• Title/Summary/Keyword: single-wall carbon nanotube

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Electrochemical Determination of 6-Benzylaminopurine (6-BAP) Using a Single-wall Carbon Nanotube-dicetyl Phosphate Film Coated Glassy Carbon Electrode

  • Li, Chunya
    • Bulletin of the Korean Chemical Society
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    • v.27 no.7
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    • pp.991-994
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    • 2006
  • Herein, insoluble single-walled carbon nanotube (SWNT) was successfully dispersed into water in the presence of a special kind of surfactant-dicetyl phosphate (DCP), subsequently, a SWNT-DCP composite film coated glassy carbon electrode (GCE) was fabricated. The electrochemical behaviors of 6-benzylaminopurine (6-BAP) at the unmodified GCE and SWNT-DCP modified GCE were examined. It is found that the SWNT-DCP modified GCE remarkably enhances the oxidation peak current of 6-BAP, indicating great potential in the determination of trace level of 6-BAP. Finally, a sensitive and simple voltammetric method with a good linear relationship in the range of ${\times}5.0\;\;10^{-8}\sim 2.5\;{\times}\;10^{-6}$ mol/L, was developed for the determination of 6-BAP. The detection limit is as low as $2.0\;{\times}\;10^{-8}$ mol/L for 3-min accumulation. This newly-proposed method was successfully demonstrated with practical samples.

Mechanical properties and deformation behavior of carbon nanotubes calculated by a molecular mechanics approach

  • Eberhardt, Oliver;Wallmersperger, Thomas
    • Smart Structures and Systems
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    • v.13 no.4
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    • pp.685-709
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    • 2014
  • Carbon nanotubes are due to their outstanding mechanical properties destined for a wide range of possible applications. Since the knowledge of the material behavior is vital regarding the possible applications, experimental and theoretical studies have been conducted to investigate the properties of this promising material. The aim of the present research is the calculation of mechanical properties and of the mechanical behavior of single wall carbon nanotubes (SWCNTs). The numerical simulation was performed on basis of a molecular mechanics approach. Within this approach two different issues were taken into account: (i) the nanotube geometry and (ii) the modeling of the covalent bond. The nanotube geometry is captured by two different approaches, the roll-up and the exact polyhedral model. The covalent bond is modeled by a structural molecular mechanics approach according to Li and Chou. After a short introduction in the applied modeling techniques, the results for the Young's modulus for several SWCNTs are presented and are discussed extensively. The obtained numerical results are compared to results available in literature and show an excellent agreement. Furthermore, deviations in the geometry stemming from the different models are given and the resulting differences in the numerical findings are shown. Within the investigation of the deformation mechanisms occurring in SWCNTs, the basic contributions of each individual covalent bond are considered. The presented results of this decomposition provide a deeper understanding of the governing deformation mechanisms in SWCNTs.

Molecular Dynamics Simulations of Fullerene Nanostructure Fabrications by Atomic Force Microscope Carbon Nanotube tip (원자간력 현미경 탄소 나노튜브 팁을 이용한 플러렌 나노 구조물 제작에 관한 분자동역학 시뮬레이션)

  • 이준하;이홍주
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.8
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    • pp.812-822
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    • 2004
  • This paper shows that carbon nanotubes can be applied to a nanopipette. Nano space in atomic force microscope multi-wall carbon nanotube tips is filled with molecules and atoms with charges and then, the tips can be applied to nanopipette when the encapsulated media flow off under applying electrostatic forces. Since the nano space inside the tips can be refilled, the tips can be permanently used in ideal conditions of no chemical reaction and no mechanical deformation. Molecular dynamics simulations for nanopipette applications demonstrated the possibility of nano-lithography or single-metallofullerene-transistor array fabrication.

