• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.266.1-266.1
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• 2013

Large-scale single-crystal organic nanowire arrays were generated using a direct printing method (liquidbridge- mediated nanotransfer molding) that enables the simultaneous synthesis, alignment and patterning of nanowires from molecular ink solutions. Using this method, single-crystal organic nanowires can easily be synthesized by self-assembly and crystallization of organic molecules within the nanoscale channels of molds, and these nanowires can then be directly transferred to specific positions on substrates to generate nanowire arrays by a direct printing process. Repeated application of the direct printing process can be used to produce organic nanowire-integrated electronics with two- or three-dimensional complex structures on large-area flexible substrates. This efficient manufacturing method is used to fabricate all-organic nanowire field-effect transistors that are integrated into device arrays and inverters on flexible plastic substrates.

• 멤브레인
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• 제25권4호
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• pp.332-342
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• 2015

본 연구는 역삼투막의 막오염을 해결하기 위하여 실란-에폭시 층을 형성시킨 다층 표면개질법을 이용하여 역삼투막의 내오염성을 향상시키고자 하였다. Sol-gel법을 이용하여 Octyltrimethoxysilane (OcTES)을 막 표면에 가교를 통해 고분자화 하였으며 n = 8인 OcTES의 알킬기가 자발적인 self-assembly를 통하여 막 표면에 가지구조를 형성시켰다. 그 위에 ethylene glycol diglycidyl ether (EGDE)의 ether기를 ring-opening을 통해 막 표면에 친수성을 부여하여 역삼투막의 내오염성을 향상시키고자 하였다. FE-TEM, AFM을 이용하여 막의 단면 및 표면구조 분석을 하였고 막 표면의 ridge and valley 구조와 OcTES, EGDE의 다층 표면개질로 인한 bridge 구조를 확인하였으며, 거칠기의 증가를 통해 막 표면의 가지가 잘 형성되었음을 확인하였다. XPS를 통하여 막 표면의 화학구조에 대한 관찰과 표면개질이 잘 이루어졌음을 확인하였으며, contact angle 분석을 통해 표면개질막의 표면에 친수성이 부여되었음을 확인하였다. EGDE 표면개질 조건 최적화를 진행한 결과 EGDE 농도는 0.5 wt%, ring-opening 온도는 $70^{\circ}C$가 가장 적합하였고, 내오염성 실험 결과 및 막오염지수(MFI)는 SUL-H10, $PA-OcTES_{1.0}$, $PA-OcTES_{1.0}-EGDE_{0.5}$이 68.7, 60.4, 5.4 ($10E-8hr/mL^2$)로 나타나 다층 표면 개질막의 내오염성이 매우 향상되었음을 확인할 수 있었다.

• 한국산학기술학회논문지
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• 제8권1호
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• pp.96-102
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• 2007

용접에 의해서 발생하는 변형은 강구조물의 치수를 변화시킬 뿐 아니라 역학적 강도를 저하시켜 강구조물의 제작공정과 공용중 심각한 문제를 발생시킬 수 있다. 특히 토목 강구조물의 경우 제작 및 조립공정에서 용접프로세스에 의해 불가피하게 발생하는 용접변형에 의한 설계치수의 변화를 검토하기 위해 넓은 장소에서 부분 또는 전체가 조립공정을 실시해야 한다. 이러한 가조립된 구조물은 현장에 설치되기 위해 해체하여 운반되어 현장에서 재조립하여 가설된다. 또한 높은 곳에서 작업해야 하므로 안전사고의 우려와 함께 크레인, 족장과 같은 부대장비를 사용해야 하므로 비경제적이다. 따라서 대형 강구조물의 제작시 발생하는 용접변형에 의한 부재오차를 검증하기 위한 가조립 공정을 생략하기 위해 용접변형 예측기법의 개발이 요구된다. 본 연구에서는 이를 위해 대형 강구조물의 용접변형 예측기법인 등가하중법을 이용한 용접부 수치모델링을 정립하고 이를 이용해 용접순서와 자중이 용접변형에 미치는 영향을 검토하였다.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1891-1896
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• 2010

Submicron-sized polymeric colloidal particles can self assemble into 3-dimensional (3D) opal structure which is a useful template for photonic crystal. Narrowly dispersed polymer microspheres can be synthesized by emulsion polymerization in water using water-soluble radical initiator. In this report, we demonstrate a facile and reproducible emulsion polymerization method to prepare various polymeric microspheres within 200 - 400 nm size ranges which can be utilized as colloidal photonic crystal template. By controlling the amount of monomer and surfactant, monodisperse polymer colloids of polystyrene (PS) and acrylates with various sizes were successfully prepared without complicated synthetic procedures. Such polymer colloids self-assembled into 3D opal structure exhibiting bright colors by reflection of visible light. The colloidal particles and the resulting opal structures were rigorously characterized, and the wavelength of the structural color from the colloidal crystal was confirmed to have quantitative relationship with the size of constituting colloidal particles as predicted by Bragg equation. The tunability of the structural color was achieved not only by varying the particle size but also by infiltration of the colloidal crystal with liquids having different refractive indices.

