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Physicochemical Properties of Organic Sludge Discharged from an Industrial Complex in Ulsan (울산지역 산업단지에서 배출되는 유기성슬러지의 물리.화학적 특성)

  • Lee, Gang-Woo;Kim, Min-Choul;Lee, Jae-Jeong;Lee, Man-Sig;Kim, Ji-Won;Park, Hung-Suck;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1760-1767
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    • 2008
  • In this study, we analyzed the physical and chemical properties such as proximate analysis, ultimate analysis, heating values, and thermogravimetric analysis for the organic sludges discharged from an industrial complex in Ulsan. The average water, combustible, and ash content of organic sludges were 72.9, 18.5, and 8.6%, respectively. And according to the ultimate analysis of organic sludges, the C, O, H, N, and S compositions were 33.9, 26.4, 4.4, 4.4, and 0.6%, respectively. According to the results of investigating the lower heating values, 6 sludges were on the range of $1,500{\sim}2,000\;kcal/kg$ and 4 sludges were on the range of over 2,000 kcal/kg. Therefore, these 10 sludges could be directly applied to industries which try to use the energy by direct incineration.

Proteomics Approach on Puroindoline Gene of Pre-harvest Sprouting Wheat

  • Kamal, Abu Hena Mostafa;Park, Cheol-Soo;Heo, Hwa-Young;Chung, Keun-Yook;Cho, Yong-Gu;Kim, Hong-Sig;Song, Beom-Heon;Lee, Chul-Won;Woo, Sun-Hee
    • Korean Journal of Breeding Science
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    • v.41 no.3
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    • pp.205-212
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    • 2009
  • Wheat (Triticum aestivum L.) grain texture is an important determinant of milling properties and end product use. Two linked genes, puroindoline a (PINA) and puroindoline b (PINB), control most of the genetic variation in wheat grain texture. Wheat seed proteins were examined to identify PINA and PINB gene using two pre-harvest sprouting wheat cultivars; Jinpum (resistant) and Keumgang (susceptible).Wheat seed proteins were separated by two-dimensional electrophoresis with IEF gels over pH ranges: pH 3-10. A total of 73 spots were digested with trypsin resulting peptide fragmentation were analyzed by matrix assisted laser desorption/ionization-time of flight mass spectrometry (MALDI-TOF/MS). Mass spectra were automatically processed and searched through NCBInr, SWISS-PORT and MSDB database with mono isotopic masses and complete gene sequence were found by UniProt database. Puroindoline a and puroindoline b that is responsible for grain texture related with baking performance and roughness. Two spots were found Pin b (16.7 kDa) and Pin a (16.3 kDa) in Jinpum compare to seven spots were identified Pin a (16.1 kDa, 16.3 kDa) and Pin b (16.7 kDa, 9.5 kDa and 14.4 kDa) in Keumgang. Some selected spots were identified puroindoline like grain softness protein (16.9 kDa, 17 kDa and 18.1 kDa) in Keumgang. Moreover, to gain a better inferring the identification of puroindoline related proteins using proteomics, we accomplished a complete gene sequence of PINA and PINB gene in pre-harvesting sprouting wheat seeds between resistant (Jinpum) and susceptible (Keumgang).

An Empirical Study on the Effects of CSR Activities on Organization Trust and Job Satisfaction in Enterprises (기업의 CSR 활동이 조직신뢰와 직무만족에 미치는 영향에 관한 실증연구)

  • Jung, Doo-Sig;Yang, Hang-Jin
    • Journal of Digital Convergence
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    • v.19 no.10
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    • pp.545-554
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    • 2021
  • The purpose of this study was to empirically examine the effects of CSR activities on a defense manufacturing employees' organizational trust and job satisfaction and the mediating effect of organizational trust. To conduct such examinationusing, 289 valid samples collected from field employees of H-company(defense manufacturer) in Chang Won. The empirical analysis results are summarized as follows. First, corporate CSR activities were found to affect job satisfaction of field employees. Second, corporate CSR activities were analyzed to be a very important motivator for field employees. In other words, it can be interpreted that employees who perceive that their organization is actively fulfilling social responsibilities have a high level of perception of organizational trust. Third, it was found that the higher the organizational trust of the employees, the higher the job satisfaction. Fourth, as a result of verifying whether there is a mediating effect of organizational trust in the relationship between corporate CSR activity and job satisfaction, it was found that the full mediating effect and the partial mediating effect were mixed.

