• Title/Summary/Keyword: specific surface

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Influence of Initial Water Content, Specific Surface, Air Drying and Freezing-thawing Action on the Liquid Limit of Soils (초기함수비, 비표면적, 풍건 및 동결.융해작용이 흙의 액성한계에 미치는 영향)

  • 류능환
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.5
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    • pp.116-124
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    • 1996
  • The purpose of The work described in this paper is to clear up the initial moisture content, specific surface, air drying and freezing-thawing process on liquid limit of clayey soils distributed widely at estuary of three main rivers in the west coast. To this end, a series of tests were conducted on clayey soils samples with natural state and treated state. From the test results, the liquid limit was decreased with decrement of initial moisture content, air drying process, and freezing-thawing cycles and increased with increment of specific surface. The specific surface which influenced on the liquid limit is over $25 m^2$m$^2$/g, and their relationships are well formulated. Air drying process is expected to improve the engineering properties of the soils such the pro-water properties were changed to anti-water proper-ties through lowering of water holding as resulted to incline from A-7-5 to A-5 on the soil classificaction plastic chart. The freezing-thawing process decreased 20% of liquid limit, especially under the first cycle of the behavious, as a result of above mentioned reasons, phase change of soil-water system brought the decrement of specific surface and affected to the liquid limit.

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Study of Specific Oligosaccharide Structures Related with Swine Flu (H1N1) and Avian Flu, and Tamiflu as Their Remedy

  • Yoo, Eun-Sun
    • Journal of Microbiology and Biotechnology
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    • v.21 no.5
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    • pp.449-454
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    • 2011
  • The infection of pandemic influenza viruses such as swine flu (H1N1) and avian flu viruses to the host cells is related to the following two factors: First, the surface protein such as HA (hemagglutinin) and NA (neuraminidase) of the influenza virus. Second, the specific structure of the oligosaccharide [sialic acid(${\alpha}2$-6) galactose(${\beta}1$-4)glucose or sialic acid(${\alpha}2$-3)galactose(${\beta}1$-4)glucose] on the host cell. After recognizing the specific structure of the oligosaccharide on the surface of host cells by the surface protein of the influenza virus, the influenza virus can secrete sialidase and cleave the sialic acid attached on the final position of the specific structure of the oligosaccharide on the surface of host cells. Tamiflu (oseltamivir), known as a remedy of swine flu, has a saccharide analog structure, especially the sialic acid analog. Tamiflu can inhibit the invasion of influenza viruses (swine flu and avian flu viruses) into the host cells by competition with sialic acid on the terminal position of the specific oligosaccharide on the surface of the host cell. Because of the emergence of Tamiflu resistance, the development of new potent anti-influenza inhibitors is needed. The inhibitors with positive-charge groups have potential as antiviral therapeutics, and the strain specificity must also be resolved.

Electrochemical Properties of EDLC Electrodes with Diverse Graphene Flake Sizes (그래핀 플레이크 크기에 따른 전기 이중층 커패시터용 전극의 전기화학적 특성)

  • Yu, Hye-Ryeon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.112-116
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    • 2018
  • Electric double layer capacitors (EDLCs) are promising candidates for energy storage devices in electronic applications. An EDLC yields high power density but has low specific capacitance. Carbon material is used in EDLCs owing to its large specific surface area, large pore volume, and good mechanical stability. Consequently, the use of carbon materials for EDLC electrodes has attracted considerable research interest. In this paper, in order to evaluate the electrochemical performance, graphene is used as an EDLC electrode with flake sizes of 3, 12, and 60 nm. The surface characteristic and electrochemical properties of graphene were investigated using SEM, BET, and cyclic voltammetry. The specific capacitance of the graphene based EDLC was measured in a 1 M $TEABF_4/ACN$ electrolyte at the scan rates of 2, 10, and 50 mV/s. The 3 nm graphene electrode had the highest specific capacitance (68.9 F/g) compared to other samples. This result was attributed to graphene's large surface area and meso-pore volume. Therefore, large surface area and meso-pore volume effectively enhances the specific capacitance of EDLCs.

