• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.49 no.6
• /
• pp.367-374
• /
• 2000

This paper presents a method to fabricate freestanding structures by (100) silicon anisotropic etching and nickel electroless plating. The electroless plating process is simpler than the electroplating, and provides good coating uniformity and improved mechanical properties. Furthermore, the (100) silicon anisotropic etching in KOH solution with being aligned to <100> direction provides vertical (100) sidewalls on etched (100) surface. In this paper, the effects of the nickel electroless plating condition on the properties of electroless plated metal structures are investigated to apply fabrication of micro structures and then various micro structures are fabricated by nickel electroless plating. And then, the structures are released by silicon anisotropic etching in KOH solution with a large gap between the structure and the substrate. The fabricated cantilever structures are $210\mum$. wide, $5\mum$. thick and $15\mum$. over the silicon substrate, and the comb structure has the comb electrodes which are $4\mum$. wide and $4.3\mum$. thick separated by$1\mum$. It is released by silicon anisotropic etching in KOH solution. The gap between the structure and the substrate is $2.5\mum$.

• 제어로봇시스템학회:학술대회논문집
• /
• 2003.10a
• /
• pp.2246-2251
• /
• 2003

This paper proposes shape design of frame structures for vibration suppression and weight reduction. The $H_{\infty}$ norm of the transfer function from disturbance sources to the output points where vibration should be suppressed, is adopted as the performance index to represent the magnitude of vibration transfer. The design parameters are the node positions of the frame structure, on which constraints are imposed so that the structure achieves given tasks. For computation of Pareto optimal solutions to the two-objective design problem, a number of linear combinations of the $H_{\infty}$ norm and the total weight of the structure are considered and minimized. For minimization of the scalared objective function, a Lagrange function is defined by the objective function and the imposed constraints on the design parameters. The solution for which the Lagrange function satisfies the Karush-Kuhn-Tucker condition, is searched by the sequential quadratic programming (SQP) method. Numerical examples are presented to demonstrate the effectiveness of the proposed design method.

• Proceedings of the Earthquake Engineering Society of Korea Conference
• /
• 2002.03a
• /
• pp.125-132
• /
• 2002

In this study, a numerical method is developed for nonlinear analysis for soil-pile-structure interaction system in time domain. Finite elements considering material nonlinearity are used for the near field and boundary elements for the far field. In the near field, frame elements are used for modeling a pile and plane-strain elements for surrounding soil and superstructure. In. the far field, boundary element formulation using the dynamic fundamental solution is adopted and coupled with the near field. Transformation of stiffness matrices of boundary elements into time domain is performed by inverse FFT. Stiffness matrices in the near field and far field are coupled. Newmark direct time integration method is applied. Developed soil-pile-structure interaction analysis method is verified with available literature and commercial code. Also, parametric studies by developed numerical method are performed. And seismic response analysis is performed using actual earthquake records.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.6
• /
• pp.797-801
• /
• 2003

One of the largest challenges for quantum chemistry today is to obtain accurate results for large complex molecular systems, and a variety of approaches have been proposed recently toward this goal. We have developed the ONIOM method, an onion skin-like multi-level method, combining different levels of quantum chemical methods as well as molecular mechanics method. We have been applying the method to many different large systems, including thermochemistry, homogeneous catalysis, stereoselectivity in organic synthesis, solution chemistry, fullerenes and nanochemistry, and biomolecular systems. The method has recently been combined with the polarizable continuum model (ONIOM-PCM), and was also extended for molecular dynamics simulation of solution (ONIOM-XS). In the present article the recent progress in various applications of ONIOM and other electronic structure methods to problems of homogeneous catalyses and nanochemistry is reviewed. Topics include 1. bond energies in large molecular systems, 2. organometallic reactions and homogeneous catalysis, 3. structure, reactivity and bond energies of large organic molecules including fullerenes and nanotubes, and 4. biomolecular structure and enzymatic reaction mechanisms.

