• Title/Summary/Keyword: size distortion

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New Unsymmetric Dinuclear Copper(II) Complexes of Trans-disubstituted Cyclam Derivatives: Spectral, Electrochemical, Magnetic, Catalytic, Antimicrobial, DNA Binding and Cleavage Studies

  • Prabu, R.;Vijayaraj, A.;Suresh, R.;Jagadish, L.;Kaviyarasan, V.;Narayanan, V.
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1669-1678
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    • 2011
  • Six new binuclear copper(II) complexes have been prepared by template condensation of the dialdehydes 1,8-[bis(3-formyl-2-hydroxy-5-methyl)benzyl]-l,4,8,11-tetraazacyclotetradecane (PC-a) and 1,8-[bis(3-formyl-2-hydroxy-5-bromo)benzyl]-l,4,8,11-tetraazacyclotetradecane (PC-b) with appropriate aliphatic diamines, and copper(II) perchlorate. The structural features of the complexes have been confirmed by elemental analysis, IR, UV-vis and mass spectra etc. The electrochemical behavior of all the copper(II) complexes show two irreversible one electron reduction process. The room temperature magnetic moment studies depict the presence of an antiferromagnetic interaction in the binuclear complexes. The catechol oxidation and hydrolysis of 4-nitrophenylphosphate were carried out by using the complexes as catalyst. The antimicrobial screening data show good results. The binding of the complexes to calf thymus DNA (CT DNA) has been investigated with absorption and emission spectroscopy. The complex [$Cu_2L^{1a}$] displays significant cleavage property of circular plasmid pBR322 DNA in to linear form. Spectral, electrochemical, magnetic and catalytic studies support the distortion of the copper ion geometry that arises as the macrocyclic ring size increases.

Bean Yellow Mosaic Virus and Cucumber Mosaic Virus Causing Mosaic Disease on Gladiolus in Korea (그라디오러스에 발생하는 BYMV와 CMV에 관한 연구)

  • Lee S.H.;Kim J.S.;Choi Y.M.
    • Korean journal of applied entomology
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    • v.22 no.3 s.56
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    • pp.198-202
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    • 1983
  • A mosaic disease of gladiolus has been commonly observed with an infection rate of $43.3\%$ in the field. Bean Yellow Mosaic Virus(BYMV) produced veinal spreading lesions on Cheonopodium amaranticolor, veinal necrosis and severe leaf distortion on Phaseolus vulgaris 'Scotia' and mosaic on Vi cia faba. Cucumber Mosaic Virus(CMV) produced local lesions on C. amaranticolor, mosaic symptoms on Nicotiana glutinosa and Cucumis sativus. BYMV and CMV were transmitted by the green peach aphid. Purified BYMV and CMV had a typical maximum absorption at 260nm. In agar gel diffusion test, BYMV and CMV gave positive reaction with their homologous antiserum. The size of BYMV was 750nm in length, and CMV was 30nm in diameter.

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A New Remeshing Technique of Tetrahedral Elements by Redistribution of Nodes in Subdomains and its Application to the Finite Element Analysis (영역별 절점 재분포를 통한 사면체 격자 재구성 방법 및 유한요소해석에의 적용)

  • Hong J.T.;Lee S.R.;Yang D.Y.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.607-610
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    • 2005
  • A remeshing algorithm using tetrahedral elements has been developed, which is adapted to the mesh density map constructed by a posteriori error estimation. In the finite element analyses of metal forging processes, numerical error increases as deformation proceeds due to severe distortion of elements. In order to reduce the numerical error, the desired mesh sizes in each region of the workpiece are calculated by a posteriori error estimation and the density map is constructed. Piecewise density functions are then constructed with the radial basis function in order to interpolate the discrete data of the density map. The sample mesh is constructed based on the point insertion technique which is adapted to the density function and the mesh size is controlled by moving and deleting nodes to obtain optimal distribution according to the mesh density function and the quality optimization function as well. After finishing the redistribution process of nodes, a tetrahedral mesh is constructed with the redistributed nodes, which is adapted to the density map and resulting in good mesh quality. A goodness and adaptability of the constructed mesh is verified with a testing measure. The proposed remeshing technique is applied to the finite element analyses of forging processes.

