• Journal of IKEEE
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• v.22 no.4
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• pp.965-969
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• 2018

In the dye-sensitized solar cell, the semiconductor oxide plays an important role in the generation and transport of electrons, and thus extensive research on this has been continuously carried out. In this study, the characteristics of dye-sensitized solar cell are studied by fabricating semiconductor oxide doped with $V_2O_5$. The $TiO_2$ paste with $V_2O_5$ is prepared by the screen printing method of the sol - gel process and the surface and electrical properties are measured. The addition of $V_2O_5$ increased grain size and improved the open circuit voltage, short circuit current, charge factor and conversion efficiency of the dye sensitized solar cell.

• Journal of the Microelectronics and Packaging Society
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• v.25 no.4
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• pp.119-122
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• 2018

Various ZnO/Ag/ZnO multilayers were fabricated and their optical properties were investigated. Top and bottom ZnO layers were formed by sol-gel method and mid-metal layers were deposited by spin coating. To find suitable deposition condition of Ag, we measure thickness and sheet resistance of Ag monolayer. After the optimization of Ag monolayer, we fabricate ZnO/Ag/ZnO multilayers. Transmittance of ZnO/Ag/ZnO multilayers increased to 63%. In near IR region, transmittance of ZnO/Ag/ZnO multilayers decreased to 35% when the concentration of Ag solution was 2.5wt%.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2191-2197
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• 2018

To remove tar and produce environment-friendly $H_2$, one of the promising routes is the sorption-enhanced steam reforming (SESR) process, in which the $CO_2$ sorbent is a key element. We prepared the $CO_2$ sorbents with $Ca_{12}Al_{14}O_{33}$ as carrier with various methods. Their characterizations were examined, and the sample prepared by solgel (SG) method showed the strongest CaO and $Ca_{12}Al_{14}O_{33}$ phases and the most excellent pore structure among all the samples. Then, a thermogravimetric experiment was conducted, and the results showed that the sample prepared by sol-gel (SG) method had the best $CO_2$ adsorption capacity and excellent long-term cyclic stability. Finally, the sorbent was used into the steam reforming experiments of tar. Under the action of the sorbent, the reforming reaction was enhanced in-situ, with the $H_2$ yield and concentration improved obviously, and especially, $H_2$ concentration can reach over 98.85%.

• Journal of the Mineralogical Society of Korea
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• v.10 no.1
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• pp.18-32
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• 1997

Analysis of geological data, relating to occurrence and formation of diamonds as well as host rocks, inclined author to have different outlook on the diamond genesis and to establish a proposition on their formation at pneumatolytic-hydrothermal conditions near superficial Earth zones. Based on that theoretical foundations and experimental works, the first low-pressure and low-temperature hydrothermal diamond synthesis from water solution in pressure autoclave was executed. As a result, the natural diamond seed crystal grew bigger ad coupling of the synthetic diamond single-crystalline grains were obtained. SEM documentation proofs that parallely paragenetic crystallization of quartz and diamond, and nucleation of new octahedral diamond crystals brush take place on the seed crystal surface. Forecast of none times growth of diamond industrial application at 2000 and seventeen times at 2010 with reference to 1995, needs technology of large and pure single-crystals diamond synthesis. Growth of the stable and destressed diamond single-crystals in the pseudo-metastable diamond plot, may be realized with processes going through the long time and with participation of free radicals catalysts admixtures only. Sol-gel colloidal processes are an example of environment which form stable crystals in thermodynamically unstable conditions through a long time. Paper critically discusses a whole way of studies on the diamond synthesis, from high-pressure and high-temperature processes through chemical vapour deposition up to hydrothermal experiments.

• Journal of the Korean Applied Science and Technology
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• v.40 no.4
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• pp.913-923
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• 2023

In this study, a triboelectric nanogenerator was fabricated using the composite of teflon-based polymer and graphene flower, which are stable in air and have relatively high electronegativity. The composite was used to fabricate an electronegative layer of a nanogenerator using a spin-coating method. For the electropositive layer, a zinc oxide film was prepared using a sol-gel method. The fabricated triboelectric nanogenerator produced a maximum power of about 44 ㎼. In conclusion, since all the active layers of the triboelectric nanogenerator was made by the solution process, it is scalable to a large area.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.4
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• pp.128-135
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• 2022

The inside of a quartz glass crucible for semiconductor processing, called a transparent layer, is manufactured using synthetic silica powder. Bubbles existing in the transparent layer of the crucible cause a problem of reducing the quality of the crucible as well as the yield of the silicon ingot. Therefore, the main goal of the synthetic silica powder, which is the raw material of the transparent layer, is to minimize the bubble generation factor. For this purpose, in the case of synthetic silica powder, it is necessary to minimize silanol groups, carbon and pores. In this study, synthetic silica gel was prepared using the sol-gel method, and changes in carbon content and specific surface area were investigated according to calcination temperature and dwelled time in a two-stage calcination process. The first-stage calcination process was performed between 500℃ and 600℃ and the second-stage calcination process was performed between 1000℃ and 1100℃. The dwelled time was carried out from 10 minutes to a maximum of 12 hours. The carbon content of the powder calcined at 1000℃ for 1 hour was 0.0031 wt.%, and the specific surface area of the powder calcined at 1100℃ for 12 hours was 16.6 m²/g.

