• 제목/요약/키워드: sigma phase

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Rice Crop Monitoring Using RADARSAT

  • Suchaichit, Waraporn
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.37-37
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    • 2003
  • Rice is one of the most important crop in the world and is a major export of Thailand. Optical sensors are not useful for rice monitoring, because most cultivated areas are often obscured by cloud during the growing period, especially in South East Asia. Spaceborne Synthetic Aperture Radar (SAR) such as RADARSAT, can see through regardless of weather condition which make it possible to monitor rice growth and to retrieve rice acreage, using the unique temporal signature of rice fields. This paper presents the result of a study of examining the backscatter behavior of rice using multi-temporal RADARSAT dataset. Ground measurements of paddy parameters and water and soil condition were collected. The ground truth information was also used to identify mature rice crops, orchard, road, residence, and aquaculture ponds. Land use class distributions from the RADARSAT image were analyzed. Comparison of the mean DB of each land use class indicated significant differences. Schematic representation of temporal backscatter of rice crop were plotted. Based on the study carried out in Pathum Thani Province test site, the results showed variation of sigma naught from first tillering vegatative phase until ripenning phase. It is suggested that at least, three radar data acquisitions taken at 3 stages of rice growth circle namely; those are at the beginning of rice growth when the field is still covered with water, in the ear differentiation period, and at the beginning of the harvest season, are required for rice monitoring. This pilot project was an experimental one aiming at future operational rice monitoring and potential yield predicttion.

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Theoretical Studies on the Gas-Phase Pyrolysis of Esters The effect of ${\alpha}$- and ${\beta}$-methylation of Ethyl Formates

  • Ikchoon Lee;Ok Ja Cha;Bon-Su Lee
    • Bulletin of the Korean Chemical Society
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    • v.11 no.1
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    • pp.49-54
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    • 1990
  • The gas-phase thermolysis reactions of ${\alpha}$- and ${\beta}$-methylated ethyl formates, Y = $CH-X-CHR_1CH_2R_2$ where X = Y = O or S and $R_1\;=\;R_2$ = H or $CH_3$, are investigated theoretically using the AM1 method. The experimental reactivity order is reproduced correctly by AM1 in all cases. The thermolysis proceeds through a six-membered cyclic transition state conforming to a retro-ene reaction, which can be conveniently interpreted using the frontier orbital theory of three-species interactions. The methyl group substituted at $C_{\alpha}\;or\;C_{\beta}$ is shown to elevate the ${\pi}$-HOMO of the donor fragment (Y = C) and depress the ${\sigma}^{\ast}$-LUMO of the acceptor fragment ($C_{\beta}$-H), increasing the nucleophilicity of Y toward ${\beta}$-hydrogen which in turn increases the reactivity. The two bond breaking processes of the $C_{\alpha}$-X and $C_{\beta}$-H bonds are concerted but not synchronous so that the reaction takes place in two stages as Taylor suggested. The initial cleavage of $C_{\alpha}$-X is of little importance but the subsequent scission of $C_{\beta}$-H occurs in a rate determining stage.

Transmission of Substituent Effects through Five-Membered Heteroaromatic Rings. III. Addition Equilibria of Hydroxide Anion to Benzaldehyde Analogues

  • Son, Chang Guk;Jeon, Yeong A;Lee, Sun Gi;Kim, Chang Geon;Kim, Chan Gyeong;Lee, Ik Chun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.12
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    • pp.1202-1206
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    • 2000
  • Transmission of substituent effects through 5-membered heteroaromatic rings is investigated theoretically at the RHF/6-31+G and B3LYP/6-31+G levels using the equilibria for the $OH^- addition to five-membered heteroaromatic aldehydes (5MHA). The transmission efficiency (S) in 5MHA(A) increases in the order NH>O>S>PH but the order exactly reverses in 5MHA($T^-$). This is originated by the delocalizability of the ${\pi}$ lonepair on Y, $$n_\pi$(Y)$. A better correlation is obtained with ${\sigma}_p^-$ in the Hammett plots with positive slope, $p_z$ > 0, indicating that the substituent (Z) effects are not transmitted by a direct conjugation. The magnitude of $p_z$ for Y=NH is the largest among the heteroaromatic systems, which is consistent with the largest transmission efficiency change $({\Delta}S)$. The equilibria for the addition processes are favorable in the gas phase $({\Delta}G^o<0)$, which reverses to unfavorable in aqueous solution $({\Delta}G^o>0)$ due to the relatively large salvation energy of $OH^-$ in the initial state in aqueous solution. The orders of ${\Delta}G^o$ and $p_z$ in the gas phase are almost maintained in solution.