Inkjet Printing of Single Walled Carbon Nanotubes

  • Song, Jin-Wong;Han, Chang-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.3
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    • pp.79-81
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    • 2008
  • A single-wall carbon nanotube (SWNT) transparent conductive film (TCF) was fabricated using a simple inkjet printing method. The TCF could be selectively patterned by controlling the dot size to diameters as small as $34{\mu}m$. In this repeatable and scalable process, we achieved 71% film transmittance and a resistance of 900 ohm/sq sheet with an excellent uniformity, about ${\pm}5%$ deviation overall. Inkjet printing of SWNT is substrate friendly and the TCF is printed on a flexible substrate. This method of fabrication using direct printing permits mass production of TCF in a large area process, reducing processing steps and yielding low-cost TCF fabrications on a designated area using simple printing.

Performance-determining factors in flexible transparent conducting single-wall carbon nanotube film

  • Song, Young Il;Lee, Jung Woo;Kim, Tae Yoo;Jung, Hwan Jung;Jung, Yong Chae;Suh, Su Jeung;Yang, Cheol-Min
    • Carbon letters
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    • v.14 no.4
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    • pp.255-258
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    • 2013
  • Flexible transparent conducting films (TCFs) were fabricated by dip-coating single-wall carbon nanotubes (SWCNTs) onto a flexible polyethylene terephthalate (PET) film. The amount of coated SWCNTs was controlled simply by dipping number. Because the performance of SWCNT-based TCFs is influenced by both electrical conductance and optical transmittance, we evaluated the film performance by introducing a film property factor using both the number of interconnected SWCNT bundles at intersection points, and the coverage of SWCNTs on the PET substrate, in field emission scanning electron microscopic images. The microscopic film property factor was in an excellent agreement with the macroscopic one determined from electrical conductance and optical transmittance measurements, especially for a small number of dippings. Therefore, the most crucial factor governing the performance of the SWCNT-based TCFs is a SWCNT-network structure with a large number of intersection points for a minimum amount of deposited SWCNTs.

Micro-Raman characterization of isolated single wall carbon nanotubes synthesized using Xylene

  • Choi, Young Chul
    • Carbon letters
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    • v.14 no.3
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    • pp.175-179
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    • 2013
  • Isolated single wall carbon nanotubes (SWCNTs) were synthesized by chemical vapor deposition (CVD) using a liquid precursor (xylene) as a carbon source. Transmission electron microscopy (TEM) and atomic force microscopy confirmed the isolated structure of the SWCNTs. Micro-Raman measurements showed a tangential G-band peak ($1590cm^{-1}$) and radial breathing mode (RBM) peaks ($150-240cm^{-1}$). The tube diameters determined from the RBM frequencies are in good agreement with those obtained from TEM. The chirality of the isolated SWCNTs could be determined based on the energy of the laser and their diameter. A further preliminary study on the nitrogen doping of isolated SWCNTs was carried out by the simple use of acetonitrile dissolved in the precusor.

Electrospinning of poly(vinylidene fluoride) with carbon nanotubes (Carbon nanotube를 포함한 PVDF/DMF 용액의 전기방사)

  • Kim, Yong-Tae;Chang Seoul;Zheng, Hai-Lan
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.183-186
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    • 2002
  • Polymer composites with carbon nanotubes have recently been investigated for improving certain properties i.e., electrical, optical and mechanical properties[1-3]. Kymakis et. al. have reported the electrical and optical properties of single wall carbon nanotube-poly(3-octylthiophene) composites[4]. Polyurethane dissolved in dimethylformanide (DMF) were electrospun by Demir et. al.[5]. (omitted)

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Quantitative Evaluation of Non-Carbon Content in the Single Wall Carbon Nanotube Soot using Thermogravimetric Analysis

  • Han, J.H.;An, K.H.;Lee, N.S.;Goak, J.C.;Jeong, M.S.;Choi, Y.C.;Oh, K.H.;Kim, K.K.;Lee, Y.H.
    • Carbon letters
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    • v.10 no.1
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    • pp.5-8
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    • 2009
  • We measured the non-carbon content of single-walled carbon nanotubes (SWCNTs) in SWCNT soot using thermogravimetric analysis. The weight increased percentage by the oxidation of metal in the raw soot is well obtained by TGA graph which was confirmed with ICP-AES, XRD, and XPS. This work will be very useful for the purity precise evaluation of SWCNT with UN-vis-NIR spectroscopy.