• Korean Chemical Engineering Research
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• v.44 no.4
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• pp.399-403
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• 2006

There has been numerous reports for the synthesis of mesoporous $TiO_2$ thin films due to not only the high surface area and regular mesoscale pores but also wide band gap and photo activity. However, the synthesis has been restricted by the limited reproducibility mainly due to the extraordinarily fast hydrolysis and condensation rate of titania precursors. In this report, molar composition of reaction batch (HCl/Ti and Ti/P123) and exterior condition (humidity and temperature) during coating and anealing process. Thereafter, the mesoporous $TiO_2$ thin films were characterized by XRD and TEM

• Journal of Korean Society of Water and Wastewater
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• v.31 no.5
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• pp.373-381
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• 2017

$RuO_2$ is a common active component of Dimensionally Stable Anodes (DSAs) for chlorine evolution that can be used in wastewater treatment systems. The recent improvement of chlorine evolution using nanostructures of $RuO_2$ electrodes to increase the treatment efficiency and reduce the energy consumption of this process has received much attention. In this study, $RuO_2$ nanorod and nanosheet electrodes were simply fabricated using the sol-gel method with organic surfactants as the templates. The obtained $RuO_2$ nanorod and nanosheet electrodes exhibit enhanced electrocatalytic activities for chlorine evolution possibly due to the active surface areas, especially the outer active surface areas, which are attributed to the increase in mass transfers compared with a conventional nanograin electrode. The electrocatalytic activities for chlorine evolution were increased up to 20 % in the case of the nanorod electrode and 35% in the case of the nanosheet electrode compared with the nanograin electrode. The $RuO_2$ nanorod 80 nm in length and 20-30 nm in width and the $RuO_2$ nanosheet 40-60 nm in length and 40 nm in width are formed on the surface of Ti substrates. These results support that the templated $RuO_2$ nanorod and nanosheet electrodes are promising anode materials for chlorine evolution in future applications.

• Journal of Magnetics
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• v.13 no.3
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• pp.110-113
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• 2008

In this study, heavy rare earth garnet $Tb_2Bi_1Ga_1Fe_4O_{12}$ powders were fabricated by a sol-gel and vacuum annealing process. The crystal structure was found to be single-phase garnet with a space group of Ia3d. The lattice constant $a_0$ was determined to be 12.465 ${\AA}$. From the analysis of the vibrating sample magnetometer (VSM) hysteresis loop at room temperature, the saturation magnetization and coercivity of the sample are 7.64 emu/g and 229 Oe, respectively. The N$\acute{e}$el temperature($T_N$) was determined to be 525 K. The M$\ddot{o}$ssbauer spectrum of $Tb_2Bi_1Ga_1Fe_4O_{12}$ at room temperature consists of 2 sets of 6 Lorentzians, which is the pattern of single-phase garnet. From the results of the M$\ddot{o}$ssbauer spectrum at room temperature, the absorption area ratios of Fe ions on 24d and 16a sites are 74.7% and 25.3%(approximately 3:1), respectively. These results show that all of the non-magnetic Ga atoms occupy the 16a site by a vacuum annealing process. Absorption area ratios of Fe ions are dependent not only on a sintering condition but also on the temperature of the sample. It can then be interpreted that the Ga ion distribution is dependent on the temperature of the sample. The M$\ddot{o}$ssbauer measurement was carried out in order to investigate the atomic migration in $Tb_2Bi_1Ga_1Fe_4O_{12}$.

• Journal of IKEEE
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• v.28 no.3
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• pp.261-270
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• 2024

In this study, a lanthanum gallium oxide (LaGaO) solution was prepared using a sol-gel method. By simply forming a LaGaO thin film through adjusting the curing temperature after applying the solution onto the substrate using a brush coating process, the potential for use as a liquid crystal (LC) alignment film in the LC display industry was validated. Through optical microscope observation, it was confirmed that the LC molecules were uniformly aligned as the curing temperature of the LaGaO thin film increased. It was confirmed that the LaGaO thin film cured at 230℃ had low pretilt angle, and that LaGaO particles were formed in a single direction as observed through an atomic force microscope. Through X-ray photoelectron spectroscopy, it was found that the LaGaO metal oxide thin film was well formed. Finally, it has been confirmed that LaGaO metal oxide has the potential as a novel LC alignment film material, as it exhibits excellent electrical and optical properties, along with high optical transmittance.