대향류 에틸렌/공기 비예혼합 화염의 구조 및 Soot 생성 메커니즘 해석

Numerical Analysis for the Detailed Structure and the Soot Formation Mechanism in Counterflow Ethylene-Air Nonpremixed Flame

  • 발행 : 1999.06.01

초록

The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

키워드

참고문헌

  1. Springer Series in Chemical Physics v.59 in Soot Formation Combustion, Mechanisms and Models Frenklach, M.;Wang, H.;Bockhorn, H.(ed)
  2. Springer Series in Chemical Physics v.59 Mechanisma and Models Mauss, F.;Trilken, B.;Breitbach, H.;Peters, N.;Bockhorn, H.(ed)
  3. Springer Series in Chemical Physics v.59 Mechanisma and Models Lindstedt, R.P.;Bockhorn, H.(ed)
  4. Springer Series in Chemical Physics v.59 Mechanisma and Models Colket, M.B.;Hall, R. J.;Bockhorn, H.(ed)
  5. AIAA Journal v.29 no.9 Kennedy, I.;Kollmann, W.;Chen, Y.
  6. Twenty-Second Symposium International) on Combustion Moss, J.B.;Stewart, C.D.;Syed, K.J.
  7. Twenty-Third Symposium (International) on Combustion Frenklach, M.;Wang, H.
  8. Combust. Flame v.87 Leung, K. M.;Lindstedt, R.P;Jones, W.P.
  9. Combust. Sci. Technol. v.39 Vandsburger, U.;Kennedy, I.;Glassman, I.
  10. Ph. D. Thesis, RWTH-Aachen Entwicklung eines kinetischen Modells der Russbildung mit schneller Polymerisation Mauss, F.
  11. Twenty-Sixth Symposium (International) on Combustion Wang, H.;Du, D.X.;Sung, C.J.;Law, C.K.
  12. Combust. Flame v.107 kennedy, I.M;Yam, C.;Rapp, D.C.;Santoro, R.J.
  13. presented at The International Gas Turbine & Aeroengine Congress & Exhibition Tolpadi, A. K.;Danis, A.M.;Mongia, H.C.;Lindstedt, R.P
  14. Combust. Flame v.47 Kent, J. H.;Wagner, H.G.
  15. Combustion Theory Williams, F.A.
  16. Sandia report, SAND86-8209 v.UC-4 Glarborg, P.;Kee, R. J.;Grcar, J.F.;Miller, J.A.
  17. Journal of Computational Physics v.68 Giovangigli, V.;Smooke, M.D.
  18. Combust. Sci. and Tech. v.53 Giovangigli, V.;Smooke, M.D.
  19. Combust. flame v.110 Wang, H.;Frenklach, M.
  20. Presented at Twenty-Seventh Symposium (International) on Combustion Bai, X.S.;Balthasar, M.;Mauss, F.;Fuchs, L.
  21. Combust. and Flame v.6 Lee, K.B.;Thring, M.W.;Beer, J.M.
  22. J. Combust. Flame v.79 Garo, A.;Prado, G.;Lahaye, J.
  23. Sandia Report SAND87-8215 The CHEMKIN Thermodynamic Data Base Kee, R.K.;Rupley, R.J.;Miller, J.A.
  24. Combust. and Flame v.100 Kazakov, A.;Wang, H.;Frenklach, M.
  25. The Laminar Flame and Flamelet Code(User Manual) Rogg, B.;Wang, W.;RUN-IDL
  26. J. Phys. Chem v.84 Tanzawa, T.;W.C. Gardiner, J.
  27. Particulate Carbon formation During Combustion Neoh, K.G.;Howard, J.B.;Sarofim, A. F.
  28. Sandia National laboratory SAND85-8240 Kee, R.J.;Crcar, J.F.;Smooke, M.D.;Miller, J.A.
  29. MAEROS User manual, Sandia SAND80-0822 Gelbard, F.
  30. Journal of the Mechanical Engineering and Technology Research Institute v.4 no.1 Lim, H.J.;Kim, Y.M.
  31. J. Colloid Interface Sci. v.118 Frenklach, M.;Harris, S. J.
  32. Combust. Flame v.109 Soot Zone Structure and Sooting Limit in Diffusion Flames: Comparison of Counterflow and Coflow Flames Kang, K.T.;Hwang, J.Y.;Chung, S.H.;Lee, W.
  33. Combust. Flame v.114 Synergistic Effect of Ethylene-Propane Mixture on Soot Formation in Laminar Diffusion Flames Hwang, J.Y.;Lee, W.;Kangm C.G.;Chung, S.H.
  34. 대한기계학회 추계학술대회 논문집 B 에틸렌 확산 화염의 매연 성장 메커니즘 황준영;정석호