• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.302-302
• /
• 2011

The binary chalcogenide semiconductor Bi2Se3 is at the center of intensive research on a new state of matter known as topological insulators. It has Dirac point in their band structures with robust surface states that are protected against external perturbations by strong spin-orbit coupling with broken inversion symmetry. Such unique band configurations were confirmed by recent angle-resolved photoelectron emission spectroscopy experiments with an unwanted n-type doping effect, showing a Fermi level shift of about 0.3 eV caused by atomic defects such as Se vacancies. Since the number of defects can be reduced using the molecular beam epitaxy (MBE) method. We have prepared the Bi2Se3 film on noble metal Au(111) and semiconductor Si(111) substrates by MBE method. To characterize the film, we have introduced several surface sensitive techniques including x-ray photoemission electron spectroscopy (XPS) and micro Raman spectroscopy. Also, crystallinity of the film has been confirmed by x-ray diffraction (XRD). Using home-built scanning tunneling microscope, we observed the atomic structure of quintuple layered Bi2Se3 film on Au(111).

• Molecules and Cells
• /
• v.40 no.8
• /
• pp.523-532
• /
• 2017

Functional near-infrared spectroscopy (fNIRS) is a noninvasive optical imaging technique that indirectly assesses neuronal activity by measuring changes in oxygenated and deoxygenated hemoglobin in tissues using near-infrared light. fNIRS has been used not only to investigate cortical activity in healthy human subjects and animals but also to reveal abnormalities in brain function in patients suffering from neurological and psychiatric disorders and in animals that exhibit disease conditions. Because of its safety, quietness, resistance to motion artifacts, and portability, fNIRS has become a tool to complement conventional imaging techniques in measuring hemodynamic responses while a subject performs diverse cognitive and behavioral tasks in test settings that are more ecologically relevant and involve social interaction. In this review, we introduce the basic principles of fNIRS and discuss the application of this technique in human and animal studies.

• Current Optics and Photonics
• /
• v.3 no.2
• /
• pp.150-153
• /
• 2019

Larynx cancer is a potentially terminal and severe type of neck and head cancer in which malignant cells start to grow and spread upwards in the larynx, or voice box. Smoking tobacco, drinking hot beverages and drinking alcohol are the main risk factors for these tumors. In this study, we aimed to develop a precise, accurate and rapid chemometrics assisted Raman spectroscopy method for diagnosis of larynx cancer in deparaffinized tissue samples. In the proposed method, samples were deparaffinized and 20 microns of each tissue were located on a coverslip. Both healthy (n = 13) and cancerous tissues (n = 13) were exposed to a Raman laser (785 nm) and excitations were recorded between wavenumbers of $50{\sim}1500cm^{-1}$. An Orthogonal Partial Least Square algorithm was applied to evaluate the Raman spectrum obtained. Sensitivity and specificity of the proposed method is high enough with the aid of Principal Component Analysis (PCA) to test the whole model. Healthy and cancerous tissues were accurately and precisely clustered. A rapid, easy and precise diagnosis algorithm was developed for larynx cancer. By this method, some useful data about differences in biomolecules of each group (phospholipids, amides, tyrosine, phenylalanine collagen etc.) was also obtained from the spectra. It is claimed that the optimized method has a great potential for clustering and separating tumor tissues from healthy ones. This novel, rapid, precise and objective diagnosis method may be an alternative for the conventional methods in literature for diagnosis of larynx cancer.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.33 no.4
• /
• pp.132-138
• /
• 2023

Doped and undoped-BiVO₄ samples with different elements (Li, Mg) and amounts were synthesized with a hydrothermal method. The synthesized samples were characterized using various techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffusion reflectance spectroscopy (UV-Vis DRS), and photoluminescence (PL) spectroscopy. Photocatalytic activity of the samples was evaluated by measuring the degradation of methyl blue (MB) under visible light irradiation. The results indicated that the incorporation of Mg and Li into BiVO₄ caused lattice distortion, the presence of surface hydroxyl groups, a narrower band gap, and a reduced recombination ratio of photo-induced electron-hole pairs. Notably, the photocatalytic activity of Mg5%-Li5% co-doped BiVO₄ sample exhibited a significant improvement compared to that of undoped BiVO₄ sample.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.5
• /
• pp.1301-1304
• /
• 2010

The Indium modified mesoporous zeolite AlMCM-41 were synthesized by hydrothermal method and characterized by powder X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) techniques. The Knoevenagel condensation of aldehyde with malononitrile or ethyl cyanoacetate was carried out at reflux condition in ethanol by using heterogeneous In/AlMCM-41 catalyst. This method is fast, efficient, easy work-up and eco-friendly to afford the corresponding Knoevenagel adducts. The catalyst was recovered and reused for several cycles with consistent activity.