Simultaneous Spectrophotometric Determination of Cr(Ⅲ) and Cr(Ⅳ) in Chromium Plating Solution via Flow-Through Analysis (흐름계를 이용한 크롬도금 용액의 Cr(Ⅲ)와 Cr(Ⅵ)의 분광학적 동시 분석 방법)

  • Kim, Sun Kwan;Nam, Hakhyun;So, Jae Chun;Lee, Won;Cha, Geun Sig;Han, Sang Hyun
    • Journal of the Korean Chemical Society
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    • v.39 no.2
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    • pp.87-93
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    • 1995
  • The amount of Cr(Ⅲ) and Cr(Ⅵ) in a chromium plating solution could be determined simultaneously within five minutes using UV/VIS spectrophotometer coupled with a flow-through analysis(FTA) setup. The λmax's at 580 nm and 440 nm which correspond to Cr(Ⅲ) and Cr(Ⅵ), respectively, well obey the Beer-Lambert law in the range over 0.05 g/L for Cr(Ⅲ) and 0.005 g/L for Cr(Ⅵ). when the pH of the sample is less than 4.0, the absorption extinction coefficients of those peaks are not much dependent on the proton concentration. The amount of Cr(Ⅲ) and Cr(Ⅵ), and the total chromium in post treatment chromium plating solution, which normally has few g/L of Cr concentration, could be easily measured using UV/VIS spectrophotometry after the sample had been diluted with sulfuric acid of pH=1.0 in the flow-through analysis setup; this method is far more convenient and faster than the common redox titration (which requires at least 40 min/sample) method, while the accuracy of the method is highly comparable to conventional titrimetric method. Since the implementation of an PTA-UV/VIS setup in any plating industry is cost effective and easy to operate, the analytic method described in this paper may be applied directly for in situ analysis of plating solutions.

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Relationships between Cellulose Decomposition and Soil Environmental Factors in Three Coniferous Plantations (3수종의 침엽수조림지내 셀룰로오스 분해와 토양 환경요인과의 관계)

  • Kim, Choon-Sig
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.1
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    • pp.39-44
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    • 2012
  • This study was carried out to determine the relationships between cellulose decomposition and soil environmental factors in larch (Larix leptolepis) and pine (red pine: Pinus densiflora; rigitaeda pine: P. rigida ${\times}$ P. taeda) species planted in the same year (1963). The variation of cellulose mass loss with soil temperature, soil pH, soil $CO_2$ efflux rates, and soil water content was measured monthly for 4 months (July, August, September and October 2006) from three coniferous plantations. Mean mass loss rates during the study period were generally more rapid in rigitaeda pine (6.5 $mg\;g^{-1}\;day^{-1}$) than in red pine (6.2 $mg\;g^{-1}\;day^{-1}$) or larch (6.1 $mg\;g^{-1}\;day^{-1}$) plantations, although the mass loss rates were not significantly different among three tree species (P > 0.05). Cellulose mass loss rates among three tree species were positively correlated with soil temperature (red pine: r = 0.77, P < 0.05; rigitaeda pine: r = 0.59, P < 0.05; larch: r = 0.48, P < 0.05) at the 20 cm soil depth, while the mass loss rates were negatively correlated with soil pH (red pine: r = -0.63, P < 0.05; rigitaeda pine: r = -0.47, P < 0.05; larch: r = -0.43, P < 0.05). There was a significant correlation between cellulose mass loss and soil $CO_2$ efflux rates except for regitaeda pine plantation, while no significant correlation (P > 0.05) between cellulose mass loss and soil water content in larch or rigitaeda pine. The results suggest that cellulose mass loss rates in soil layers depend on the different soil environmental factors caused by tree species.

