• Journal of Conservation Science
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• v.36 no.2
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• pp.143-151
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• 2020

In the present article, we have analyzed five slags excavated from the Unified Silla period iron smelting site, i.e., location 4-2 of the Inje Bupyeong-ri site, to investigate the iron smelting process. The total Fe content of the slag excavated from the Inje Bupyeong-ri site ranged between 3.65 and 23.78 wt%, lower than that of typical slag, and deoxidation agent of the slag ranged between 65.92 and 88.96 wt%, higher than that of typical slag. These results suggest that the recovery rate of iron was significantly high. Furthermore, cristobalite was detected in most of the samples, and the furnace temperature, estimated by substituting the analyzed data into the FAS and FCS state diagrams, was confirmed as 1,600℃ or more. These results suggest that the operation at the Inje Bupyeong-ri site was performed at a temperature capable of producing cast iron by completely melting the carbon-containing iron. Observation of the microstructure showed that the iron fragments excavated at the Inje Bupyeong-ri site were identified as white cast iron. Steadite from the ternary iron-carbon-phosphorus system was observed in the white cast iron structure. These results show that indirect smelting was performed when the iron smelting by-products were produced. Based on the analysis results, it was confirmed that the Inje Bupyeong-ri site was the indirect smelting site in the Unified Silla period.

• Journal of Korean Society on Water Environment
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• v.26 no.5
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• pp.768-774
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• 2010

This study was conducted to provide a technical solution to treat effectively perchlorate from inorganic wastewater of zinc smelting. Despite an inhibition dissolved inorganic substances in the wastewater discharged from zinc smelting has demonstrated with the activity of microbes, biological treatment technology could reduce perchlorate to a satisfactory level under such stressful conditions. It was found that either conductivity or $SO{_4}^{2-}$ concentration of the wastewater was able to be used as the adequate index and the values were $2,450{\mu}S/cm$ and 1,200 ppm respectively. When $SO{_4}^{2-}$ increased from 0 to 16,000 ppm (conductivity : $428{\rightarrow}24,800{\mu}S/cm$), perchlorate biodegradation rate was reduced due to 1/10 times from 0.0365 to 0.0033/h, however, most of perchlorate was removed under the condition of hydraulic retention time (HRT) at 0.5day and mixed liquor volatile suspended solid (MLVSS) at 2,000 ~ 3,000 ppm.

• Journal of Korea Technology Innovation Society
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• v.13 no.4
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• pp.700-716
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• 2010

This paper examines the development of smelting reduction process in POSCO from 1990 to 2007 with the perspective of post catch-up technological innovation. POSCO paid attention to smelting reduction process as a sort of next-generation iron and steel technology, and implemented COREX (coal ore reduction) by the cooperation with V$\"{o}$oest. In addition to this, POSCO started to develop FINEX (fine iron ore reduction) which can use abundant powder ore, and FINEX was developed through model plant, pilot plant, demo plant, and commercial facility. POSCO came up to innovation leader beyond fast follower by securing almost technologies concerning FINEX. The case of smelting reduction process shows various characteristics including appropriate technological choice, successive scale-up, spiral development system, complementary technological cooperation, long-tenn investment, the existence of top management's leadership, and Korean government's support in early stage. This case can be interpreted as a path-revealing innovation in the middle of technological paradigm change.

• Resources Recycling
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• v.30 no.2
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• pp.3-13
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• 2021

Nickel is widely used due to its excellent toughness, malleability and enhanced corrosion resistance. Therefore, nickel is indispensable in our daily lives, and it is widely used in basic to advanced applications such as stainless steel, super alloys and electronic devices. Recently, nickel has been widely used as the major material in secondary batteries and capacitors. The use of nickel continues to rise and has increased from 800 thousand tonnes per year worldwide in the 1970s to about 2 million tonnes in the 2010s. However, nickel is a representative rare metal and ranks 23rd among the abundant elements in the earth's crust. This study reviews the current status of the nickel smelting processes as well as the trend in production amount and use. Nickel is extracted by a wide variety of smelting methods depending on the type of ore. These smelting methods are essential for the development of new recycling processes that can extract nickel from secondary nickel resources.

• Resources Recycling
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• v.5 no.4
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• pp.17-24
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• 1996

The computer simulation model was established to verify the applicability of smelting reduction concept to treatment of industrial wastes which becomes issue on the enviromental and recycling view point. Computer simulation model provides as following results. The increase of post combustion ratio(PCR) and heat transfer efficiency of PC energy(HTE) is effective ways to save energy. But, in order to increase PCR, recovery efficiency of post combustion energy(HTE) have to be higher than 85% HTE considering refractory life and saving energy together. Coke is most useful fuel source because it shows lowest dependence of PCR and low hydrogen content. The quality of hot metal of current process would be expected to the similar level with that of blast furnace. The utilization of scrap and Al dross can be also possible to maximize the advantages of current process which is high temperature and chemical dilution with hot metal and slag. In case of scrap, energy consumption was slightly increases because of heating up energy of scrap. Consquently, current process concept provides the possibility of intergrating recycles of industrial wastes materials such as EAF slag, coke oven dust, life terminated acidic refractory, aluminium dross and scrap by smelting reduction process.