A Study on DRL-based Efficient Asset Allocation Model for Economic Cycle-based Portfolio Optimization (심층강화학습 기반의 경기순환 주기별 효율적 자산 배분 모델 연구)

  • JUNG, NAK HYUN;Taeyeon Oh;Kim, Kang Hee
    • Journal of Korean Society for Quality Management
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    • v.51 no.4
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    • pp.573-588
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    • 2023
  • Purpose: This study presents a research approach that utilizes deep reinforcement learning to construct optimal portfolios based on the business cycle for stocks and other assets. The objective is to develop effective investment strategies that adapt to the varying returns of assets in accordance with the business cycle. Methods: In this study, a diverse set of time series data, including stocks, is collected and utilized to train a deep reinforcement learning model. The proposed approach optimizes asset allocation based on the business cycle, particularly by gathering data for different states such as prosperity, recession, depression, and recovery and constructing portfolios optimized for each phase. Results: Experimental results confirm the effectiveness of the proposed deep reinforcement learning-based approach in constructing optimal portfolios tailored to the business cycle. The utility of optimizing portfolio investment strategies for each phase of the business cycle is demonstrated. Conclusion: This paper contributes to the construction of optimal portfolios based on the business cycle using a deep reinforcement learning approach, providing investors with effective investment strategies that simultaneously seek stability and profitability. As a result, investors can adopt stable and profitable investment strategies that adapt to business cycle volatility.

Initial Characterization of yliH in Salmonella typhimurium

  • Park, Kyung-Hwa;Song, Mi-Ryung;Choy, Hyon-E.
    • Journal of Microbiology
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    • v.45 no.6
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    • pp.558-565
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    • 2007
  • Using microarray analysis, we determined those Salmonella genes induced at the entry of stationary phase, and subsequently discovered that uncharacterized yliH was induced most dramatically. We set out to establish the molecular mechanism underlying the stationary phase induction of yliH under the standard culture condition, LB with vigorous aeration, by analyzing its promoter activity in various mutant backgrounds, lacking stationary phase ${\sigma}$, $RpoS^-$, or stringent signal molecules ppGpp, ${\Delta}relA$ ${\Delta}spoT$. It was found that the stationary phase induction of yliHp was partially dependent on rpoS but entirely dependent on ppGpp. DNA sequence analysis revealed that the Salmonella yliH gene is composed of 381 base-pair nucleotides, with overall amino acid sequence revealing 76.38% amino acid identity and 88.98% similarity with Escherichia coli yliH, although no motif from data base was noted for its possible role. Recently however, it has been reported that yliH in E. coli was implicated in biofilm formation and motility by repressing these activities (Domka et al., 2006). We have constructed a mutant Salmonella deleting yliH gene by allele replacement and examined its phenotype, and found that the yliH in Salmonella more or less affects motility and adherence by enhancing these activities. The effect on biofilm formation in Salmonella was uncertain. Moreover, addition of cloned yliH of E. coli into Salmonella did not reduce motility or adherence. Taken together, it appears that the pathways implicating yliH for biofilm formation and motility in E. coli and in Salmonella are somewhat different.

Interaction Proteome Analysis of Major Intracellular Serine Protease 1 in Bacillus subtilis

  • Park Sun-Young;Park Byoung-Chul;Lee Ah-Young;Kho Chang-Won;Cho Say-Eon;Lee Do-Hee;Lee Baek-Rak;Myung Pyung-Keun;Park Sung-Goo
    • Journal of Microbiology and Biotechnology
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    • v.16 no.5
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    • pp.804-807
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    • 2006
  • Bacterial serine proteases, especially those from Bacillus, have been extensively studied. Intracellular serine protease 1 (Isp1) is responsible for most of the proteolytic activity in B. subtilis. To identify Isp1 substrates and study its physiological functions, a mutant of Isp1, which has lost the enzymatic activity, was constructed. Through a GST affinity chromatographic method, several Bacillus proteins that specifically interacted with S246A mutant Isp1 protein were isolated and then identified by MALDI-TOF analysis. ClpC and elongation factor Tu (EF-Tu) were among those proteins specifically bound to mutant Isp1. In addition, several proteins involved in stationary phase adaptive response (such as RNA polymerase sigma factor, spoIIIE) were also identified. These findings led us to suggest that the major function of this serine protease, whose expression is greatly increased during the stationary phase, is to mediate transition of the cell into the stationary phase in a proper and timely manner.

