• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.867-876
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• 2012

The concentration of veterinary antibiotics in aqueous and sediment matrices was measured in agricultural irrigation ditches bordering several animal-feeding operations (AFOs) and then compared to its concentration in the watershed. Analytical determination in aqueous samples was based on solid phase extraction (SPE) and appropriate buffer solutions were used to extract residuals in sediment samples. Separation and detection of extracted veterinary antibiotics were performed with high performance liquid chromatograph tandem mass spectrometry (HPLC/MS/MS). In general, higher concentrations of antibiotic were observed in the aqueous phase of irrigation ditches, with the highest concentration of erythromycin hydrochloride (ETM-$H_2O$) of $0.53{\mu}g\;L^{-1}$, than in aqueous watershed samples. In contrast, higher concentrations were measured in river sediment than in irrigation ditch sediment with the highest concentration of oxytetracycline of $110.9{\mu}g\;kg^{-1}$. There was a high calculated correlation ( > 0.95) between precipitation and measured concentration in aqueous samples from the irrigation ditches for five of the ten targeted veterinary antibiotics, indicating that surface runoff could be an important transport mechanism of veterinary antibiotics from field to environment. Further, environmental loading calculation based on measured concentrations in aqueous samples and flow information clearly showed that irrigation ditches were 18 times greater than river. This result suggests the likelihood that veterinary antibiotics can be transported via irrigation ditches to the watershed. The transport via surface runoff and likely environmental loading via irrigation ditches examined in this study helps identify the pathway of veterinary antibiotics residuals in the environment.

• Journal of The Korean Society of Agricultural Engineers
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• v.55 no.2
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• pp.47-57
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• 2013

This study is to assess the reduction of non-point source pollution loads for rice straw mulching of upland crop cultivation at a watershed scale. For Byulmi-cheon watershed (1.21 $km^2$) located in the upstream of Gyeongan-cheon, the HSPF (Hydrological Simulation Program-Fortran) and SWAT (Soil and Water Assesment Tool), physically based distributed hydrological models were applied. Before evaluation, the model was calibrated and validated using 9 rainfall events. The Nash-Sutcliffe model efficiency (NSE) for streamflow using the HSPF was 0.62~0.76 and the determination coefficient ($R^2$) for water quality (sediment, total nitrogen T-N, and total phosphorus T-P) were 0.72, 0.62, and 0.63 respectively. The NSE for streamflow using the SWAT were 0.43~0.81 and the $R^2$ for water quality (sediment, T-N, and T-P) were 0.54, 0.87, and 0.64 respectively. From the field experiment of 16 rainfall events, the rice straw cover condition reduced surface runoff average 10.0 % compared to normal surface condition. By handling infiltration capacity (INFILT) in HSPF model, the value of 16.0 mm/hr was found to reduce about 10.0 % reduction of surface runoff. For this condition, the reduction effect of sediment, T-N, and T-P loads were 87.2, 28.5, and 85.1 % respectively. By handling soil hydraulic conductivity (SOL_K) in SWAT model, the value of 111.2 mm/hr was found to reduce about 10.0 point reduction of surface runoff. For this condition, the reduction effect of sediment, T-N, and T-P loads were 80.0, 83.2, and 78.7 % respectively. The rice straw surface covering was effective for removing surface runoff dependent loads such as sediment and T-P.

• Geomechanics and Engineering
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• v.17 no.6
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• pp.507-513
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• 2019

Reinforced soil and Expanded Polystyrenes (EPS) mixture (RSEM) is a geomaterial which has many merits, such as light weight, wide strength range, easy for construction, and economic feasibility. It has been widely applied to improve soft ground, solve bridge head jump, fill cavity in pipeline and widen highway. Reutilizing dredged sediment to produce RSEM as earthfill can not only consume a large amount of waste sediment but also significantly reduce the construction cost. Therefore, there is an urgent need understand the basic stress-strain characteristics of reinforced dredged sediment-EPS mixture (RDSEM). A series of cyclic triaxial tests were then carried out on the RDSEM and control clay. The effects of cement content, EPS beads content and confining pressure on the cyclic stress-strain behaviour of RDSEM were analyzed. It is found that the three stages of dynamic stress-strain relationship of ordinary soil, vibration compaction stage, vibration shear stage and vibration failure stage are also applicative for RDSEM. The cyclic stress-strain curves of RDSEM are lower than that of control clay in the vibration compaction stage because of its high moisture content. The slopes of backbone curves of RDSEMs in the vibration shear stage are larger than that of control clay, indicating that the existence of EPS beads provides plastic resistance. With the increase of cement content, the cyclic stress-strain relationship tends to be steeper. Increasing cement content and confining pressure could improve the cyclic strength and cyclic stiffness of RDSEM.

