a common plasticizer of VAE. The glass transition temperature $(T_g)$ of the dried plasticized VAE emulsion film, which measured by Differential Scanning Calorimeter, was decreased with increasing the DBP contents while the viscosity of the plasticized VAE emulsion was increased with the DBP contents. These results suggest that the plasticizer in the dried VAE film can prevent the strong interaction between chains, resulted by the decrease of $T_g$. In the emulsion, however, the particle sizes were swelled by the penetration of plasticizers and then its viscosity increased with the DBP content. When the DBP was added, the mechanical properties of the plasticized VAE films, such as tensile strength, elongation and creep resistance, were decreased while the water resistance was increased.

• Polymer(Korea)
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• v.31 no.1
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• pp.31-36
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• 2007

It has been reported that the surface properties of the plasma treated material were changed while maintaining its bulk properties. In this study, surface modification of nylon fiber by plasma treatment was tried to attain high water-repellency Nylon fiber was treated with RF plasma under a vacuum system using various parameters such as gas specious, processing time and processing power. Morphological changes by low pressure plasma treatment were observed using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Moreover, the mechanical and inherent properties were analyzed by tensile strength, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The high water-repellency property of nylon fiber was evaluated by a water-drop standard test under various conditions in terms of aging effect. The results showed that the water-repellency of plasma-surface-treated nylon fiber was greatly improved compared to untreated nylon fiber.

• Journal of the Korean earth science society
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• v.30 no.1
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• pp.58-68
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• 2009

Three-dimensional distributions of longwave radiation flux for the April-September 1998 period are generated from radiative transfer calculations using the GEWEX Asian Monsoon Experiment (GAME) reanalysis temperature and humidity profiles and International Satellite Cloud Climatology Project (ISCCP) cloudiness as inputs to understand the effect of cloud radiative forcing in the monsoon season. By subtracting the heating of the clear atmosphere from the cloudy radiative heating, cloud-induced atmospheric radiative heating has been obtained. Emphasis is placed on the impact of horizontal gradients of the cloud-generated radiative heating on the Asian monsoon. Cloud-induced heating exhibits its maximum heating areas within the Indian Ocean and minimum heating over the Tibetan Plateau, which establishes the north-south oriented differential heating gradient. Considering that the differential heating is a ultimate source generating the atmospheric circulation, the cloud-induced heating gradient established between the Indian Ocean and the Plateau can enhance the strength of the north-south Hadley-type monsoon circulation. Cooling at cloud top and warming at cloud bottom, which are the vertical distributions of cloud-induced heating, can exert on the monsoon circulation by altering the atmospheric stability.