• Title/Summary/Keyword: solutions

Search Result 19,398, Processing Time 0.038 seconds

Rapid Determination of Electroplating Solutions (1) -Copper from Copper Plating Solutions (각종 도금액의 신속분석법 (제 1 보))

  • 염희택
    • Journal of the Korean institute of surface engineering
    • /
    • v.1 no.1
    • /
    • pp.5-13
    • /
    • 1967
  • Up to this date, numerous methods of analysis of electropling solutions are published. Some, however, need lots of works before reaching final results, or require high technique and special instruments, and also some are unaccurate due to unclearnes of end point. Like our undevelop countries, technicians of electroplating shops are most high school graduates or under, and have not much knowledge on chemistry. Furthermore, those technicians have to control their plating solutions by themselves without having enough analytical laboratory equipment . Therefore, in this paper the simplest, besides accurate method is investigated after comparing numerous methods published. Among the methods of copper determinations from acid and alkaline copper plating baths, EDTA titration method are chosen, due to these methods are the simpest and fastest for the evaluation of metal content, without requirng any special instrument. For acid copper solutions, chelate titrations were accurate enough. Since the end point of titration of chelate method is variable according to the kind of indicators and other metal's coexisitence as well as solution component, many difficulties were encountered from cyanide copper, on the contrary of acid copper bath. PAN , PV, and MX indicators were tried , but it is found that MX is the best. In chyanide solution ,due to cyanide is the masking reagent , elimination of this component is essential , and finally found that elimination CN-by precipitation with AgNO$_3$ solution was the simplest and the most accurate way among others. This method was very accurate for the new plating solutions even coexistence with organic brightners. However used solutions for long months running have to be predetermined the accurate copper value by thiosulfate method form time to time, before chelate titration by means of AgNO$_3$ precipitation. Always some constant deviations will be seen according to the solutions nature. Therefore those deviation values have to be compensated each time.

  • PDF

Rheological Properties of Gelatinized Dilute Rice Starch Solutions (쌀전분 희석 호화액의 유동학적 특성)

  • Kim, Young-Sug;Kim, Ju-Bong;Lee, Shin-Young;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
    • /
    • v.16 no.1
    • /
    • pp.11-16
    • /
    • 1984
  • Rheological properties of waxy and non-waxy rice starch solutions were evaluated with a narrow gap rotational and Cannon Fenske viscometers. The gelatinized rice starch solutions containing 0.2-1.0% starch displayed pseudoplastic flow behavior. At higher starch level, degree of pseudoplasticity of waxy rice starch solutions increased, while that of non-waxy rice did not changed apparently. The consistency coefficient (K) of non-waxy rice starch solutions increased with increasing gelatinization temperature, but waxy rice starch solutions remained constant, and in alkaline aqueous solutions both of them showed increasing K values. The value of K increased exponentially with an increase in concentration. The effect of the temperature on the viscosity of the solutions followed Arrhenius' type equation, and the activation energies were in the range of 3.675-3.775 kcal/g-mol that were near to that of pure water. The changes of reduced viscosity with concentration were followed Huggin's equation and the values of intrinsic viscosity and interaction coefficient were 0.78-1.59 dl/g and 0.67-2.75, respectively.

  • PDF

A Study on the Qualitative Differences Analysis between Multiple Solutions in Terms of Mathematical Creativity (수학적 창의성 관점에서 다중해법 간의 질적 차이 분석)

  • Baek, Dong-Hyeon;Lee, Kyeong-Hwa
    • School Mathematics
    • /
    • v.19 no.3
    • /
    • pp.481-494
    • /
    • 2017
  • Tasks of multiple solutions have been said to be suitable for the cultivation of mathematical creativity. However, studies on the fact that multiple solutions presented by students are useful or meaningful, and students' thoughts while finding multiple solutions are very short. In this study, we set goals to confirm the qualitative differences among the multiple solutions presented by the students and, if present, from the viewpoint of mathematical creativity. For this reason, after presenting the set of tasks of the two versions to eight mathematically gifted students of the second-grade middle school, we analyzed qualitative differences that appeared among the solutions. In the study, there was a difference among the solution presented first and the solutions presented later, and qualitatively substantial differences in terms of flexibility and creativity. In this regard, it was concluded that the need to account for such qualitative differences in designing and applying multiple solutions should be considered.

