• 제목/요약/키워드: soot oxidation

검색결과 89건 처리시간 0.022초

DPF내 포집된 입자상 물질의 산화율 산출을 위한 실험적 연구 (Experimental Study on Estimation of Oxidation Rate of PM inside of Diesel Particulate Filter)

  • 심범주;박경석;조규희;이형준;민병두
    • 한국자동차공학회논문집
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    • 제21권2호
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    • pp.98-103
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    • 2013
  • Conventional method to estimate mass of particulate matter accumulated in diesel particulate filter is to use pressure difference between upstream and downstream of the filter. Then measured pressure difference should be compared that of clean condition which is no particulate matter accumulated in DPF. During regeneration soot oxidation is also estimated by same method. This methodology, however, has demerit on accuracy because of pressure difference deviation of clean DPFs and pressure difference caused by non-carbon based PM which is different from that of caused by carbon based PM. This study suggests new methodology to estimate accumulated soot oxidation rate through exhaust gas characteristics during regeneration. Results, more high accuracy of soot oxidation was obtained by analysis of relationship between fuel mass and concentration of carbon dioxide and oxygen.

동층류 축대칭 확산화염내의 화염구조 및 매연입자 분포의 예측 (Predictions on the Flame Structure and Soot Distribution in the Coflowing Laminar Diffusion Flames)

  • 이정기;김상수
    • 대한기계학회논문집
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    • 제16권8호
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    • pp.1583-1594
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    • 1992
  • 본 연구에서는 동층류 축대칭 확산화염에서 이전까지의 화염해석 방법들을 면 밀히 고찰하여 층류 확산화염 방식의 연소문제를 해결하는데 있어서 접근이 용이하고 타당성을 가지는 화염해석 방법을 찾아내는데 있으며 매연 입자에 관한 생성및 산화모 델을 총체적으로 연결하여 실험결과와의 비교를 통해 적절한 모델인수를 결정하며 복 사효과와 열영동효과를 고려하여 화염해석과 화염내의 매연입자의 분포를 예측하는데 있다.

DPF 재생을 위한 버너-산화촉매 복합 적용 (Combined Application of Burner and Oxidation Catalyst for Diesel Particulate Filter Regeneration)

  • 심성훈;정상현
    • 한국연소학회지
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    • 제15권3호
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    • pp.25-31
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    • 2010
  • Combined technique of burner and DOC has been used for regeneration of Diesel Particulate Filter. Experiments has been performed to increase the temperature of engine exhaust gas to burn the collected soot in DPF at all conditions of operation of 3 liter diesel engine. Ignition temperature of soot can be successfully obtained by heats of burner flame and residual fuel oxidation at diesel oxidation catalyst even in the condition of oxygen deficiency. It is found that the load of air compressor and heat loss can be reduced to the level of practical application. It is also found that CO and THC emissions are not increase by additional combustion of regeneration burner.

$C_2H_4$/Air 비예혼합 난류화염의 매연생성 모델링 (Numerical Modeling of Soot Formation in $C_2H_4$/Air Turbulent Non-premixed Flames)

  • 김태훈;우민호;김용모
    • 한국연소학회지
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    • 제15권4호
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    • pp.22-28
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    • 2010
  • The Direct Quadrature Method of Moments (DQMOM) has been presented for the solution of population balance equation in the wide range of the multi-phase flows. This method has the inherently interesting features which can be easily applied to the multi-inner variable equation. In addition, DQMOM is capable of easily coupling the gas phase with the discrete phases while it requires the relatively low computational cost. Soot inception, subsequent aggregation, surface growth and oxidation are described through a population balance model solved with the DQMOM for soot formation. This approach is also able to represent the evolution of the soot particle size distribution. The turbulence-chemistry interaction is represented by the laminar flamelet model together with the presumed PDF approach and the spherical harmonic P-1 approximation is adopted to account for the radiative heat transfer.

에틸렌 층류 확산화염의 복사경계조건에 따른 매연생성 및 산화특성 (Soot Formation and Oxidation of an Ethylene Laminar Diffusion Flame with Different Radiation Boundary Conditions)

  • 이춘범;남연우;이원남;신현동
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.11-18
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    • 2003
  • The soot formation and oxidation characteristics with different radiation boundary conditions have been studied experimentally in a co-flow ethylene/air laminar diffusion flame. The boundary conditions are two cases, one is a fully refractive radiation boundary condition by a polished aluminum cylinder(AL) and the other is a fully absorbing radiation boundary condition by a black body cylinder(BB). The AL case compared with BB condition show the lower inception point, denser soot volume fraction, wider and longer annular soot area owing to the reabsorption of radiating energy.

