• Title/Summary/Keyword: solid content

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Curing Reaction and Physical Properties of High-Solid Acrylic/Isocyanate Coatings (하이솔리드 아크릴/이소시아네이트 도료의 경화반응과 도막물성)

  • Park, Hong-Soo;Shim, Il-Woo;Jo, Hye-Jin;Kim, Seong-Kil;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.4
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    • pp.371-378
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    • 2005
  • In the previous study, three kinds of monomers and the functional monomer, acetoacetoxyethyl methacrylate (AAEM), which could improve the film property and cross-linkage, were polymerzied into acrylic resin copolymers (HSA-98-20, HSA-98-0, HSA-98+20) containing 80% solid content. In this study, the high-solid coatings(HSA-98-20C, HSA-98-0C, HSA-98+20C) were prepared by the curing reaction between acrylic resins containing 80% solid content and isocyanate at room temperature. Various properties were examined for the film coated with the prepared high-solid coatings. The introduction of AAEM in the coatings enhanced the abrasion resistance and solvent resistance of coatings, which indicated the possible use of high-solid coatings for top-coating materials of automobile. The curing times measured by viscoelastic measurement were 350, 264, and 212 min for HSA-98-20C, HSA-98-0C, and HSA-98+20C, respectively. This shows that the curing times become shorter with increasing $T_g$ values.

Structure and Elastic Properties of (Nb1-xTax)C, (Nb1-xHfx)C, Ultra-High Temperature Solid Solution Ceramics using the First Principles Calculation (제1원리계산을 이용한 (Nb1-xTax)C, (Nb1-xHfx)C 초고온 세라믹 고용체의 구조 및 탄성특성)

  • Kim, Myungjae;Kim, Jiwoo;Kim, Jiwoong;Kim, Kyung-Nam
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.682-689
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    • 2021
  • NbC, HfC, TaC, and their solid solution ceramics have been identified as the best materials for ultrahigh-temperature ceramics. However, their structural stability and elastic properties are mostly unclear. Thus, we investigated structure and elastic properties of (Nb1-xTax)C and (Nb1-xHfx)C solid solutions via ab initio calculations. Our calculated results show that the stability of (Nb1-xTax)C and (Nb1-xHfx)C increases with the increase of Hf and Ta content, and (Nb1-xHfx)C is more stable than (Nb1-xTax)C at the same content of Hf and Ta. The lattice constants decrease with increasing of Hf and Ta content. (Nb1-xTax)C and (Nb1-xHfx)C carbides are mechanically stable and brittle. Bulk modulus of (Nb1-xTax)C increases with increasing Ta content. In contrast, bulk modulus of (Nb1-xHfx)C decreases with increasing Hf content. Hardness of solid solutions shows the highest values at the (Nb0.25Ta0.75)C and (Nb0.75Hf0.25)C. In particular, (Nb0.75Hf0.25)C shows the highest hardness for the current system. The results indicate that the overall mechanical properties of (Nb1-xHfx)C solid solutions are superior to those of (Nb1-xTax)C solid solutions. Therefore, controlling the Hf and Ta element and content of the (Nb1-xTax)C and (Nb1-xHfx)C Solid solution is crucial for optimizing the material properties.

Solid Bioenergy Properties of Paulownia tomentosa Grown in Korea

  • Qi, Yue;Yang, Chunmei;Hidayat, Wahyu;Jang, Jae-Hyuk;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.6
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    • pp.890-896
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    • 2016
  • Paulownia tomentosa is one of fast-growing wood species in Korea. In order to evaluate the solid bioenergy properties of Paulownia tree, this study examined the heating value, moisture content (MC), pH and proximate analysis of stem, branch, root, bark and leaf. The heating values of wood parts were slightly higher than those of bark and leaf, and that of branch was the highest among all the samples. The higher moisture content of bark and leaf referred to their lower heating value. Also, the pH of stem, branch and root was similar and lower than those of bark and leaf. The ash content of bark and leaf was much higher than that of wood parts, which is the one of the reasons for effect on the lower heating value and higher pH. While, the volatile matter content (VMC) of bark and leaf was lower than those of wood parts. The bark showed the highest fixed carbon content (FCC), while the FCC of stem was the lowest among all the samples. The obtained results are encouraging that the Paulownia tree could be totally utilized as alternative fuels for bioenergy production.