• Journal of Soil and Groundwater Environment
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• v.25 no.4
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• pp.77-86
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• 2020

Persulfate-based advanced oxidation processes (AOPs) can oxidize various organic pollutants. In this study, persulfate/Fe(II) system was utilized in phenol removal, and the effect of various organic and inorganic chelators on Fe(II)-medicated persulfate activation was investigated. The feasibility of persulfate/Fe(II)/chelator in cleanup of phenol-contaminated sediment was confirmed through toxicity assessment. In persulfate/Fe(II) conditions, the rate and extent of phenol removal increased in proportion to persulfate concentration. In chelator injection condition, the rate of phenol removal was inversely proportional to chelator concentration when it was injected above optimum ratio. Thiosulfate showed greater chelation tendency with persulfate than citrate and interfered with persulfate access to Fe(II), making the latter a more suitable chelator for enhancing persulfate activation. In contaminated clay sediment condition, 100% phenol removal was obtained within an hour without chelator, with the removal rate increased up to four times as compared to the rate with chelator addition. A clay sediment toxicity assessment at persulfate:Fe(II):phenol 20:10:1 ratio indicated 71.3% toxicity reduction with 100% phenol removal efficiency. Therefore, persulfate/Fe(II) system demonstrated its potential utility in toxicity reduction and cleanup of organic contaminants in sediments.

• Journal of Conservation Science
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• v.36 no.3
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• pp.152-161
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• 2020

The purpose of this study was to compare the chemical properties of white soil and refined clay sediment, which are produced early in the refining process. The characteristics of the white wares made at the kiln site in Goseong-ri, Chuncheon were also examined. Three groups of materials were examined: white wares excavated from the white wares kiln, raw material from white soil collected from the surface, and a refined clay sediment group. There were also three analysis methods, which were a main components analysis, a trace components analysis, and a mineral analysis. The main components analysis found that the white wares clay was in the RO₂4.04~4.28 and the RO + R₂O 0.30~0.31 mole areas, which were similar to the results for the refined clay sediment. However, the refining process used to produce better quality white wares meant that the large differences in the early white soil raw material appeared in the refined sediment. The mineral phase analysis showed that the crystals detected in the early white soil raw materials and refined clay sediment were almost identical. However, quartz and mullite mineral phases, which can occur above a certain temperature, were detected in the excavated white wares clay. Rare earth elements that were not affected by the pottery making process and the weathering of clay materials were found to have the same origin in all three groups.

• Journal of Korea Water Resources Association
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• v.43 no.11
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• pp.995-1009
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• 2010

Accelerated soil erosion due to extreme climate change, such as increased rainfall intensity, and human-induced environmental changes, is a widely recognized problem. Existing soil erosion models are generally based on the gross erosion concept to compute annual upland soil loss in tons per acre per year. However, such models are not suitable for event-based simulations of erosion and deposition in time and space. Recent advances in computer geographic information system (GIS) technologies have allowed hydrologists to develop physically based models, and the trend in erosion prediction is towards process-based models, instead of conceptually lumped models. This study aims to propose an effective and robust distributed rainfall-sediment yield-runoff model consisting of basic element modules: a rainfall-runoff module based on the kinematic wave method for subsurface and surface flow, and a runoff-sediment yield-runoff model based on the unit stream power method. The model was tested on the Cheoncheon catchment, upstream of the Yongdam dam using hydrological data for three extreme flood events due to typhoons. The model provided acceptable simulation results with respect to both discharge and sediment discharge even though the simulated sedigraphs were underestimated, compared to observations. The spatial distribution of erosion and deposition demonstrated that eroded sediment loads were deposited in the cells along the channel network, which have a short overland flow length and a gentle local slope while the erosion rate increased as rainfall became larger. Additionally, spatially heterogeneous rainfall intensity, dependant on Thiessen polygons, led to spatially-distinct erosion and deposition patterns.

