• 제목/요약/키워드: stable ring

검색결과 218건 처리시간 0.02초

Microalga Scenedesmus sp.: A Potential Low-Cost Green Machine for Silver Nanoparticle Synthesis

  • Jena, Jayashree;Pradhan, Nilotpala;Nayak, Rati Ranjan;Dash, Bishnu P.;Sukla, Lala Behari;Panda, Prasanna K.;Mishra, Barada K.
    • Journal of Microbiology and Biotechnology
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    • 제24권4호
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    • pp.522-533
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    • 2014
  • Bionanotechnology has revolutionized nanomaterial synthesis by providing a green synthetic platform using biological systems. Among such biological systems, microalgae have tremendous potential to take up metal ions and produce nanoparticles by a detoxification process. The present study explores the intracellular and extracellular biogenic syntheses of silver nanoparticles (SNPs) using the unicellular green microalga Scenedesmus sp. Biosynthesized SNPs were characterized by AAS, UV-Vis spectroscopy, TEM, XRD, FTIR, DLS, and TGA studies and finally checked for antibacterial activity. Intracellular nanoparticle biosynthesis was initiated by a high rate of $Ag^+$ ion accumulation in the microalgal biomass and subsequent formation of spherical crystalline SNPs (average size, 15-20 nm) due to the biochemical reduction of $Ag^+$ ions. The synthesized nanoparticles were intracellular, as confirmed by the UV-Vis spectra of the outside medium. Furthermore, extracellular synthesis using boiled extract showed the formation of well scattered, highly stable, spherical SNPs with an average size of 5-10 nm. The size and morphology of the nanoparticles were confirmed by TEM. The crystalline nature of the SNPs was evident from the diffraction peaks of XRD and bright circular ring pattern of SAED. FTIR and UV-Vis spectra showed that biomolecules, proteins and peptides, are mainly responsible for the formation and stabilization of SNPs. Furthermore, the synthesized nanoparticles exhibited high antimicrobial activity against pathogenic gram-negative and gram-positive bacteria. Use of such a microalgal system provides a simple, cost-effective alternative template for the biosynthesis of nanomaterials in a large-scale system that could be of great use in biomedical applications.

ZnO-Fe2O3계 Spinel안료에 대한 연구 (Synthesis of Spinel Pigment on ZnO-Fe2O3 System)

  • 이진성;이응상
    • 한국세라믹학회지
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    • 제26권2호
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    • pp.187-194
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    • 1989
  • Synthesis of spinel pigment on ZnO-Fe2O3 system. The object of this research is the synthesis of new spinel pigments on the basic of ZnO-Fe2O3 system which was substituted by ZnO-Fe2O3 by MgO-Al2O3. This research was progressed by measuring the X-ray diffraction and the reflectances of the substitued ZnO-Fe2O3 group. Which was obtained by sintering at the temperature of 1,00$0^{\circ}C$, 1,10$0^{\circ}C$, 1,20$0^{\circ}C$ and 1,25$0^{\circ}C$ and them by regrinding. In order to coloring test, here basic compositions of Barium glaze, Zinc glaze, Lime glaze, Lead glaze and Talc glaze used in this experiment are obtained from the ceramic work. Adding synthetic stains in these basic glazes with 3%, mixing and glazing on the specimen. The specimens was fired at 1,28$0^{\circ}C$ in reducing and oxidizing atmosphere in the gas kiln. The results of the research as follow. 1. Many kinds of spinel pigment was produced on ZnO-Fe2O3 system that is to say, not always only spinel. 2. Spinel peak was observed strongly on the ZnO-Fe2O3 system withsubstituting by MgO-Fe2O3 and MgO-Al2O3 group(the ratio of MgO, Al2O3 being increased, observed more strongly). 3. The most effective temperature ranges was 1,20$0^{\circ}C$~1,25$0^{\circ}C$. 4. The color of spinel pigments on this system was observed by "stable YR". 5. It was yellow red in oxidizing and green in reducing atmosphere on the coloring test.ring test.