Preparation of Porous Glasses by the Phase-separation of the Silicate Glass Containing $TiO_2$ ($TiO_2$를 함유한 규산염 유리의 상분리를 이용한 다공질 유리의 제조)

  • 김병훈;최석진;박태철
    • Journal of the Korean Ceramic Society
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    • v.28 no.1
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    • pp.29-36
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    • 1991
  • Microporous glasses in the system TiO2-SiO2-Al2O3-B2O3-CaO-Na2O were prepared by the phase-separation technique. Morphology and distribution of pore and specific surface area of glasses heated and leached out at various conditions were investigated by SEM and Porosimeter. Crystallization of glasses heated above transition temperature was also inspected by X-ray diffraction method. When the heating temperature and time increased, the pore size and volume increased, but the specific surface area decreased above the critical temperature. The phase-separation, specific surface area and pore size showed more sensitive change on the variation of heating temperature than of heating time. The specific surface area and micropore volume of porous glasses prepared in this study were about 120-330$m^2$/g and 0.001-0.01cc/g, respectively. Mean pore size of porous glasses were about 20-90$\AA$. Anatase phases was deposited when the parent glass was heat-treated at 75$0^{\circ}C$ for 6hrs.

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Adsorption Characteristics of Endo Ⅱ and Exo Ⅱ Purified from Trichoderma viride on Microcrystalline Celluloses with Different Surface Area

  • 김동원;정영규;장영훈;이재국
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.498-503
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    • 1995
  • The adsorption behaviors of two major components purified, endo Ⅱ and exo Ⅱ, from Trichoderma viride were investigated using microcrystalline cellulose with different specific surface area as substrates. Adsorption was found to apparently obey the Langmuir isotherm and the thermodynamic parameters, ΔH, ΔS, and ΔG, were calculated from adsorption equilibrium constant,K. The adsorption process was found to be endothermic and an adsorption entropy-controlled reaction. The amount of adsorption of cellulase components increased with specific surface area and decreased with temperature and varied with a change in composition of the cellulase components. The maximum synergistic degradation occurred at the specific weight ratio of the cellulase components at which the maximum affinity of cellulase components obtains. The adsorption entropy and enthalpy for respective enzyme system increased with specific surface area increase. The adsorption entropy was shown to have a larger value with enzyme mixture.

Synthesis and Characterization of High Surface Area of Zirconia: Effect of pH (고비표면적 지르코니움 산화물의 제조 및 특성 분석: pH 영향)

  • Jeong, Ye-Seul;Shin, Chae-Ho
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.133-141
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    • 2019
  • High specific surface area zirconia with acid-basic property was synthesized by precipitation using reflux method or hydrothermal synthesis method using ammonium hydroxide solution as precipitant in the range of pH of Zr solution from 2 to 10. The prepared zirconia was characterized by the nitrogen adsorption, X-ray diffraction (XRD), isopropanol temperature programmed desorption (IPA-TPD), scanning electron microscopy and X-ray photoelectron spectroscopy, and the catalytic activity in the IPA decomposition reaction was correlated with the acid-basic properties. When using reflux method, high pH of Zr solution was required to obtain high fraction of tetragonal zirconia, and pure tetragonal zirconia was possible at pH 9 or higher. High pH was required to obtain high specific surface area zirconia, and the hydrous zirconia synthesized at pH 10 had high specific surface area zirconia of $260m^2g^{-1}$ even after calcination at $600^{\circ}C$. However, hydrothermal synthesis with high pressure under the same conditions resulted in very low specific surface area below $40m^2g^{-1}$ and monoclinic phase zirconia was synthesized. High pH of the solution was required to obtain high specific surface area tetragonal phase zirconia. In hydrothermal synthesis requiring high pressure, monoclinic zirconia was produced irrespective of the pH of the solution, and the specific surface area was relatively low. Zirconia with high specific surface area and tetragonal phase was predominantly acidic compared to basicity and only propylene, which was observed as selective dehydration reaction in IPA decomposition reaction, was produced.

Full-scale Case Study on the Relationship between Surface Characteristics of GAC and TOC Removal (입상활성탄의 표면특성과 TOC제거와의 상관성 연구)

  • Baek, Youngae;Joe, Woohyun;Hong, Byungeui;Kim, Kwangho;Choi, Young-june
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.323-328
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    • 2008
  • During the full-scale water treatment operation at "G" Water Treatment Plant in Seoul, we investigated changes in pore volume distribution and specific surface area of GAC with time. The pore volume of the used GAC decreased to the level below 0.6 cc/g while that of the brand new GAC was ranged 0.7~0.9 cc/g. The specific surface area of GAC pores changed within the range between $1100{\sim}1200m^2/g$ and $700{\sim}800m^2/g$. Bacteria attached to the surface of GAC shows a gradual increase ($0.4{\time}10^6{\sim}8.5{\time}10^6CFU/g$) under scanninig electron microscope (SEM). TOC removal was enhanced due to growth of the attached bacteria on GAC. It was found that TOC removal was closely related with physical parameters (pore volume, specific surface area) linearly under the investigated conditions. The used GAC need to be exchanged into new one or re-generated to remove organic matters (TOC) effectively from the finished drinking water.