• Journal of Electrical Engineering and Technology
• /
• v.11 no.6
• /
• pp.1872-1879
• /
• 2016

The techniques to recycle and reuse plastics attract public attention. These public attraction and needs result in improving the recycling technique. However, the identification technique for black plastic wastes still have big problem that the spectrum extracted from near infrared radiation spectroscopy is not clear and is contaminated by noise. To overcome this problem, we apply Raman spectroscopy to extract a clear spectrum of plastic material. In addition, to improve the classification ability of fuzzy Radial Basis Function Neural Networks, we apply supervised learning based clustering method instead of unsupervised clustering method. The conditional fuzzy C-Means clustering method, which is a kind of supervised learning based clustering algorithms, is used to determine the location of radial basis functions. The conditional fuzzy C-Means clustering analyzes the data distribution over input space under the supervision of auxiliary information. The auxiliary information is defined by using k Nearest Neighbor approach.

• Electronics and Telecommunications Trends
• /
• v.33 no.3
• /
• pp.59-69
• /
• 2018

Terahertz (THz) imaging and spectroscopy have been developed as non-destructive testing methods for various industrial applications. However, they have not been widely adopted in real applications owing to a high system price and the large size of conventional THz time-domain spectroscopy systems, which are based on ultrashort optical pulse lasers. Recently, various types of compact THz emitters and detectors have become available. As a result, THz non-destructive test (NDT) systems have become viable solutions. Herein, we briefly review the recent advances in THz NDT techniques adopting continuous-wave THz systems, including our recent results of a THz-based waterproof test system and an electrical connection inspection system for car manufacturing.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
• /
• 2001.06a
• /
• pp.1022-1022
• /
• 2001

To obtain accurate and repeatable analyses using NIR technology it is important to select an NIR instrument and / or its sample presentation attachments which allow the operator to minimize sampling errors without compromising the benefits of NIR analysis -namely rapid, low cost, minimal sample preparation, minimal structural facilities, minimal hazards. For each sample type and consistency there may be different optimal combinations of instrument, sample presentation attachment, and sample preparation. This paper will consider options available to NIR users in the area of plant and soil analysis and evaluate the potential benefits and disadvantages of crop nutrient diagnoses using laboratory based and airborne imaging techniques.

• Transactions on Electrical and Electronic Materials
• /
• v.15 no.4
• /
• pp.221-225
• /
• 2014

Although gold wire bonding techniques have already matured in semiconductor manufacturing, weakly bonded wires in semiconductor chip assembly can jeopardize the reliability of the final product. In this paper, weakly bonded or failed aluminum bonding pads are analyzed using X-ray photoelectron spectroscopy (XPS), Auger electron Spectroscopy (AES), and energy dispersive X-ray analysis (EDX) to investigate potential contaminants on the bond pad. We found the source of contaminants is related to the dry etching process in the previous manufacturing step, and fluorocarbon plasma etching of a passivation layer showed meaningful evidence of the formation of fluorinated by-products of $AlF_x$ on the bond pads. Surface analysis of the contaminated aluminum layer revealed the presence of fluorinated compounds $AlOF_x$, $Al(OF)_x$, $Al(OH)_x$, and $CF_x$.

• Journal of the Korean Magnetic Resonance Society
• /
• v.10 no.1
• /
• pp.38-45
• /
• 2006

The NMR and MS techniques were applied to identification and quantitative analysis of oligomers in a commercialized poly (trimethylene terephthalate). Oligomers in a commercialized poly (trimethylene terephthalate) were extracted via a dissolving and reprecipitation method. Analysis of the components of the extract using NMR and MS revealed that it contained mainly cyclic oligomers with degrees of polymerization of 2, 4 and 5 (dimer, tetramer and pentamer). Trimer and cyclic oligomers with degrees of polymerization of more than 6 were not found in the extract in the present study. Quantitative analysis of dimer was performed by NMR spectroscopy.