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인버스 확산화염에서의 나노 수트 입자 생성 (Nano-Soot Particle Formation in Inverse Diffusion Flames)

  • 이의주;신현준;오광철;신현동
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.19-26
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    • 2003
  • Experimental measurements of flame structure and soot characteristics were performed for ethene inverse diffusion flames (IDF). IDF has been considered as the excellent flow field to study the incipient soot because soot particle do not experience the oxidation process. In this study, LIF image clarified the reaction zone of IDF with OH signal and PAH distribution. laser light scattering technique also identified the being of soot particle. To address the degree of soot maturing, C/H ratio and morphology of soot sample were investigated. From these measurements, the effect of flow residence time and temperature on soot inception could be suggested, and more details on soot characteristic in the IDF was determined according to fuel dilution and flame condition. The fuel dilution results in a decrease of temperature and enhancement of residence time, but the critical dilution mole fraction is existed for temperature not to effect on soot growth. Also, the soot inception evolved on the specific temperature and its morphology are independent of the fuel dilution ratio of fuel.

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대향류 에틸렌/공기 비예혼합 화염의 구조 및 Soot 생성 메커니즘 해석 (Numerical Analysis for the Detailed Structure and the Soot Formation Mechanism in Counterflow Ethylene-Air Nonpremixed Flame)

  • 임효준;김후중;김용모
    • 한국자동차공학회논문집
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    • 제7권5호
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    • pp.40-54
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    • 1999
  • The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

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측정방법에 따른 에틸렌 확산화염의 온도분포;열전대 및 이색법 측정 결과 비교 (Temperature Distribution in Ethylene Diffusion Flames Based on Measurement Techniques;Comparison of Thermocouple and Tow-Color Pyrometry)

  • 이원남;나용대;이범기;박승남
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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    • pp.175-182
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    • 2000
  • Flame temperatures were measured and compared using a rapid insertion technique and a two-color pyrometry with Abel inversion process in co-flow ethylene diffusion flames. The measured line-of-sight temperature showed very limited usefulness in understanding the detailed soot formation/oxidation process in a co-flow diffusion flame. The flame temperatures could be measured with reasonable accuracy for the soot laden regions in ethylene diffusion flames using two-color pyrometry with an Abel inversion technique. Two-color-pyrometry with Abel inversion was demonstrated as a useful temperature measurement technique for co-flow diffusion flames, expecially under pressure conditions, where a thermocouple is not applicable. The soot volume fraction could be also obtained using tow-color pyrometry with Abel inversion, which provides important information for understanding the soot formation/oxidation mechanism in diffusion flames.

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DC 코로나 방전이 적용된 에틸렌 정상 확산 화염의 Soot 배출 저감 (Reduction of Soot Emitted from a $C_2$$H_4$ Normal Diffusion Flame with Application of DC Corona Discharge)

  • 이재복;황정호
    • 대한기계학회논문집B
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    • 제25권4호
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    • pp.496-506
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    • 2001
  • The effect of corona discharge on soot emission was experimentally investigated. Size and number concentrations of soot aggregates were measured and compared for various voltages. Regardless of the polarity of the applied voltage, the flame length decreased and the tip of flame spreaded with increasing voltage. For the experimental conditions selected, the flame was blown off toward the ground electrode by corona ionic wind. When the negative applied voltage was greater than 3kV(for electrode spacing = 3.5cm), soot particles in inception or growth region were affected by the corona discharge, resulting in the reduction of number concentration. The results show that the ionic wind favored soot oxidation and increased flame temperature. Number concentration and primary particle size greatly increased, when the corona electrodes were located the region of soot nucleation or growth(close to burner mouth).

백금담지 알루미나 촉매와 오존 산화제 동시 적용에 의한 탄소 입자상 물질의 저온 산화반응 (Simultaneous Application of Platinum-Supported Alumina Catalyst and Ozone Oxidant for Low-temperature Oxidation of Soot)

  • 이진수;이대원
    • Korean Chemical Engineering Research
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    • 제56권5호
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    • pp.752-760
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    • 2018
  • 경유자동차에서 배출되는 탄소 입자상 물질 연소 온도구간을 낮추는 것은 미세먼지 배출 저감과 내연기관 자동차의 고연비 저배출 성능 구현이라는 측면에서 매우 중요한 기술적 과제 중 하나이다. 본 논문에서는 탄소 입자상 물질의 산화를 위해 오존을 산화제로 이용하고 백금계 산화촉매를 동시에 적용했을 때 관찰되는 $150^{\circ}C$ 부근 저온영역에서의 탄소 입자상 물질 연소반응에 관하여 논했다. 백금계 산화촉매를 적용했을 때 오존에 의한 탄소 입자상 물질의 산화속도를 크게 개선시키지 못했지만 연소반응의 이산화탄소 선택도를 향상시켰으며, 탄소 입자상 물질의 선택적 산화를 위해 고려된 NO의 $NO_2$로의 사전 전환($NO_2$-rich 조건)은 $NO_2$와 오존의 상호 상승작용에 의해 $150^{\circ}C$ 부근 온도영역에서의 탄소상 입자물질 연소성능을 높이는데 효과가 있었다.