Soil and Leaf Nutrient Properties by Establishment Periods of Chesnut (Castanea crenata Sieb. et. Zucc.) Orchards in Sancheong-gun (경상남도 산청군 밤나무 재배지의 조성 기간에 따른 토양 및 잎 양분 특성)

  • Kim, Choon-Sig;An, Hyun-Chul;Cho, Hyun-Seo;Lim, Jong-Taek;Byun, Jae-Kyeong
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1137-1143
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    • 2011
  • Optimum soil management of chestnut orchards is important to ensure high quality and yields of chestnut. This study was conducted to evaluate soil and green leaf characteristics by establishment periods of chestnut (Castanea crenata Sieb. et. Zucc.) orchards in Sancheong-gun, Gyeongsangnam-do. Total 30 plots with the criteria of similar cultivation practices were chosen and classified into two establishment periods by over 20-year-old orchards (17 plots) and below 19-year-old orchards (13 plots). Soil bulk density was significantly higher (p<0.05) in over 20-year-old ($1.16g\;cm^{-3}$) than in below 19-year-old ($1.03g\;cm^{-3}$) plots. Soils in over 20-year-old plots were severely acidified with pH 4.56 compared to pH 4.73 in below 19-year-old plots. However, soil organic matter, total nitrogen, available phosphorus, and potassium were not significantly different (p>0.05) between both establishment periods. Leaf area, leaf mass, and nutrient (N, P, K, Ca, Mg) concentration of green leaves were also not significantly different (p>0.05) between both establishment periods. The results indicate that soil bulk density in chestnut orchards is dependent on the establishment periods, while soil chemical property and leaf nutrient concentration may be little influenced by the establishment periods.

Synthesis and Characterization of Zeolite Using Water Treatment Sludge (정수슬러지를 이용한 제올라이트의 합성 및 특성연구)

  • Ko, Hyun Jin;Ko, Yong Sig
    • Clean Technology
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    • v.26 no.4
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    • pp.263-269
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    • 2020
  • Zeolite was synthesized hydrothermally using the water-treatment sludge, and the effects of various synthesis parameters like reaction temperature, reaction time, and Na2O/SiO2 molar ratio on the crystallization of zeolite were investigated. Crystal structure, physical property, and thermal stability of zeolite crystals were characterized by X-ray powder diffraction, FTIR spectroscopy, BET nitrogen adsorption, and TGA measurements. The removal efficiencies of nitrogen in ammonia, heavy metal ions, and TOC were calculated to evaluate zeolite's adsorption capacity. The primary chemical composition of water-treatment sludge was 28.79% Al2O3 and 27.06% SiO2. The zeolites were synthesized by merely employing the water-treatment sludge as silica and alumina sources without additional chemicals. Zeolite crystals synthesized through the water-treatment sludge were confirmed as an A-type zeolite structure. Zeolite A had the highest crystallinity obtained from a gel with the molar composition 2.1Na2O-Al2O3-1.6SiO2-65H2O after 5 h at a temperature of 90 ℃. The specific surface area of zeolite obtained was 55 ㎡ g-1, which was higher than commercial zeolite A. The removal efficiency of nitrogen in ammonia was 68% after 3 h of reaction time, while the removal efficiencies of Pb2+ and Cd2+ ions were 99.1% and 99.3%, respectively. These results indicate active ion exchange between Pb2+ or Cd2+ ion and Na+ ion in the zeolite framework. The adsorption experiments on the different zeolite addition conditions were performed for 3 h with 300 ppm humic acid. Based on the results, TOC's highest efficiency was 83% when 5 g of zeolite was added.