Surface Functionalization of Carbon Fiber for High-Performance Fibrous Supercapacitor (고성능 섬유형 슈퍼커패시터를 위한 탄소섬유의 표면 기능화)

  • Lee, Young-Geun;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.32 no.2
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    • pp.107-113
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    • 2022
  • Fibrous supercapacitors (FSs), owing to their high power density, good safety characteristic, and high flexibility, have recently been in the spotlight as energy storage devices for wearable electronics. However, despite these advantages, FCs face many challenges related to their active material of carbon fiber (CF). CF has low surface area and poor wettability between electrode and electrolyte, which result in low capacitance and poor long-term stability at high current densities. To overcome these limits, fibrous supercapacitors made using surface-activated CF (FS-SACF) are here suggested; these materials have improved specific surface area and better wettability, obtained by introducing porous structure and oxygen-containing functional groups on the CF surface, respectively, through surface engineering. The FS-SACF shows an improved ion diffusion coefficient and better electrochemical performance, including high specific capacity of 223.6 mF cm-2 at current density of 10 ㎂ cm-2, high-rate performance of 171.2 mF cm-2 at current density of 50.0 ㎂ cm-2, and remarkable, ultrafast cycling stability (96.2 % after 1,000 cycles at current density of 250.0 ㎂ cm-2). The excellent electrochemical performance is definitely due to the effects of surface functionalization on CF, leading to improved specific surface area and superior ion diffusion capability.

A Study On Extracting Surface-Specific Point Using The Cross Section of The Terrain (지형 단면을 이용한 의미점 추출에 관한 연구)

  • Ryoo, Seung-Taek;Yoon, Kyoung-Hyun
    • Journal of Korean Society for Geospatial Information Science
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    • v.6 no.2 s.12
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    • pp.133-141
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    • 1998
  • Terrain modelling is composed of a method using the rectangular grid and another using the triangulated irregular network. The method using the triangulated irregular network is most widely used because it can express the characteristics of the terrain well with only a small amount of information on the terrain and also reduces the rendering time. The process of extracting the surface-specific point and a triangular process is needed to construct such triangulated irregular network. This paper concentrates on the process of extracting the surface-specific point. The 8-direction neighborhood method and other transformed methods of the former method are frequently used to extract the surface-specific point. Another method which eliminates the unnecessary points using the Polygon reduction method is also suggested However, the 8-direction neighborhood method has a big fault of also drawing out some unnecessary points. To resolve such problem, we suggest a method of extracting the surface-specific point using the cross section of the terrain. This method reduces the time to extract the surface-specific point and enables a more precise extraction with less terrain information.

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Study on the Enhanced Specific Surface Area of Mesoporous Titania by Annealing Time Control: Gas Sensing Property (열처리 시간에 따른 메조기공 타이타니아의 비표면적 향상 연구: 가스센싱 특성 변화)

  • Hong, M.-H.;Park, Ch.-S.;Park, H.-H.
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.2
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    • pp.21-26
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    • 2015
  • Mesoporous ceramic materials were applied in various fields such as adsorbent and gas sensor because of low thermal conductivity and high specific surface area properties. This structure could be divided into open-pore structure and closed-pore structure. Although closed-pore structure mesoporous ceramic materials have higher mechanical property than open-pore structure, it has a restriction on the application because the increase of specific surface area is limited. So, in this work, specific surface area of closed-pore structure $TiO_2$ was increased by anneal time. As increased annealing time, crystallization and grain growth of $TiO_2$ skeleton structured material in mesoporous structure induced a collapse and agglomeration of pores. Through this pore structural change, pore connectivity and specific surface area could be enhanced. After anneal for 24 hrs, porosity was decreased from 36.3% to 34.1%, but specific surface area was increased from $48m^2/g$ to $156m^2/g$. CO gas sensitivity was also increased by about 7.4 times due to an increase of specific surface area.