• 제목/요약/키워드: solid salt

검색결과 292건 처리시간 0.024초

염 절임동안에 일어나는 무조직의 유변학적인 변화 (Change in rheological properties of radish during salting)

  • 김병용;조재선
    • Applied Biological Chemistry
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    • 제35권5호
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    • pp.399-403
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    • 1992
  • 무의 염절임 과정에서 일어나는 염의 침투와 관련하여 무의 응력완화 변화를 측정하고 점탄성의 변화를 제시하였다. 침지 염용액의 농도와 침지온도가 증가할수록 염의 확산은 더 잘 일어났으나 염용액의 온도에 따른 염의 침투 정도는 낮은 염용액의 농도에 의해서 더 많은 영향을 미쳤다. 염장하지 않은 무의 높은 조직의 강도와 점탄성은 염용액의 온도를 증가시킴에 따라 초기 응력에 대한 조직의 강도약화를 보여 주었으며 응력완화의 정도도 빨라졌고 평형상태에서 잔여응력 양도 감소하였다. 또한 염용액의 농도가 증가할수록 무 조직의 응력완화정도와 잔존응력양의 변화가 거의 일치함을 보였다. 염용액의 온도와 농도를 증가시킴에 따라 염절인 무조직의 점탄성 성분들도 낮아졌는데, 온도에 따른 무의 점탄성의 낮아지는 정도는 염침투나 초기응력과 마찬가지로 낮은 염용액의 농도에서 더 많은 영향을 받았다.

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Salt Distiller With Mesh-covered Crucible for Electrorefiner Uranium Deposits

  • Kwon, S.W.;Lee, Y.S.;Kang, H.B.;Jung, J.H.;Chang, J.H.;Kim, S.H.;Lee, S.J.
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2017년도 춘계학술논문요약집
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    • pp.83-83
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    • 2017
  • Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. The solid cathode processing is necessary to separate the salt from the cathode since the uranium deposit in a solid cathode contains electrolyte salt. Distillation process was employed for the cathode processing. It is very important to increase the throughput of the salt separation system due to the high uranium content of spent nuclear fuel and high salt fraction of uranium dendrites. In this study, a mesh-covered crucible was investigated for the sat distillation of electrorefiner uranium deposits. A liquid salt separation step and a vacuum distillation step were combined for salt separation. The adhered salt in uranium deposits was efficiently removed in the mesh-covered crucible. The salt distiller was operated simply since repeated cooling - heating step was not necessary for the change of the crucible. The operation time could be reduced by the use of the mesh-covered crucible and the combined operation of the two steps. A method to preserve a vacuum level was proposed by double O-rings during the operation of the distiller with the mesh-covered crucible. After the salt distillation, the salt content was measured and was below 0.1wt% after the salt distillation. The residual salt after the salt distillation can be removed further during melting of uranium metal.

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Characterization of the Aroma of Salt-fermented Anchovy Sauce Using Solid Phase Microextraction-Gas Chromatography-Olfactometry Based on Sample Dilution Analysis

  • Kim, Hyung-Joo;Baek, Hyung-Hee
    • Food Science and Biotechnology
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    • 제14권2호
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    • pp.238-241
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    • 2005
  • Aroma-active compounds were evaluated from salt-fermented anchovy sauce by solid phase microextraction-gas chromatography-olfactometry (SPME-GC-O) based on sample dilution analysis (SDA). SPME extract from carboxen/polydimethylsiloxane (CAR/PDMS) fiber was the most similar to the original odor of salt-fermented anchovy sauce used for this experiment, followed by divinylbenzene/CAR/PDMS (DVB/CAR/PDMS) fiber. Because salt-fermented anchovy sauce contains 23% NaCl, NaCl concentration of diluent was considered when salt-fermented anchovy sauce was serially diluted. Linear relationship between GC response and sample concentration was observed when diluted with 23% NaCl solution, whereas not observed when diluted with deodorized distilled water. Eleven and 16 aroma-active compounds were detected by SPME-GC-O based on SDA using CAR/PDMS and DVB/CAR/PDMS fibers, respectively. Butanoic acid and 3-methyl butanoic acid showed the highest ${\log}_2SD$ factors for CAR/PDMS and DVB/CAR/PDMS fibers. Dimethyl trisulfide, methional, trimethyl amine, 1-penten-3-ol, and acetic acid were also detected as potent aroma-active compounds.