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Magnetocardiography System in Open-door Magnetically-shielded Room (열린 자기차폐실의 심자도 시스템)

  • Kim, J.M.;Lee, Y.H.;Kwon, H.;Yu, K.K.;Kim, K.;Park, Y.K.;Sasada, Ichiro
    • Progress in Superconductivity
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    • v.9 no.1
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    • pp.50-55
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    • 2007
  • We have installed a 61-channel magnetocardiography (MCG) system inside a magnetically shielded room (MSR) with a size of $2.4\;m\;{\times}2.4\;m\;{\times}2.4\;m$. The MCG system consists of 1st-order axial gradiometers containing double relaxation oscillation SQUIDs (DROSs) with pick-up coils of a base line of 70 mm. The MSR holds a shielding factor of 50 at 0.1 Hz and 10000 at 100 Hz, when its door in the middle on a front wall is closed. On opening the MSR door, we have obtained the characteristics of the MCG system with a 2.9 Hz noise generated from an air conditioning unit at 13 m distance off the MSR. In an open-door MSR ($140^{\circ}$ opening), a noise at the center channel increases up to $700\;fT/Hz^{l/2}$ at 2.9 Hz and $1.7\;pT/Hz^{1/2}$ at 60 Hz. MCG signals for a healthy human do not show distortion until the door opens to $45^{\circ}$, but show the effect of noise when the door opens further at $90^{\circ}$ and $140^{\circ}$. With the door opens to $45^{\circ}$, MCG measurement can be performed with ease of door operation and without creating claustrophobia for the patient.

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Exploiting Patterns for Handling Incomplete Coevolving EEG Time Series

  • Thi, Ngoc Anh Nguyen;Yang, Hyung-Jeong;Kim, Sun-Hee
    • International Journal of Contents
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    • v.9 no.4
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    • pp.1-10
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    • 2013
  • The electroencephalogram (EEG) time series is a measure of electrical activity received from multiple electrodes placed on the scalp of a human brain. It provides a direct measurement for characterizing the dynamic aspects of brain activities. These EEG signals are formed from a series of spatial and temporal data with multiple dimensions. Missing data could occur due to fault electrodes. These missing data can cause distortion, repudiation, and further, reduce the effectiveness of analyzing algorithms. Current methodologies for EEG analysis require a complete set of EEG data matrix as input. Therefore, an accurate and reliable imputation approach for missing values is necessary to avoid incomplete data sets for analyses and further improve the usage of performance techniques. This research proposes a new method to automatically recover random consecutive missing data from real world EEG data based on Linear Dynamical System. The proposed method aims to capture the optimal patterns based on two main characteristics in the coevolving EEG time series: namely, (i) dynamics via discovering temporal evolving behaviors, and (ii) correlations by identifying the relationships between multiple brain signals. From these exploits, the proposed method successfully identifies a few hidden variables and discovers their dynamics to impute missing values. The proposed method offers a robust and scalable approach with linear computation time over the size of sequences. A comparative study has been performed to assess the effectiveness of the proposed method against interpolation and missing values via Singular Value Decomposition (MSVD). The experimental simulations demonstrate that the proposed method provides better reconstruction performance up to 49% and 67% improvements over MSVD and interpolation approaches, respectively.

Development of MR Compatible Coaxial-slot Antenna for Microwave Hyperthermia (초고주파 가열치료를 위한 MR 호환 동축 슬롯 안테나의 개발)

  • Kim, T.H.;Chun, S.I.;Han, Y.H.;Kim, D.H.;Mun, C.W.
    • Journal of Biomedical Engineering Research
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    • v.30 no.4
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    • pp.333-340
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    • 2009
  • MR compatible coaxial-slot antenna for microwave hyperthermia was developed while its structure and size of each part were determined by computer simulation using finite element method(FEM). Its local heating performance was evaluated using tissue-mimic phantom and swine muscles. 2% agarose gel mixed with 6mM/$\ell$ $MnCl_2$ as a biological tissue-mimic phantom was heated by the proposed antenna driven by a 2.45GHz microwave generator. The temperature changes of the phantom were monitored using multi-channel digital thermometer at the distance of 0mm, 5mm, 10mm and 20mm from the tip center of the antenna. Also muscle tissue of swine was heated for 2 and 5minutes with 50W and 30W of microwave generator powers, respectively, to evaluate the local heating performance of the antenna. MRI compatibility was also verified by acquiring MR images and MR temperature map. MR signals were acquired from the agarose gel phantom using $T2^*$ GRE sequence with 1.5T clinical MRI scanner(Signa Echospeed, GE, Milwaukee, WI, U.S.A.) at Pusan Paik Hospital and were transferred to PC in order to reconstruct MR images and temperature map using proton resonance frequency(PRF) method and laboratory-developed phase unwrapping algorithm. Authors found that it has no severe distortion due to the antenna inserted into the phantom. Finally, we can conclude that the suggested coaxial-slot antenna has an excellent local heating performance for both of tissue-mimic phantom and swine muscle, and it is compatible to 1.5T MRI scanner.