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AUTO-GUIDING SYSTEM FOR CQUEAN (CAMERA FOR QUASARS IN EARLY UNIVERSE)

  • Kim, Eun-Bin;Park, Won-Kee;Jeong, Hyeon-Ju;Kim, Jin-Young;Kuehne, John;Kim, Dong-Han;Kim, Han-Geun;Odoms, Peter S.;Chang, Seung-Hyuk;Im, Myung-Shin;Pak, Soo-Jong
    • 천문학회지
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    • 제44권4호
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    • pp.115-123
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    • 2011
  • To perform imaging observations of optically red objects such as high redshift quasars and brown dwarfs, the Center for the Exploration of the Origin of the Universe (CEOU) recently developed an optical CCD camera, Camera for QUasars in EArly uNiverse (CQUEAN), which is sensitive at 0.7-1.1 ${\mu}m$. To enable observations with long exposures, we develop an auto-guiding system for CQUEAN. This system consists of an off-axis mirror, a baffle, a CCD camera, a motor and a differential decelerator. To increase the number of available guiding stars, we design a rotating mechanism for the off-axis guiding camera. The guiding field can be scanned along the 10 arcmin ring offset from the optical axis of the telescope. Combined with the auto-guiding software of the McDonald Observatory, we confirm that a stable image can be obtained with an exposure time as long as 1200 seconds.

배전자동화시스템 통신서비스를 위한 이중화 통신망 보호절체 알고리즘 연구 (A Study on the Protection Switching Mechanism for Distribution Automation System Ethernet Networks Service of Distribution Automation System)

  • 유남철;김재동;오재곤
    • 전기학회논문지
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    • 제62권6호
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    • pp.744-749
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    • 2013
  • The protection switching technology is widely adopted in the fiber-optical transmission equipments based on TDM(Time Division Multiplexing), such as PDH, SDH/SONET. A variety of protection switching algorithms for Ethernet networks and the progress of standardization are summarized in the document. There are several kinds of protection switching algorithms for Ethernet networks, such as STP, RSTP, MSTP and etc. However, since Ethernet signal move through detour route, it causes much time to recover. Accordingly, it is difficult to secure a usability of Ethernet networks and QOS(Quality of Service). Also, if the protection switching protocol standardized by IEEE and ITU-T is used, it remains a inherent network switching time for protection. Therefore, a specific protection switching algorithm for Ethernet are needed for seamless and stable operation of Ethernet networks service for Distribution Automation System(DAS). A reliable protection algorithm with no switching delay time is very important to implement Self-healing service for DAS. This study of FPGA based protection switching algorithm for Ethernet networks shows that in case of faults occurrence on distribution power network, immediate fault isolation and restoration are conducted through interaction with distribution equipments using P2P(Peer to Peer) communication for protection coordination. It is concluded that FPGA based protection switching algorithm for Ethernet networks available 0ms switching time is crucial technology to secure reliability of DAS.

Nitrobenzene을 guest로 포접한 3차원 금속착체 포접화합물의 결정구조 (Crystal Structure of the Three-Dimensional Metal Complex Inclusion Compound Clathrated Nitrobenzene Guest)

  • 박기민;박상윤;이욱;이와모토 토시타케
    • 대한화학회지
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    • 제40권7호
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    • pp.509-514
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    • 1996
  • 3차원 금속착체 포접화합물 $Cd(pn)Ni(CN)_4{\cdot}0.5NO_2C_6H_5$(pn: 1,2-diaminopropane=propylenediamine)은 사방정계 공간군 $Pn2_1$a로, a=13.868(5), b=26.591(4), c=7.840(1)${\AA}$, V=2891(1)${\AA}^3$, Z=4이며, 28000개의 독립적인 회절반점에 대한 R값은 0.054이다. 이 포접화합물의 host구조는 가지 달린 지방족 guest 분자를 포접한 포접화합물의 host 구조(T-type)와 같다. Nitrobenzene guest 분자는 T-type의 nodal형 턴넬속에 안정하게 포접되는데, 이는 node 위치체 pn-amino group이 놓이고, antinode 위치에 부피가 큰 방향조 고리가 놓이며, 이들 사이에 극성인 nitro group이 있기 때문이다. 턴넬형의 포접골간을 갖는 금속착체 $Cd(pn)Ni(CN)_4$의 host 구조가 가지 달린 방향족 guest 분자를 포접하고 있다.