Solid-salt pressure-retarded osmosis with exothermic dissolution energy for sustainable electricity production

  • Choi, Wook;Bae, Harim;Ingole, Pravin G.;Lee, Hyung Keun;Kwak, Sung Jo;Jeong, Nam Jo;Park, Soon-Chul;Kim, Jong Hak;Lee, Jonghwi;Park, Chul Ho
    • Membrane and Water Treatment
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    • 제6권2호
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    • pp.113-126
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    • 2015
  • Salinity gradient power (SGP) systems have strong potential to generate sustainable clean electricity for 24 hours. Here, we introduce a solid-salt pressure-retarded osmosis (PRO) system using crystal salt powders rather than seawater. Solid salts have advantages such as a small storage volume, controllable solubility, high Gibbs dissolution energy, and a single type of water intake, low pretreatment costs. The power densities with 3 M draw solutions were $11W/m^2$ with exothermic energy and $8.9W/m^2$ without at 35 bar using a HTI FO membrane (water permeability $A=0.375L\;m^{-2}h^{-1}bar^{-1}$). These empirical power densities are ~13% of the theoretical value.

Salt-Induced Protein Precipitation in Aqueous Solution: Single and Binary Protein Systems

  • Kim, Sang-Gon;Bae, Young-Chan
    • Macromolecular Research
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    • 제11권1호
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    • pp.53-61
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    • 2003
  • A molecular-thermodynamic model is developed for the salt-induced protein precipitation. The protein molecules interact through four intermolecular potentials. An equation of state is derived based on the statistical mechanical perturbation theory with the modified Chiew's equation for the fluid phase, Young's equation for the solid phase as the reference system and a perturbation based on the protein-protein effective two body potential. The equation of state provides an expression for the chemical potential of the protein. In a single protein system, the phase separation is represented by fluid-fluid equilibria. The precipitation behaviors are simulated with the partition coefficient at various salt concentrations and degree of pre-aggregation effect for the protein particles. In a binary protein system, we regard the system as a fluid-solid phase equilibrium. At equilibrium, we compute the reduced osmotic pressure-composition diagram in the diverse protein size difference and salt concentrations.

Residual salt separation technique using centrifugal force for pyroprocessing

  • Kim, Sung-Wook;Lee, Jong Kwang;Ryu, Dongseok;Jeon, Min Ku;Hong, Sun-Seok;Heo, Dong Hyun;Choi, Eun-Young
    • Nuclear Engineering and Technology
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    • 제50권7호
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    • pp.1184-1189
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    • 2018
  • Pyroprocessing uses various molten salts during electrochemical unit processes. Reaction products after the electrochemical processes must contain a significant amount of residual salts to be separated. Vacuum distillation is a common method to separate the residual salts; however, its high operation temperature may cause side reactions. In this study, a simple rotation technique using centrifugal force was suggested to separate the residual salts from the reaction products at relatively low temperature compared to the distillation technique. When a reaction product container with porous wall rotates inside a vessel heated above the melting point of the residual salt, the residual salt in the liquid phase is separated through centrifugal force. It was shown that the $LiNO_3-Al_2O_3$ mixture can be separated by this technique to leave solid $Al_2O_3$ inside the container, with a separation efficiency of 99.4%.

고체-고체-기체 화학 열펌프 시스템의 반응기 설계에 관한 연구 (A Study on the Reactor Design of Solid-Solid-Gas Chemical Heat Pump System)

  • 김성준;이태희;;최홍규;이종호
    • 설비공학논문집
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    • 제6권4호
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    • pp.406-416
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    • 1994
  • In this study the reactor design procedure and method of solid-solid-gas chemical heat pump system using STELF technology were investigated. For manufacturing IMPEX block which is the kernel of reactor, proper salt pair should be selected, and equilibrium temperature drop and COP should be examined for selected salt pair. Moreover, apparent density, residual porosity, and graphite ratio should be calculated to give minimum block volume and mass, and maximum energy density without causing heat and mass transfer problems. Since heat exchange area can be changed with operating condition, reactor diameter, length, and stainless steel thickness should be decided for desired specifications. These procedure and method were applied to the case study of 6kW cold production and 8 hours storage capacity reactor.