• Textile Coloration and Finishing
• /
• v.9 no.1
• /
• pp.23-32
• /
• 1997

Composite membranes having different mixing ratio of Wool(SCMK) and poly(ethylene terephthalate) (PET) were prepared by dissolving wool/PET in hexafluoro-2-propanol(HFIP), casting the obtained solution on a glass plate and evaporation the solvent in the presence and absence of an electric field. The internal structure of the prepared membrane was investigated using polarise microscope dyeing and dye permeation method. In the composite membrane prepared under electric field, both components were micro mixing, while in the membranes prepared under nonelectric field, the two components formed a random sea/island structure according to different mixing ratio. Such characteristic membrane structure was influenced the permeation behavior of C.I. Acid Red 118 through the membranes from an aqueous solution.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2011.04a
• /
• pp.31-35
• /
• 2011

Factors influencing penetration kinetics of PVAm solution into paper were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, number of plies and filler addition and hydrophobicity of paper was varied by adding AKD. Important factors affecting liquid penetration are found to be pore structure and hydrophobicity of paper. Pore structure of paper can be designed by controlling refining degree and filler addition. Hydrophobicity of paper can be controlled by internal sizing.

• Structural Engineering and Mechanics
• /
• v.67 no.3
• /
• pp.311-316
• /
• 2018

Vibration of concrete beams reinforced by agglomerated silicon dioxide ($SiO_2$) nanoparticles is studied based on numerical methods. The structure is simulated by Euler-Bernoulli beam model and the Mori-Tanaka model is used for obtaining the effective material properties of the structure. The concrete beam is located in soil medium which is modeled by spring elements. The motion equations are derived based on energy method and Hamilton's principle. Based on exact solution, the frequency of the structure is calculated. The effects of different parameters such as volume percent of $SiO_2$ nanoparticles and agglomeration, soil medium and geometrical parameters of beam are shown on the frequency of system. The results show that with increasing the volume percent of $SiO_2$ nanoparticles, the frequency increases.

• Membrane Journal
• /
• v.6 no.4
• /
• pp.273-283
• /
• 1996

A cation-exchange membranes were prepared by polystyrene and poly(sodium 4-styrene sulfonate). The degree of crosslinking of polystyrene membranes was controlled by DVB. At the same time, the structure of PS membranes was changed from RO to MF by varying the concentration of PSS in the casting solution. Water flux increased with PS-PSS membranes due to the sulfonate groups, and final membrane cast from the solution containing 5% of DVB and 3% of PSS showed MF structure.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1997.04b
• /
• pp.34-35
• /
• 1997

The phase inversion is a significant phenomena in the preparation of membranes and wet spinning. In both these processes, a viscous dope solution is precipitated in a nonsolvent bath and a porous structure is formed under certain conditions. Such structure could have been considered as a diffusion controlled process. The membrane formation of the polymer solution includes both phase separation and gelation. We have studied the influence of variables on the final structure and tried to control the porosity and ultrafiltration(UF) performance of the polyacrylonitrile(PAN) and its copolymer.

• Bulletin of the Korean Chemical Society
• /
• v.16 no.2
• /
• pp.120-125
• /
• 1995

Solid solutions of Pr2-xBaxNiO4±δ with K2NiF4-type structure were prepared in air and characterized by powder X-ray diffraction, Rietveld refinements, iodometry titrations, and conductivity measurements. The range of the solid solution was 0 ≤ x < 0.5. The crystal structure changes from orthorhombic (Fmmm) for x ≤ 0.1 to pseudo-tetragonal (I4/mmm) for x ≥ 0.2. The orthorhombic structure of x=0.1 transforms to tetragonal at low temperature. The bond distances obtained from the Rietvel analyses did not vary significantly with the Ba content except that of Ni-O (parallel to the c-axis) which showed an abrupt increase from x=0.1 to 0.2. The excess oxygen content (δ) decreases from 0.241 to 0.03 with increasing substituted Ba contents within the solution range. The samples are all semiconductors at the temperature range 4 < T < 300 K.