Sinterability of Low-Cost 3Y-ZrO2 Powder and Mechanical Properties of the Sintered Body

  • Kim, Min-Sung;Go, Shin-Il;Kim, Jin-Myung;Park, Young-Jo;Kim, Ha-Neul;Ko, Jae-Woong;Jung, Seung-Hwa;Kim, Jae-Yuk;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.54 no.4
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    • pp.285-291
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    • 2017
  • This study investigated the effects of grain size and phase constitution on the mechanical properties of $3Y-ZrO_2$ by varying the sintering conditions. The raw powder prepared by a low-cost wet milling using the coarse solid oxide powders was sintered by both pressureless sintering and hot-pressing, respectively. As increasing holding time at $1450^{\circ}C$ for pressureless sintering, it promoted the microstructural coarsening of matrix grains and the phase transformation to tetragonal phase, whereas the bimodal microstructure embedded with abnormal $cubic-ZrO_2$ grains was observed regardless of sintering time. On the other hand, the specimens hot-pressed at $1300^{\circ}C$ for 2 h reached ~ 97% of relative density with homogeneous fine microstructure and mixed phase constitution. It was found that the proportion of untransformed monoclinic zirconia had the most adverse effect on the biaxial strength compared to the impacts of grain size and density. The pressureless sintering of the low-cost powder for prolonged sintering time to 8 h led to a decent combination of mechanical properties ($H_V=13.2GPa$, $K_{IC}=8.16MPa{\cdot}m^{1/2}$, ${\sigma}=981MPa$).

A 12 mW ADPLL Based G/FSK Transmitter for Smart Utility Network in 0.18 ㎛ CMOS

  • Park, Hyung-Gu;Kim, Hongjin;Lee, Dong-Soo;Yu, Chang-Zhi;Ku, Hyunchul;Lee, Kang-Yoon
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.13 no.4
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    • pp.272-281
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    • 2013
  • This paper presents low power frequency shift keying (FSK) transmitter using all digital PLL (ADPLL) for smart utility network (SUN). In order to operate at low-power and to integrate a small die area, the ADPLL is adopted in transmitter. The phase noise of the ADPLL is improved by using a fine resolution time to digital converter (TDC) and digitally controlled oscillator (DCO). The FSK transmitter is implemented in $0.18{\mu}m$ 1-poly 6-metal CMOS technology. The die area of the transmitter including ADPLL is $3.5mm^2$. The power consumption of the ADPLL is 12.43 mW. And, the power consumptions of the transmitter are 35.36 mW and 65.57 mW when the output power levels are -1.6 dBm and +12 dBm, respectively. Both of them are supplied by 1.8 V voltage source. The frequency resolution of the TDC is 2.7 ps. The effective DCO frequency resolution with the differential MOS varactor and sigma-delta modulator is 2.5 Hz. The phase noise of the ADPLL output at 1.8 GHz is -121.17 dBc/Hz with a 1 MHz offset.

Correlation Development on Critical Power in a Spherical Narrow Gap (구형 간극에서의 임계 출력에 대한 상관식 개발)

  • Park, Rae-Joon;Ha, Kwang-Soon;Kim, Sang-Baik;Kim, Hee-Dong;Jeong, Ji-Hwan
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.235-240
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    • 2001
  • The CHFG (Critical Heat Flux in Gap) test results have been evaluated to quantify the critical power in hemispherical narrow gaps and a new correlation has been developed. The CHFG test results have shown that increases in the gap thickness and pressure lead to an increase in critical power. The pressure effect on the critical power was found to be much milder than predictions by CHF correlations of other researches. From the CHFG test results, a new correlation on critical power in the hemispherical gap has been developed using the non-dimensional parameters as follows: $$\frac{qCHF}{{\rho}g^hfg}{\cdot}4\sqrt{\frac{{\rho}_g^2}{g{\sigma}{\Delta}{\rho}}=\frac{0.1042}{1+0.1375({\rho}g/{\rho}l)^{0.21}(D/s)}$$ The developed correlation has been expanded to apply the spherical geometry using the Siemens/KWU's correlation.

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The Characteristics of Water Based Ferrofluid of Magnetite Prepared by Air Oxidation (공기산화법으로 제조한 Magnetite의 물분산매 자성 유체의 특성)

  • 신학기;장현명;한창덕;김태옥
    • Journal of the Korean Ceramic Society
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    • v.27 no.1
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    • pp.109-117
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    • 1990
  • Magnetite for Water-based ferrofluid was synthesized by air oxidation of aqueous suspension in the pH range 7-12 at $65^{\circ}C$. The optimum condition of magneite formation was delineated by examining various physicochemcial properties such as Fe2+ content, phase characteristics, MHC and $\sigma$max. The point of zero charge of iron oxide powders obtained at various pH conditions were correlated with the oxidation state of Fe in the iron oxide. The magnetite powder prepared at pH 9 ws dispersed using sodium oleate and sodium dodecylbenzenesulfonate (SDBS) as dispersants, and the dispersion characteristics of the magnetite ferrofluid were examined by means of the fraction of solid dispersed, zeta potential data and FT-IR spectrum. A simple calculation on the potential energy of two interacting magnetite particles showed that the dispersion stability was directly correlated with height of the potential energy barrier or the shape of zeta potential.

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