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Effects of Salt Addition in Sugar Based Osmotic Dehydration on Mass Transfer and Browning Reaction of Carrots

  • Chang, Moon-Jeong;Han, Myung-Ryun;Kim, Myung-Hwan
    • Preventive Nutrition and Food Science
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    • 제8권3호
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    • pp.230-234
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    • 2003
  • Mass transfer characteristics during osmotic dehydration of carrots were studied as functions of immersion temperature and time, and sugar and salt concentrations. The effect of osmotic dehydration on the degree of browning of air-dried carrots was also evaluated. Increasing the immersion temperature and time, sugar concentration, and salt addition increased water loss, sugar gain, molality and rate of dehydration. The water loss and increases in solids, and molality were rapid in the beginning of the process and then increased slowly during remainder of the process. Increasing 1 or 2% salt concentration in the 40$^{\circ}$Brix sugar solution at 6$0^{\circ}C$ increased water loss and solid gain. Salt addition was not able to significantly affected on water loss and solid gain compare to temperature (40~8$0^{\circ}C$) and sugar concentration (20~60$^{\circ}$Brix) changes due to the low salt concentration. A minimum degree of browning of the air-dried carrots (O.D. = 0.048) could be achieved using binary solutions (40$^{\circ}$Brix sugar solution with 2% salt addition) with 24 min of immersion time compared to control (O.D. = 1.308) or blanching with 24 min of immersion time (O.D. = 0.174).

Spherical Granule Production from Micronized Saltwort (Salicornia herbacea) Powder as Salt Substitute

  • Shin, Myung-Gon;Lee, Gyu-Hee
    • Preventive Nutrition and Food Science
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    • 제18권1호
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    • pp.60-66
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    • 2013
  • The whole saltwort plant (Salicornia herbacea) was micronized to develop the table salt substitute. The micronized powder was mixed with distilled water and made into a spherical granule by using the fluid-bed coater (SGMPDW). The SGMPDW had superior flowability to powder; however, it had low dispersibility. To increase the dispersibility of SGMPDW, the micronized powder was mixed with the solution, which contained various soluble solid contents of saltwort aqueous extract (SAE), and made into a spherical granule (SGMPSAE). The SGMPSAE prepared with the higher percentages of solid content of SAE showed improved dispersibility in water and an increase in salty taste. The SGMPSAE prepared with 10% SAE was shown to possess the best physicochemical properties and its relative saltiness compared to NaCl (0.39). In conclusion, SGMPSAEs can be used as a table salt substitute and a functional food material with enhanced absorptivity and convenience.

고-액 분리법을 이용한 LCC 도가니에서의 카드뮴 회수에 관한 연구 (A Study of Cadmium Recovery from LCC Crucible Using Solid-liquid Separation Method)

  • 박대엽;김택진;김지용;김경량;김시형;심준보;백승우;안도희
    • 공학기술논문지
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    • 제4권4호
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    • pp.431-436
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    • 2011
  • This study was carried out to reduce the problem during distillation process, which separate U, TRU (TRans Uranium) metal electro deposit, Cd and LiCl-KCl eutectic salt generating from LCC (Liquid Cadmium Cathode) electro winning process. The cadmium recovering apparatus was manufactured to separate for each metal using solid-liquid separation method. The apparatus consists of the first sieve for the separation of U and TRU metal electrodeposit, the second sieve for the separation of LiCl-KCl eutectic salt, cadmium collection basket, and a heating furnace. In addition, the size of each sieve is 2 mm to 3 mm. In this experiment, a metal wire was employed to replace TRU metal electrodeposit and U, which exist actually in a LCC crucible. In the solid state, The LiCl-KCl is separated at 340℃ at which the solid and the liquid of the remaining cadmium and LiCl-KCl eutectic salt coexists in each, after the metal wire separated at 500℃. As a result, it seems that it would be beneficial to set the processing condition in the distillation process with the additional treatment process of cadmium and LiCl-KCl eutectic salt.