Planar microchip-based lactate biosensor (평면 소자형 락테이트 바이오센서)

  • Ha, Jeonghan;Huh, Hwang;Kang, Tae Young;Lee, Yong Seok;Yoon, Soon Ho;Shin, Jungwon;Nam, Hakhyun;Cha, Geun Sig
    • Analytical Science and Technology
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    • v.19 no.6
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    • pp.482-489
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    • 2006
  • Two electrode-based lactate biosensor was prepared by immobilizing lactate oxidase (LOD) obtained from pediococcus species in a poly(vinyl alcohol). Hydrogen peroxide ($H_2O_2$) produced by the reaction of lactate and LOD was detected on the Pt-black that was electrochemically deposited on the Au electrode. Sensors fabricated with Pt-black deposited Au electrode provided a high current of $H_2O_2$ oxidation at a substantially lowered applied potential (+300 mV vs. Ag/AgCl), resulting in reduced interferences from easily oxidizable species such as ascorbic acid, acetaminophen, and uric acid. An outer membrane is formulated by adjusting water uptake of hydrophilic polyurethane (HPU). The sensor performance was evaluated in vitro with both flow-through arrangement and static mode. The sensor showed a linear range from 0.1 mM to about 9.0 mM in 0.05 M phosphate buffer (pH 7.6) containing 0.05 M NaCl. Storing the sensors prepared in this work at $4^{\circ}C$ buffer solution while not in use, they provided same electrochemical performance for more than 25 days.

Characteristics of Monascus Natural Pigments Produced by Monascus sp. MK2-2 (Monascus sp. MK2-2가 생산하는 홍국천연색소의 특성)

  • Jeon, Chun-Pyo;Kim, Chang-Suk;Lee, Jung-Bok;Shin, Ji-Won;Choi, Sung-Yeon;Choi, Chung-Sig;Lee, Oh-Seuk;Kwon, Gi-Seok
    • Journal of Life Science
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    • v.17 no.1 s.81
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    • pp.137-142
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    • 2007
  • For the production of natural pigments with microbe, the strains which produced monascus pigment were isolated, and then culture condition and extraction condition were investigated. These results are summarized as follows; The strain which ran produce monascus natural pigment was isolated from natural microbial sources and we made mutant of this strain with UV($235_{nm}$, 30 second) irradiation. The mutant was identified as Monascus sp. MK2-2. The optimal culture conditions were investigated optimal medium containing 0.3% rice powder, 0.2% yeast extract, 0.3% $NH_4H_2PO_4$ and $30^{\circ}C$ in a rotary shaker (120 rpm) for 5 days (initial pH 5.0), while the pigment production was determined at 24 hr intervals. The effective carbon sources were wheat flour > rice powder > fructose, and effective nitrogen sources were sodium nitrate > $KNO_3$ for production of the monascus natural pigment. The pigment capacity is good from 17 to 22 in C/N ratio. The production amount of monascus natural pigment was 0.38 g per 1 kg of rice. Also, extract of red yeast rice had anti-thrombosis activity like a degree of aspirin.

Concentration of Polycyclic Aromatic Hydrocarbons in Cereals, Pulses, Potatoes, and their Products (곡류, 두류, 서류 및 그 가공품 중 다환 방향족 탄화수소 (polycyclic aromatic hydrocarbons) 화합물 함량)

  • Kim, Hee-Yun;Chung, So-Young;Sho, Yo-Sub;Park, Seong-Soo;Lee, Eun-Ju;Suh, Jung-Hyuk;Lee, Yun-Dong;Choi, Woo-Jeong;Kim, Jung-Soo;Eom, Ji-Yoon;Park, Hui-Og;Jin, Myeong-Sig;Kim, Dong-Sul;Ha, Sang-Chul;Lee, Jong-Ok
    • Korean Journal of Food Science and Technology
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    • v.37 no.4
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    • pp.537-541
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    • 2005
  • Estimation of concentrations of PAHs [benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene, indeno(1,2,3-c,d)pyrene] in cereals, pulses, potatoes, and their products available in Korean markets gave mean levels of 0.13, 0.08, 0.06, 0.03, 0.08, 0.15, 0.45, and $0.14{\mu}g/kg$, respectively, with recoveries between 82.6-106.6%. Methodology involved saponification and extraction with n-hexane, purification on Sep-Pak Florisil cartridges, and high performance liquid chromatography using a fluorescence detector.