• Journal of Conservation Science
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• v.38 no.1
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• pp.33-44
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• 2022

The study, iron-making process was examined through the scientific analysis of six by-products that were obtained during iron making at the Songdu-ri site in Jincheon. The total Fe content of the slags excavated from the Songdu-ri site was 36.29-54.61 wt%, whereas the deoxidation agent was 26.48-49.08 wt%. The compound analysis result indicated that fayalite and wüstite are the main compounds in slag. Furthermore, the microstructure analysis result confirmed the presence of fayalite and wüstite in the slag. It can be inferred from the flat shape in a bright matrix structure of the hammer scales that forging was performed in the latter stage. The Raman micro-spectroscopy results confirmed that the surface was hematite (Fe₂O₄), middle layer was magnetite (Fe₃O₄), and inner layer was wüstite (FeO). The presence of smelting and smithing slags, spheroid hammer scales, and flake hammer scales suggests that at the Songdu-ri site, iron-making process is carried out by division of labor into producing iron bloom through direct smelting, refining and forge welding, and ingot production.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2003.10a
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• pp.22-34
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• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.5
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• pp.507-516
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• 2010

Stationary combustion sources such as coal-fired power plants, waste incinerators, industrial manufacturing, etc. are recognized as major sources of mercury emissions. Due to rapid economic growth, zinc production in Korea has increased significantly during the last 30 years. Total zinc production in Korea exceeded 739,000 tons in 2008, and Korea is currently the third largest zinc producing country in the world. Previous studies have revealed that zinc smelting has become one of the largest single sectors of total mercury emissions in the World. However, studies on this sector are very limited, and a large gap in the knowledge regarding emissions from this sector needs to be bridged. In this paper, Hg emission measurements were performed to develop emission factors from zinc smelting process. Stack sampling and analysis were carried out utilizing the Ontario Hydro method and US EPA method 101A. Preliminary data showed that $Hg^0$ concentrations in the flue gas ranged from 4.56 to $9.90\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$, Hg(p) concentrations ranged from 0.03 to $0.09\;{\mu}g/m^3$ with an average of $0.04\;{\mu}g/m^3$, and RGM concentrations ranged from 0.23 to $1.17\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$. To date, emission factors of 7.5~8.0 g/ton for Europe, North America and Australia, and of 20 or 25 g/ton for Africa, Asia and South America are widely accepted by researchers. In this study, Hg emission factors were estimated using the data measured at the commercial facilities as emissions per ton of zinc product. Emission factors for mercury from zinc smelting pross ranged from 4.32 to 12.96 mg/ton with an average of 8.31 mg/ton. The emission factors that we obtained in this study are relatively low, considering Hg contents in the zinc ores and control technology in use. However, as these values are estimated by limited data of single measurement of each, the emission factor and total emission amount must be updated in future.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.5 no.2
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• pp.160-171
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• 1995

The size characteristics of lead particle which is one of the important factors associated with absorption of lead were ignored in establishing lead standard. This study was conducted to investigate distribution of lead particles by operation of industry. Aerodynamic Mass Median Diameters (MMD) of airborne lead particles in the battery and litharge manufacturing industry were $14.1{\mu}m$ and $15.1{\mu}m$, respectively. There was no significant difference between those two values(p>0.05). However, the diameters in radiator manufacturing and secondary smelting industry were $1.3{\mu}m$, $4.9{\mu}m$, respectively. Those were significantly smaller than the particle sizes in other industries(p<0.05). Total lead concentrations in the secondary smelting industry were higher than those in the battery and litharge manufacturing industry. Total lead concentrations in other industries except radiator manufacturing industry exceeded the standard of $50{\mu}g/m^3$. Only radiator manufacturing industry indicated lead concentrations significantly lower than those in other industries(p<0.05). Concentrations of lead particles smaller than $1{\mu}m$ defined as respirable fraction by OSHA's CPA model assumption were $72.4{\mu}g/m^3$ in the secondary smelting industry, exceeding $50{\mu}g/m^3$. The relationship of concentrations between total lead and lead of particles smaller than $1{\mu}m$ was log Y = 0.46 logX + 0.06(n=119, $r^2=0.44$, p=0.0001). Relationship of respirable lead concentrations between OSHA and ACGIH was significantly detected in the litharge and battery manufacturing industry(p=0.0001), but was not significant in the radiator(p=0.2720) and secondary smelting manufacturing industry(p=0.2394). As MMDs of lead particles generated in industry were small, difference of respirable lead concentration between OSHA and ACGIH became smaller. There was a significant difference between concentrations respirable lead defined by two organizations such as OSHA and ACGIH in the battery and litharge manufacturing industry. Average concentration of respirable lead by ACGIH definition was 43.3 % of total lead in secondary smelting and 48.9 % in radiator manufacturing industry, and lower fractions were indicated in battery and litharge manufacturing industry. Relationships of total lead with IPM, TPM, and RPM were significant respectively(p=0.0001) and lead concentrations by particle size could be estimated using this relationship. Linear regression equation between total lead concentration(X) and ACGIH-RPM concentration(Y) was log Y = 0.76 log X - 0.40($r^2=0.89$, p=0.0001).

• Journal of Conservation Science
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• v.33 no.6
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• pp.519-532
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• 2017

Studies on ancient ironmaking technologies are primarily based on archaeological surveys and scientific analysis data, and technological systems are examined by comparing the results of restorative experiments. In this study, to examine the ancient iron production technologies such as smelting and smithing in the Jungwon area, a restoration experiment was conducted based on archaeological data, and the iron and slag, etc. produced in the experiment were analyzed. Further, the changes in physicochemical properties due to the smelting of the raw material, specifically, iron ore were determined, and the smithing process, which involves fabrication of ironwares, was analyzed along with the characteristics of each step. In the case of smelting, increasing recovery rates and production of high-quality primary iron material were important for the following processes. For the iron bars produced through the smithing process, it was found that quality improvements made by reducing physical defects such as inclusions or gas holes were more important than the composition of the iron itself. The study also yielded comparative study data for various byproducts, such as smithing slag, which could be utilized in other ironmaking technology studies.