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Angiogenesis Inhibitor Derived from Angiostatin Active Sites

  • Park, Kyoung-Soo;Lim, Dong-Yeol;Park, Sang-Don;Kim, Min-Young;Kim, Yang-Mee
    • Bulletin of the Korean Chemical Society
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    • 제25권9호
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    • pp.1331-1335
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    • 2004
  • Angiogenesis is essential for the growth and persistence of solid tumors. Their metastases, anti-angiogenesis could lead to the suppression of tumor growth. One of the main strategies of cancer treatment is developing molecules of anti-angiogenic activity. In this study, two angiogenic inhibitors, Ang3 (KLFDF) and Ang4 (XLFDF) derived from KLYDY, which is the sequence of angiostatin active sites kringle 5, were designed and synthesized. Previously we reported the activities and structures of two inhibitors, Ang1 (KLYDY) and Ang2 (KLWDF). In order to investigate the effect of Phe substitution, Ang3 was designed with a sequence of KLFDF. In order to reduce conformational flexibility of side chain in Lys, Ang4 was designed with a sequence of XLFDF, where X has amino substituted phenyl ring. Solution structures of those inhibitors were investigated using NMR spectroscopy and their activities as angiogenesis inhibitors were studied. Ang1 and Ang2 show angiogenic activities, while Ang3 and Ang4 have no activities and have extended structures compared to Ang1 and Ang2. Therefore, Phe rings do not have effective hydrophobic interactions with other aromatic residues in Ang3 and Ang4. The representative structure of Ang2 has a stable intramolecular hydrogen bond. Therefore, intramolecular hydrogen bonding might be more important in stabilizing the structure than the hydrophobic interactions in these inhibitors. More rigid structure, which can be expected to have higher activities and better match with the receptor bound conformations, can be obtained with a constrained cyclic structure. Further peptidomimetic approaches should be tried to develop angiogenesis inhibitors.

리포익산을 함유한 PNIPAM 하이드로젤의 제조 (Preparation of PNIPAM Hydrogel Containing Lipoic Acid)

  • 윤혜리;이종휘
    • 폴리머
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    • 제36권4호
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    • pp.455-460
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    • 2012
  • Poly(N-isopropylacrylamide)(PNIPAM)는 체온과 비슷한 온도에서 부피상 변화 혹은 온도 감응성 팽윤 거동의 특성을 보여 약물전달시스템에서 중요하게 연구되고 있다. 그러나 PNIPAM의 친수성 특징 때문에 소수성 약물을 그 네트워크 안에 고르게 넣기는 쉽지 않다. 항산화제인 알파 리포익산은 개환중합으로 고분자화(polylipoic acid, PLA) 될 수는 있으나, 분자량이 낮고 분해되기 쉬워 고분자 재료로 사용되기에는 어려움이 많다. 이러한 결점들을 극복하기 위해 소수성 활성성분인 알파 리포익산을 NIPAM과 반응시켜 안정적인 하이드로젤을 만들었다. 단순한 혼합과 가열에 의한 라디칼 반응으로 하이드로젤(PNIPAM/PLA)이 성공적으로 만들어졌고, 이를 DSC, FTIR, Raman spectroscopy를 통해서 확인하였다. PNIPAM/PLA는 온도 감응성 특성을 보여주며, 리포익산의 함량이 증가할수록 부피팽창 정도는 감소하였다. 이러한 하이드로젤을 사용하여 PNIPAM에 소수성 약물을 쉽게 담지할 수 있고 리포익산은 항산화제로 효과가 있어, 본 하이드로젤은 최종 약물전달체로서도 유용하다.