Feasibility of RF Sensor Application for On-line Monitoring of Tomato Paste Processing (토마토 패이스트 가공공정의 온라인 모니터링용 RF 센서의 활용 가능성)

  • Kim, Seong-Min;Garvey, Casey;Leary, Thomas;McCarthy, Michael
    • Journal of Biosystems Engineering
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    • v.33 no.6
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    • pp.410-415
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    • 2008
  • On-line monitoring of fresh tomato paste processing was done using two radio frequency (RF) sensors resonant at 85 and 110 MHz. Fresh tomato juice with soluble solid content of about $5^{\circ}Brix$ was evaporated up to $23^{\circ}Brix$ and diluted down to about $5^{\circ}Brix$ again with a pilot scale evaporator. The RF sensors were installed in a processing pipe and monitored. The pastes at a specific $^{\circ}Brix$ level were sampled and analyzed for physical properties such as soluble solid content and viscosity. The relationships between sensor outputs and measured physical properties were analyzed. Analysis results showed RF sensor is feasible to apply on-line monitoring of tomato paste processing.

Composting of Organic Wastes by solid State Fermentation Reactor (Solid State Fermentation Reactor를 이용한 유기성 폐기물의 발효)

  • 홍운표;이신영
    • Microbiology and Biotechnology Letters
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    • v.27 no.4
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    • pp.311-319
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    • 1999
  • Leaves of Aloe vera Linne and bloods of domestic animal were composted in a soild state fermentation reactor (SSFR) by using microbial additive including a bulking and moisture controlling agent. From solid-culture of microbial additive, 10 species of bacteria and 10 species of fungi were isolated and, their enzyme activities including amylase, carboxy methyl cellulase CMCase, lipase and protease were detected. Optimum fermentation conditions of Aloe leaves and domestic animal bloods in SSFR were obtained from the studies of response surface analysis employing microbial additive content, initial moisture content, and fermentation temperature as the independent variables. The optimum conditions for SSFR using Aloe leaves were obtained at 9.45$\pm$73%(w/w) of microbial additives, 62.73$\pm$4.54%(w/w) of initial moisture content and 55.32$\pm$3.14$^{\circ}C$ of fermentation temperature while those for SSFR using domestic animal bloods were obtained at 10.25$\pm$2.04%, 58.68$\pm$4.97% and 57.85$\pm$5.$65^{\circ}C$, respectively. Composting process in SSFR was initially proceeded through fermentation and solid materials were decomposed within 24 hours by maintaining higher moisture level, and maturing and drying steps are followed later. After the fermentation step, the concentrations of solid phase inorganic components were increased while that of organic components were decreased. Also, concentrations of total organic carbon(TOC), peptides, amino acids, polysaccharides, and low fatty acids in water extracts were increased. As fermentation in composting process depends on initial C/N ratios in water extracts of two samples were increased because of increased water-soluble TOC. From these results, it was revealed that solid state fermentation reactor using microbial additives can be used in composting process of organic wastes with broad C/N ratio.

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Effects of Organic Content on Anaerobic Biodegradability of Sludge Generating from Slaughterhouse

  • Oh, Seung-Yong;Kim, Ho;Kim, Chang-Hyun;Kim, Seung-Hwan;Yoon, Young-Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.4
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    • pp.296-302
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    • 2013
  • This study was carried out to investigate the effect of organic content level on ultimate methane potential and anaerobic biodegradability of substrate by biochemical methane potential assay. Three organic matters (whole sludge and liquid and solid fraction of sludge) of the same origin, which had different organic contents, were fermented at the batch anaerobic reactor for 70 days. Ultimate methane potential and anaerobic biodegradability were determined by the terms of volatile solid (VS) and chemical oxygen demand (COD). Volatile solid contents of whole sludge and solid and liquid fraction of sludge were 2.4, 18.8, and 0.2% and COD were 5.3, 30.4, and 0.5%, respectively. Ultimate methane potentials ($B_u$-COD) and anaerobic biodegradability ($D_{VS}$) determined by VS content were $0.5Nm^3kg^{-1}-VS_{added}$, 76.3% for whole sludge, $0.5Nm^3kg^{-1}-VS_{added}$, 76.3% for the liquid fraction of sludge, and $0.6Nm^3kg^{-1}-VS_{added}$, 77.0% for the solid fraction of sludge. Ultimate methane potentials ($B_u$-COD) and anaerobic biodegradability ($D_{COD}$) determined by COD were $0.2Nm^3kg^{-1}-COD_{added}$, 73.4% for whole sludge, $0.2Nm^3kg^{-1}-VS_{added}$, 74.0% for the liquid fraction of sludge, and $0.33Nm^3kg^{-1}-COD_{added}$, 99.1% for the solid fraction of sludge. In conclusion, ultimate methane potential and anaerobic biodegradability given by the VS term showed more reasonable results because COD might be underestimated by the interference of $NH_4{^+}$ in the case of highly concentrated organic material.

