• Elastomers and Composites
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• 제50권3호
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• pp.159-166
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• 2015

Silica which is used for reinforcing filler in tire industry is widely known as eco-friendly material exerting $CO_2$ reduction effect through decrease of rolling resistance and improvement of wet grip. Generally silica is classified as a highly polar filler because it contains a large number of silanol (Si-OH) group on its surface. And also silica gives a lower reinforcing effect than carbon black due to its poorer rubber-filler interaction. Therefore silica is treated with silane coupling agent or activator, then following the conventional rubber blend method, vulcanized sheets were prepared using a hot press, and cure characteristics, mechanical properties and abrasion resistance of the test specimens were investigated. It was found that with an increase in the silane coupling agent content the tensile strength, 300% modulus and abrasion resistance increased while Mooney viscosity decreased and crosslink density slightly increased with an increase of activator.

• 한국전기전자재료학회논문지
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• 제25권10호
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• pp.779-785
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• 2012

The epoxy/micro-and nano-mixed silica composites(EMNC) systems were prepared and the AC insulation breakdown strength was evaluated. Glass transition temperature (Tg) and crosslink density were also measured by dynamic mechanical analyzer(DMA) in order to correlate them with the electrical and mechanical properties, and the effect of silane coupling agent on the electrical properties was also studied. Electrical properties and crosslink density of epoxy/micro-silica composite were noticeably improved by addition of nano-silica and silane coupling agent, and the highest breakdown strength was obtained by addition of 0.5~5 phr of nano-silica and 2.5 phr of silane coupling agent, and the highest tensile and flexural strength were obtained by addition of 2.5 phr of nano-silica.

• 한국응용과학기술학회지
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• 제27권3호
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• pp.300-309
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• 2010

Melamincyanurate(MC), as an non halogen flame retardant are used as the polymer and plastic materials. In this study, melamine and cyanuric acid were used for the synthesis of MC. The optimum condition of synthetic MC were controlled by different molar ratio of melamine to cyanuric acid. MC was modified by coupling reaction with four different agents. The influences of modified MC were based on the coupling agent types. Preparation methods are available to offer the prospect of improved morphology control deposit stability in polyol. The results reveal that glycidoxypropyltrimethoxysilane(GDS) has the best storage stability. The best properties were obtained with melamine and cyanuric acid from 1:1 molar ratio. Modification of MC through coupling agent can efficiently enhanced the deposit stability in polyol up to 30 %.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1076-1077
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• 2006

Conductive pastes consist of conductive fillers( Au, Ag, Ni, Cu etc.), organic binders, solvents and additives. Meanwhile, there are some metal powders such as copper, nickel etc that are used for pastes which have serious surface corrosion problems. This problem leads to change of the color and decrease in conductivity and affect storage stability of conductive pastes. By using silane coupling agent and dispersion agent, we can ensure both the corrosion stability and long term storage stability, and enhance the high performance electrical and mechanical properties of EMI shielding silicone sealant.

• 공업화학
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• 제31권2호
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• pp.230-236
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• 2020

본 연구에서는 모바일 기기용 방수 및 내충격 기능성 소재로 사용되는 우레탄-아크릴레이트 점착테이프의 부착력 향상 연구를 수행하였다. 소수성 표면을 가진 기재(substrate) 필름과 아크릴 점착제 사이의 젖음성 및 밀착력 하락으로 인한 점착테이프의 물성 저하를 개선하기 위해, 에폭시 작용기를 가진 실란 커플링제인 3-glycidoxy-propyl trimethoxysilane (GPTMS)을 UV 경화형 우레탄-아크릴레이트 수지에 함량별로 첨가하여 필름을 제조하였다. FT-IR, EDS, XPS를 이용하여 실란 커플링제의 함량에 따른 기재 필름의 표면 결합 특성을 확인하였고, 인장강도, 접촉각, 겔 분율(gel fraction)을 측정하여 기계적 물성 변화를 비교하였다. 또한 우레탄-아크릴레이트 필름의 양쪽에 아크릴 점착제를 코팅하여 양면 점착테이프를 제조하고, 180, 90° 박리강도(peel strength)를 측정하여 실란 커플링제 함량별로 기재 필름과 점착제 사이의 접착력(밀착력)을 비교하였다. 실란 커플링제 함량이 증가할수록 기재필름의 다양한 물성의 변화를 보였지만, 0.5~1 wt% 정도의 첨가는 기타 물성의 손실 없이 효과적으로 점착층과의 계면 부착력을 향상시켰다.