Electroplating process for the chip component external electrode

  • Lee, Jun-Ho
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2000년도 추계학술발표회 초록집
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    • pp.1-2
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    • 2000
  • In chip plating, several parameters must be taken into consideration. Current density, solution concentration, pH, solution temperature, components volume, chip and media ratio, barrel geometrical shape were most likely found to have an effect to the process yields. The 3 types of barrels utilized in chip plating industry are the onventional rotating barrel, vibrational barrel(vibarrel), and the centrifugal type. Conventional rotating barrel is a close type and is commonly used. The components inside the barrel are circulated by the barrel's rotation at a horizontal axis. Process yield has known to have higher thickness deviation. The vibrational barrel is an open type which offers a wide exposure to electrolyte resulting to a stable thickness deviation. It rotates in a vertical axis coupled with multi-vibration action to facilitate mixed up and easy transportation of components. The centrifugal barrel has its plated work centrifugally compacted against the cathode ring for superior electrical contact with simultaneous rotary motion. This experiment has determined the effect of barrel vibration intensity to the plating thickness distribution. The procedures carried out in the experiment involved the overall plating process., cleaning, rinse, Nickel plating, Tin-Lead plating. Plating time was adjusted to meet the required specification. All other parameters were maintained constant. Two trials were performed to confirm the consistency of the result. The thickness data of the experiment conducted showed thatbthe average mean value obtained from higher vibrational intensity is nearer to the standard mean. The distribution curve shown has a narrower specification limits and it has a reduced variation around the target value. Generally, intensity control in vi-barrel facilitates mixed up and easy transportation of components. However, it is desirable to maintain an optimum vibration intensity to prevent solution intrusion into the chips' internal electrode. A cathodic reaction can occur in the interface of the external and internal electrode. 2H20 + e $\rightarrow$M/TEX> 20H + H2.. Hydrogen can penetrate into the body and create pressure which can cause cracks. At high intensity, the chip's motion becomes stronger, its contact between each other is delayed and so plating action is being controlled. However, the strong impact created by its collision can damage the external electrode's structure there by resulting to bad plating condition.

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Investigating the Anatomical and Physical-Mechanical Properties of the 8-Year-Old Superior Teakwood Planted in Muna Island, Indonesia

  • SAVERO, Alvin Muhammad;WAHYUDI, Imam;RAHAYU, Istie Sekartining;YUNIANTI, Andi Detti;ISHIGURI, Futoshi
    • Journal of the Korean Wood Science and Technology
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    • 제48권5호
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    • pp.618-630
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    • 2020
  • Muna teakwood, especially from old stands, has been popular as raw material for timber industries in Indonesia for the past ten decades. Due to the scarcity of this wood, superior-grown seedlings of Muna teakwood have been developed and widely planted. Since there is no information on its characteristics, therefore, the aim of this research was to investigate wood characteristics of the 8-year-old superior-grown teak from Muna Island to ensure their proper utilization as raw material for wooden furniture. Wood discs and boards from basal area of three different trees were used as the samples. Macroscopic and microscopic anatomical characteristics were observed following the IAWA's list, while their physical-mechanical properties were measured following British Standard 373-57. Results showed that anatomical characteristics of this wood sample are similar to regular teakwood, but its heartwood portion is higher. Differences among trees are found in regards to wood texture, growth ring width, as well as early and latewood portion. The green moisture content was lower than that of fast-growing teak of a similar age. The wood is more stable than the old teakwood, but its specific gravity is lower. In general, mechanical properties of this wood were higher than those of the regular fast-growing teakwood, but lower than the old one. Based on its specific gravity, this superior Muna teakwood was categorized as a Strength Class of III. The wood is suitable enough for wooden furniture manufacturing.

울진 소광리 금강소나무림의 송이발생지와 능이발생지의 토양환경 비교 (Comparison to Soil Environment of Tricholoma matsutake and Sarcodon aspratus at Uljin Sokwang-ri Pinus densiflora for. erecta Uyeki Forest)

  • 허태철;주성현
    • Current Research on Agriculture and Life Sciences
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    • 제20권
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    • pp.77-82
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    • 2002
  • This study was carried out in order to produce useful material for the forest multiple use and forest protection by physico-chemical soil analysis of studied area in Sokwang-ri Forest Genetic Resource Protection Forest which was divided into in standard plots include Tricholoma matsutake and Sarcodon aspratus production forest. The result of physico-chemical soil analysis represented as following. The soil type of T. matsutake production forest was Dry brown forest soil(B1), while on the other hand the soil type of S. aspratus production forest was Moderately moist brown forest soil(B3). Between T. matsutake and S. aspratus production forest did not result in significant changes in soil pH(5.22-5.60) and soil depth(47cm), but available phosphorus, carbon, and nitrogen contents were different results. CN ratio of the fairy ring of T. matsutake was quite lower than that in S. aspratus production forests, which indicated that T. matsutake production forest was built up in the relatively immature soils which contain little organic matter. Generally, it was predicted that Pinus densiflora for. erecta forest succeeded to deciduous tree forest in stable soil environments. To conserve these T. matsutake and S. aspratus production forest, the contents of available phosphorous and exchangeable cation should be increased by continuous soil environment management and it should be established the secondary growth forests of old aged Pinus densiflora for. erecta trees as soon as possible.

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