A Development of the Stabilization Technology for the Solid Form of Radioactive Waste (방사성폐기물 아스팔트 고화체 안정화 특성연구)

  • 김태국;이영희;이강무;안섬진;손종식
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.202-206
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    • 2003
  • In this study, a modified bituminization technology has been developed, which needs no grinding of the granular resin waste, and enables the solid form to keep its shape stability as good as that of a cemented solid from Also, the study intended to apply the developed technology to the practical treatment of radioactive resin waste. In the experiment, the granular type resin was used and the straight-run distillation bitumen with penetration rate 60/70 was used as the solidifying agent. The PE was used as the additive. The shape stability increased remarkably with the additive of PE, which act as a binder in the solid form. The shape of the solid form was maintained without failure during the long-term exposure test when the additive content of spent PE is more than 10wt%. The proper ranges of bitumen content, PE content and operating temperature are 30-50wt%, 10-20wt% and $180^{\circ}C$ respectively. The bituminized solid form of radioactive resin waste by the technology of this study has the remarkably superior quality than the conventional solid forms, partially for the shape stability.

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The Effects of Skin Contact Time and Suspended Solid on The White Wine Quality (Skin Contact와 Suspended Solid가 백포도주 품질에 미치는 영향)

  • Rho, Tae-Uk;Kim, Chanjo;Sung, Chang;Moon, Youngja;Kim, Bong-Nan;Oh, Manjin
    • Korean Journal of Agricultural Science
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    • v.24 no.2
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    • pp.290-297
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    • 1997
  • Danored is considered as the most favorable grape variety for national wine manufacturing in terms of sugar, organic acid contents, annual production amount, as well as quality control convenience after harvest. This study was canied out to know the influence of suspended solid(SS) and skin contact time(SCT) with Danored variety on the white wine quality. The results are summarized as follows; 1. Suspended solid and skin contact time did not greatly influence on the chemical composition of Danored juice. But skin contact time provided slightly increaseness to the content of phenol compounds 2. Suspended solid accelerated fermentation rate of white wine manufacturing. Although the content of suspended solid are less amount than 0.3% in must, wine fermentation was completed to dryness in concentration of sugar. 3. When the content of suspended solid was around 3%, higher alcohol in white wine was increased by the 20%. This result is relatively small increasement compared to the other reported results. 4. Because Danored contained less amount of phenol compounds comparison with other grape varieties, browning capacity in white wine was much favorable to quite low concentration. Especially, phenolic compounds was decreased remarkably as one of fermentation characteristics of Danored variety. 5. As a result of sensory evaluation, wine quality was A-1> B-1> A-2> B-2 in its favorable ranking orders. It was so concluded that A-1 might be the most acceptable one from this study.

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Degradation of All-Solid-State Lithium-Sulfur Batteries with PEO-Based Composite Electrolyte

  • Lee, Jongkwan;Heo, Kookjin;Song, Young-Woong;Hwang, Dahee;Kim, Min-Young;Jeong, Hyejeong;Shin, Dong-Chan;Lim, Jinsub
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.199-207
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    • 2022
  • Lithium-sulfur batteries (LSBs) have emerged as a promising alternative to lithium-ion batteries (LIBs) owing to their high energy density and economic viability. In addition, all-solid-state LSBs, which use solid-state electrolytes, have been proposed to overcome the polysulfide shuttle effect while improving safety. However, the high interfacial resistance and poor ionic conductivity exhibited by the electrode and solid-state electrolytes, respectively, are significant challenges in the development of these LSBs. Herein, we apply a poly (ethylene oxide) (PEO)-based composite solid-state electrolyte with oxide Li7La3Zr2O12 (LLZO) solid-state electrolyte in an all-solid-state LSB to overcome these challenges. We use an electrochemical method to evaluate the degradation of the all-solid-state LSB in accordance with the carbon content and loading weight within the cathode. The all-solid-state LSB, with sulfur-carbon content in a ratio of 3:3, exhibited a high initial discharge capacity (1386 mAh g-1), poor C-rate performance, and capacity retention of less than 50%. The all-solid-state LSB with a high loading weight exhibited a poor overall electrochemical performance. The factors influencing the electrochemical performance degradation were revealed through systematic analysis.

Automation of Solid-state Bioreactor for Oyster Mushroom Composting

  • Lee, Ho-Yong;Kim, Won-Rok;Min, Bong-Hee
    • Mycobiology
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    • v.30 no.4
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    • pp.228-232
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    • 2002
  • This study focused on the production of high quality compost for the growth of aero-thermophilic fungi, which has a promoting effect on the growth rate and production of oyster mushrooms. The automated solid-state bioreactor system was designed on the basis of a Three-Phase-One system, which controls the serial steps of prewetting, pasteurization and fermentation processes. High numbers of thermophilic fungi and bacteria were recovered from the mushroom composts prepared by this solid-state bioreactor. The rates of composting process were depended on physical as well as chemical factors. Among these factors, the parameters of moisture content and temperature were found to be particularly important. In our automated system, constant levels of moisture content, temperature and ventilation via mixing were provided by a centralized control apparatus including PLC, water tank and water jacket systems. These features induced higher microbiological activity of aero-thermophiles.