EXISTENCE OF POLYNOMIAL INTEGRATING FACTORS

  • Stallworth, Daniel T.;Roush, Fred W.
    • Kyungpook Mathematical Journal
    • /
    • v.28 no.2
    • /
    • pp.185-196
    • /
    • 1988
  • We study existence of polynomial integrating factors and solutions F(x, y)=c of first order nonlinear differential equations. We characterize the homogeneous case, and give algorithms for finding existence of and a basis for polynomial solutions of linear difference and differential equations and rational solutions or linear differential equations with polynomial coefficients. We relate singularities to nature of the solution. Solution of differential equations in closed form to some degree might be called more an art than a science: The investigator can try a number of methods and for a number of classes of equations these methods always work. In particular integrating factors are tricky to find. An analogous but simpler situation exists for integrating inclosed form, where for instance there exists a criterion for when an exponential integral can be found in closed form. In this paper we make a beginning in several directions on these problems, for 2 variable ordinary differential equations. The case of exact differentials reduces immediately to quadrature. The next step is perhaps that of a polynomial integrating factor, our main study. Here we are able to provide necessary conditions based on related homogeneous equations which probably suffice to decide existence in most cases. As part of our investigations we provide complete algorithms for existence of and finding a basis for polynomial solutions of linear differential and difference equations with polynomial coefficients, also rational solutions for such differential equations. Our goal would be a method for decidability of whether any differential equation Mdx+Mdy=0 with polynomial M, N has algebraic solutions(or an undecidability proof). We reduce the question of all solutions algebraic to singularities but have not yet found a definite procedure to find their type. We begin with general results on the set of all polynomial solutions and integrating factors. Consider a differential equation Mdx+Ndy where M, N are nonreal polynomials in x, y with no common factor. When does there exist an integrating factor u which is (i) polynomial (ii) rational? In case (i) the solution F(x, y)=c will be a polynomial. We assume all functions here are complex analytic polynomial in some open set.

  • PDF

Silver Colloidal Effects on Excited-State Structure and Intramolecular Charge Transfer of p-N,N-dimethylaminobenzoic Acid Aqueous Cyclodextrin Solutions

  • Choe, Jeong Gwan;Kim, Yang Hui;Yun, Min Jung;Lee, Seung Jun;Kim, Gwan;Jeong, Sae Chae
    • Bulletin of the Korean Chemical Society
    • /
    • v.22 no.2
    • /
    • pp.219-227
    • /
    • 2001
  • The silver colloidal effects on the excited-state structure and intramolecular charge transfer (ICT) of p-N,N-dimethylaminobenzoic acid (DMABA) in aqueous cyclodextrin (CD) solutions have been investigated by UV-VIS absorption, steady-state and time-resolved fluorescence, and transient Raman spectroscopy. As the concentration of silver colloids increases, the ratio of the ICT emission to the normal emission (Ia /Ib) of DMABA in the aqueous $\alpha-CD$ solutions are greatly decreased while the Ia /Ib values in the aqueous B-CD solutions are significantly enhanced. It is also noteworthy that the ICT emission maxima are red-shifted by 15-40 nm upon addition of silver colloids, implying that DMABA encapsulated in $\alpha-CD$ or B-CD cavity is exposed to more polar environment. The transient resonance Raman spectra of DMABA in silver colloidal solutions demonstrate that DMABA in the excited-state is desorbed from silver colloidal surfaces as demonstrated by the disappearance of νs (CO2-)(1380 cm-1 ) with appearance of ν(C-OH)(1280 cm -1) band, respectively. Thus, in the aqueous B-CD solutions the carboxylic acid group of DMABA in the excited-state can be readily hydrogen-bonded with the secondary hydroxyl group of B-CD while in aqueous and $\alpha-CD$ solutions the carboxylic acid group of DMABA has the hydrogen-bonding interaction with water. Consequently, in the aqueous B-CD solutions the enhancement of the Ia /Ia value arises from the intermolecular hydrogen-bonding interaction between DMABA and the secondary hydroxyl group of B-CD as well as the lower polarity of the rim of the B-CD cavity compared to bulk water. This is also supported by the increase of the association constant for DMABA/ B-CD complex in the presence of silver colloids.

MULTIPLICITY OF SOLUTIONS AND SOURCE TERMS IN A NONLINEAR PARABOLIC EQUATION UNDER DIRICHLET BOUNDARY CONDITION

  • Choi, Q-Heung;Jin, Zheng-Guo
    • Bulletin of the Korean Mathematical Society
    • /
    • v.37 no.4
    • /
    • pp.697-710
    • /
    • 2000
  • We investigate the existence of solutions of the nonlinear heat equation under Dirichlet boundary conditions on $\Omega$ and periodic condition on the variable t, $Lu-D_tu$+g(u)=f(x, t). We also investigate a relation between multiplicity of solutions and the source terms of the equation.

  • PDF

UNIQUENESS OF POSITIVE SOLUTIONS FOR PREDATOR-PREY INTERACTING SYSTEMS WITH NONLINEAR DIFFUSION RATES

  • Ahn, Inkyung
    • Journal of the Chungcheong Mathematical Society
    • /
    • v.10 no.1
    • /
    • pp.87-95
    • /
    • 1997
  • In general, the positive solution to biological reaction-diffusion equations is not unique. In this paper, we state the sufficient and necessary conditions of the existence of positive solutions, and give and the proof for the uniqueness of positive solutions for a certain elliptic interacting system.

  • PDF

EXISTENCE OF POSITIVE SOLUTIONS FOR THE SECOND ORDER DIFFERENTIAL SYSTEMS WITH STRONGLY COUPLED INTEGRAL BOUNDARY CONDITIONS

  • Lee, Eun Kyoung
    • East Asian mathematical journal
    • /
    • v.34 no.5
    • /
    • pp.651-660
    • /
    • 2018
  • This paper concerned the existence of positive solutions to the second order differential systems with strongly coupled integral boundary value conditions. By using Krasnoselskii fixed point theorem, we prove the existence of positive solutions according to the parameters under the proper nonlinear growth conditions.