• Ocean and Polar Research
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• v.24 no.1
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• pp.63-71
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• 2002

This preliminary study on the changes of macrobenthic assemblages in experimental sediment fences was conducted as a part of tidal marsh restoration project. Intertidal sediment fences were designed to increase the efficiency of trapping sediments on unvegetated tidal flats in order to raise sediment elevation and to allow colonization of intertidal vegetation. Although increment of soil surface level was not observed over the first three months of the study, it was possible to obtain some effects of the sediment fence. Three months later, the particle sizes of the surface sediment at experimental plots became much finer compared to unfenced areas on the natural mudflats located in the same tide level as that of the plots. The difference was much greater on the plot with drainage canals than on the plot without ones. Species diversity of the experimental plots became much higher than that of natural sites. Perinereis aibuhitensis and Glauconome chinensis which were absent from initial community appeared with high density in the plot with drainage canals. Those species were significantly different in abundance between the experimental plot and the natural mudflat. Changes in species composition were not detected in another experimental plot without drainage canals.

• Journal of Environmental Science International
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• v.5 no.6
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• pp.771-778
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• 1996

The sediment in the highly contaminated Gamjeon brook was collected, mixed with the raw material of the tile, and then the commercial tile was produced using the mixture. The concentrations of the heavy metals in the mixture-before and after the tile was produced-were analyzed and the effects of the acid solution on the produced tile were examined. The production of the tiles was successful and the result of heavy metal analysis showed that the concentration of Fe was the highest and that of Cd was the lowest The amount of heavy metal in the sediment - the raw material of the tile mixture was more than that of the produced tile. The elution concentration of the heavy metal by the acid solution(pH : 4 - 7) was low and the quality of the produced tile was better than the commercial tile. The result of this study suggested that the contaminated sediment was removed to produce good tiles, therefore the water pollution and soil pollution were reduced.

• Journal of The Korean Society of Agricultural Engineers
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• v.46 no.1
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• pp.87-97
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• 2004

The paper presents the results from the applications of the Water Erosion Prediction Project (WEPP) model to a single plot, and also a small watershed in the Mid Korean Peninsula which is comprised of hillslopes and channels along the water courses. Field monitoring was carried out to obtain total runoff, peak runoff and sediment yield data from research sites. For the plot of 0.63 ha in size, cultivated with com, the relative error of the simulated total runoff, peak runoff rates, and sediment yields using WEPP ranged from -16.6 to 22％, from -15.6 to 6.0％, and from 23.9 to 356.4％ compared to the observed data, respectively. The relative errors for the upland watershed of 5.1 ha ranged from -0.7 to 11.1 ％ for the total runoff, from -6.6 to 35.0 ％ for the sediment yields. The simulation results seem to justify that WEPP is applicable to the Korean dry croplands if the parameters are correctly defined. The results from WEPP applications showed that the major source areas contributing sediment yield most are downstream parts of the watershed where runoff concentrated. It was suggested that cultural practice be managed in such a way that the soil surface could be fully covered by crop during rainy season to minimize sediment yield. And also, best management practices were recommended based on WEPP simulations.

• Journal of Korean Society on Water Environment
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• v.26 no.4
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• pp.637-647
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• 2010

The Universal Soil Loss Equation (USLE)-based modeling systems have been widely used to simulate soil erosion studies. However the GIS-based USLE modeling systems have limitation in gully erosion evaluation which is one of the most important factor in soil erosion estimation. In this study, the integrated soil erosion evaluation system using with Sediment Assessment Tool for Effective Erosion Control (SATEEC) system, nLS and Unit Stream Power-based Erosion/Deposition (USPED) model was developed to simulate gully erosion. Gully head location using nLS model, USPED for gully erosion, and the SATEEC estimated sheet and rill erosion were evaluated and combined together with the integrated soil erosion evaluation system. This system was applied to the Haean-myeon watershed, annual average sediment-yield considering sheet, rill and gully erosion was simulated as 101,933 ton/year at the study watershed. if the integrated soil erosion evaluation system is calibrated and validated with the measured data, this system could be efficiently used in developing site-specific soil erosion best management system to reduce soil erosion and muddy water inflow into the receiving waterbody.