Structural design method of the steel brush type loading platen adopted in multi-axial compression experiments (다축압축 실험에 적용되는 철제 빗살구조 재하판의 구조 설계 기법)

  • SaGong, Myung;Lee, Jun-S.;Kim, Sung-Soo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.4
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    • pp.351-359
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    • 2007
  • Multi-axial compression tests have been frequently conducted to evaluate the in situ properties of rock masses and the mechanical behaviors of rock strata through the model tests. Without the proper boundary condition for the model tests, the mechanical behavior of rock mass would deviate, as can be expected, from the in situ conditions. The boundary condition will affect the internal stress distribution of the specimens and cause some distortion on the measurement. In this study, a design process regarding the steel brush, which has been employed for multi-axial compression test to reduce the frictional restraint along the specimen/loading platen interface, is introduced. The individual brushes are regarded as a simple column and beam to calculate the cross-sectional size and length of the brushes in consideration of the buckling capacity and the allowable deflection.

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Word Sense Similarity Clustering Based on Vector Space Model and HAL (벡터 공간 모델과 HAL에 기초한 단어 의미 유사성 군집)

  • Kim, Dong-Sung
    • Korean Journal of Cognitive Science
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    • v.23 no.3
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    • pp.295-322
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    • 2012
  • In this paper, we cluster similar word senses applying vector space model and HAL (Hyperspace Analog to Language). HAL measures corelation among words through a certain size of context (Lund and Burgess 1996). The similarity measurement between a word pair is cosine similarity based on the vector space model, which reduces distortion of space between high frequency words and low frequency words (Salton et al. 1975, Widdows 2004). We use PCA (Principal Component Analysis) and SVD (Singular Value Decomposition) to reduce a large amount of dimensions caused by similarity matrix. For sense similarity clustering, we adopt supervised and non-supervised learning methods. For non-supervised method, we use clustering. For supervised method, we use SVM (Support Vector Machine), Naive Bayes Classifier, and Maximum Entropy Method.

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Effect of Mechanical Constraints on the Angular Distortion of Welding Joints (용접 각변형에 미치는 구속도의 영향)

  • Park, Jeong Ung;Lee, Jae Won;Lee, Hae Woo
    • Journal of Korean Society of Steel Construction
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    • v.13 no.5
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    • pp.547-556
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    • 2001
  • This study presents new method in which to derive the constraint coefficient from the quantity of angular deformation by welding measured by varying the shape of welded joints and the magnitude of constraints by varying the shape of welded joints and the magnitude of constraints by experiment and from the result analyzed by elastic FEM method and then to decide equivalent load with it The numerical analysis results by this new method verified the validity by agreeing with the experimental result on specimen. In addition These results are applicable to the prediction of the quantity of welding deformation for large structures regardless of the size and the shape While in the effects of the constraints based on the shape of welded joints in the case of Butt welding when the constraint coefficients are not considered the deformed quantity is produced larger than one by the experiment and consequently is largely affected by the constraints But in the case of Fillet welding the deformed quantity is seldom affected regardless of considering the constraint coefficients or not.

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Trimming Line Design using Incremental Development Method and Finite Element Inverse Method (점진 전개기법 및 유한요소 역해석법을 이용한 자동차 패널 트리밍 라인 설계)

  • Chung, W.J.;Park, C.D.;Song, Y.J.;Oh, S.W.
    • Transactions of Materials Processing
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    • v.15 no.6 s.87
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    • pp.445-452
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    • 2006
  • In most of automobile body panel manufacturing, trimming process is generally performed before flanging. To find feasible trimming line is crucial in obtaining accurate edge profile after flanging. Section-based method develops blank along manually chosen section planes and find trimming line by generating loop of end points. This method suffers from inaccurate results of edge profile. On the other hand, simulation-based method can produce more accurate trimming line by iterative strategy. In this study, new fast simulation-based method to find feasible trimming line is proposed. Finite element inverse method is used to analyze the flanging process because final shape after flanging can be explicitly defined and most of strain paths are simple in flanging. In utilizing finite element inverse method, the main obstacle is the initial guess generation for general mesh. Robust initial guess generation method is developed to handle genera] mesh with very different size and undercut. The new method develops final triangular mesh incrementally onto the drawing tool surface. Also in order to remedy mesh distortion during development, energy minimization technique is utilized. Trimming line is extracted from the outer boundary after finite element inverse method simulation. This method has many advantages since trimming line can be obtained in the early design stage. The developed method is verified by shrink/stretch flange forming and successfully applied to the complex industrial applications such as door outer flanging process.