• 한국재료학회지
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• 제31권3호
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• pp.122-131
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• 2021

In the fabrication of joined materials between anodized aluminum alloy and polymer, the performance of the metal-polymer joining is greatly influenced by the chemical properties of the oxide film. In a previous study, the dependence of physical joining strength on the thickness, structure, pore formation, and surface roughness of films formed on aluminum alloys is investigated. In this study, we investigated the effect of silane coupling treatment on the joining strength and sealing performance between aluminum alloy and polymer. After a two-step anodization process with additional treatment by silane, the oxide film with chemically modified nanostructure is strongly bonded to the polymer through physical and chemical reactions. More specifically, after the two-step anodization with silane treatment, the oxide film has a three-dimensional (3D) nanostructure and the silane components are present in combination with hydroxyl groups up to a depth of 150 nm. Accordingly, the joining strength between the polymer and aluminum alloy increases from 29 to 35 MPa, and the helium leak performance increases from 10-2-10-4 to 10-8-10-9 Pa ㎥ s-1.

• 공업화학
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• 제9권4호
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• pp.608-613
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• 1998

본 연구의 목적은 순수 카본블랙과 이중상 구조의 카본블랙 (DPCB)이 함유되어 있는 고무조성물의 물리적 특성에 대하여 조사하였다. DPCB는 FT-IR분석결과 1100~1200 파장에서 실리카 표면에 존재하는 Si-O 피크를 나타냈다. DPCB와 유기 실란커프링제 (Si69)를 함유하는 고무조성물의 가황속도는 순수 카본블랙을 함유한 고무조성물에 비해 지연되었다. Si69를 함유한 DPCB의 300% 모듈러스와 상호작용계수 ($a_f$)는 순수 카본블랙보다 높게 나타났으며, 내마모특성 지표인 피코 무게감소량은 일정하게 나타났다. DPCB의 $0^{\circ}C$에서의 tan ${\delta}$는 DPCB 50 phr 기준 실란커플링제를 2.0% 사용한 수준에서 순수 카본블랙보다 우수하였으며, $60^{\circ}C$에서의 tan ${\delta}$는 실란커프링제의 사용량이 증가 할수륵 감소하였다. 결국 본 연구에 사용된 DPCB는 일정한 마모저항을 유지하면서 회전저항을 개선하는데 적합하다고 생각한다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1995년도 추계 학술발표회
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• pp.127-127
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• 1995

• Carbon letters
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• 제7권2호
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• pp.87-96
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• 2006

This paper describes the physical properties of filled Nylon6 composites resin with nano-sized carbon black particle and graphite nanofibers prepared by melt extrusion method. In improving adhesions between resin and fillers, the surface of the carbon filler materials were chemically modified by thermo-oxidative treatments and followed by treatments of silane coupling agent. Crystallization temperature and rate of crystallization increased with increases in filler concentration which would act as nuclei for crystallization. The silane treatments on the filler materials showed effect of reduction in crystallization temperature, possibly from enhancement in wetting property of the surface of the filler materials. Percolation transition phenomenon at which the volume resistivity was sharply decreased was observed above 9 wt% of carbon black and above 6 wt% of graphite nanofiber. The graphite nanofibers contributed to more effectively in an increase in electrical conductivity than carbon black did, on the other hand, the silane coupling agent negatively affected to the electrical conductivity due to the insulating property of the silane. Positive temperature coefficient (PTC) phenomenon, was observed as usual in other composites, that is, temperature increase results conductivity increase. The dispersity of the fillers were excellently approached by melt extrusion of co-rotational twin screw type and it could be illustrated by X-ray diffraction and SEM.

• 폴리머
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• 제26권4호
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• pp.445-451
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• 2002

본 연구에서는 실리카의 표면처리를 위해 실란 커플링제인, ${\gamma}$-methacryloxy propyl trimethoxy silane (MPS), ${\gamma}$-glycidoxy propyl trimethoxy silane (GPS), and ${\gamma}$-mercapto propyl trimethoxy silane (MCPS) 등을 사용하여 실리카 흡착특성과 기계적 계면물성에 대하여 고착하였다. 실란처리에 따른 실리카의 평형 확산압력, 표면 자유에너지, 비표면적을 BET법을 이용한 $N_2$/77 K 기체 흡착을 통하여 알아보았다. 본 실험결과 신란처리에 의해 실리카 표면에 도입된 비극성 관능기로 인해 실리카의 비표면적, 평형 확산압력, 표면 자유에너지의 비극성 요소가 증가하였으며 결과적으로 실리카/고무 복합재료의 기계적 계면 물성인 tearing energy ($G_{mc}$)가 향상되었음을 확인할 수 있었다. 그리고 MPS로 표면처리한 경우가 GPS, MCPS에 비해서 우수한 기계적 계면물성을 나타남을 관찰할 수 있었다.