• 한국세라믹학회지
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• 제42권7호
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• pp.497-502
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• 2005

This study investigated the effects of the substrate and powder content on the fabrication of SiO$_{2}$ photonic crystals by evaporation method. Photonic crystals were self-assembled on quartz, Corning 1737 glass, slide glass, and ITa glass to verify the effects of the wetting angle and surface morphology. The powder contents of the solution were varied from 0.2 to 2.0 wt$\%$. The number of photonic crystal layers increased according to the decrease of wetting angle and surface roughness. The resultant photonic crystals showed the best optical characteristics when the number of photonic crystal layers was within 40 and 50. In addition, the intensity peak of Fabry¡?Perot fringes increased when the wetting angle was large and the particle size was small. Photonic crystals coated on ITO glass showed the highest reflectance peak of 63$\%$ relative intensity.

• Archives of Pharmacal Research
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• 제27권5호
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• pp.562-569
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• 2004

Self-assembling nanospheres of hydrophobized pullulan have been developed. Pullulan acetate (PA), as hydrophobized pullulan, was synthesized by acetylation. Carboxymethylated poly(ethylene-glycol) (CMPEG) was introduced into pullulan acetate (PA) through a coupling reaction using N, N'-dicyclohexyl carbodiimide (DCC). A synthesized PA-PEG-PA (abbreviated as PEP) conjugate was confirmed by Fourier transform-infrared (FT-IR) spectroscopy. Since PEP conjugates have amphiphilic characteristics in aqueous solution, polymeric nanoparticles of PEP conjugates were prepared using a simple dialysis method in water. From the analysis of fluorescence excitation spectra primarily, the critical association concentration (CAC) of this conjugate was found to be 0.0063 g/L. Observations by scanning electron microscopy (SEM) showed the spherical morphologies of the PEP nanoparticles. The particle size distribution of the PEP conjugates was determined using photon correlation spectroscopy (PCS) and the intensity-average particle size was 193.3 ${\pm}$ 13.53 nm with a unimodal distribution. Clonazepam (CNZ), as a model drug, was easy to entrap into polymeric nanoparticles of the PEP conjugates. The drug release behavior was mainly diffusion controlled from the core portion.

• 한국소음진동공학회논문집
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• 제20권1호
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• pp.98-105
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• 2010

Squeal, a kind of self-excited vibration, is generated by the friction between the disc and the friction materials. It occurs at the ending stage of the braking process, and radiates and audible frequency range of 1 kHz to 10 kHz. Squeal is generated from unstability because of the coupling between the translation and rotation of the system. This instability is caused by the follower force and follower force is normal component of the friction force. In this paper modal analysis of wheel brake system was performed in order to predict the squeal phenomenon. It was shown that the prediction of system instability is possible by FEM. A finite element model of that brake system was made. Some parts of a real brake was selected and modeled. Modal analysis method performs analyses of each brake system component. Experimental modal analysis was performed for each brake components and experimental results were compared with analytical results from FEM. To predict the dynamic unstability of a whole system, the complex eigenvalue analysis for assembly modeling of components confirmed by modal analysis is performed. The finite element models of the disk brake assembly have been constructed, and the squeal noise problems have been solved by complex eigenvalue analysis. The complex eigenvalue analysis results compared with real train test.

• Steel and Composite Structures
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• 제31권3호
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• pp.217-232
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• 2019

Modular steel buildings consist of prefabricated room-sized structural units that are manufactured offsite and installed onsite. The inter-module connections must fulfill the assembly construction requirements and soundly transfer the external loads. This work proposes an innovative assembled connection suitable for modular buildings with concrete-filled steel tube columns. The connection uses pretensioned strands and plugin bars to vertically connect the adjacent modular columns. The moment-transferring performance of this inter-module connection was studied through monotonic and cyclic loading tests. The results showed that because of the assembly construction, the connected sections were separated under lateral bending, and the prestressed inter-module connection performed as a weak semirigid connection. The moment strength at the early loading stage originated primarily from the contact bonding mechanism with the infilled concrete, and the postyield strength depended mainly on the tensioned strands. The connection displayed a self-centering-like behavior that the induced deformation was reversed during unloading. The energy dissipation originated primarily from frictional slipping of the plugin bars and steel strands. The moment transferring ability was closely related to the section dimension and the arrangements of the plugin bars and steel strands. A simplified strength calculation and evaluation method was also proposed, and the effectiveness was validated with the test data.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 춘계학술대회논문집
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• pp.434-438
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• 2003

The shearing process for the sheet metal is normally used in the precision elements such as semi-conductor components. In these precision elements, the burr formation brings a bad effect on the system assembly and demands the additional de-burring process. In this paper, we have developed the desktop-type precision punching system to investigate the burr formation mechanism and present kinematically Punch-die auto aligning methodology, for the purpose of burr unifomizing and minimizing, between the rectangular shaped punch and die. By using the scanning electron microscope, the aligned punching results are compared with the miss-aligned ones. Also, we measured the relative burr heights using the self-designed laser measuring device for insitu self aligning. Since it is hard to get the perfect, so called, burr-free edges during the shearing process, we introduced the ultrasonic do-burring machine. The de-burring operation was carried out by a novel do-burring method, the reversal flow resistance method, under different machining loads and abrasive types. The final do-burring results show the validity of our punching do-burring system pursuing the burr-free punched elements.

• Bulletin of the Korean Chemical Society
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• 제24권5호
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• pp.593-599
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• 2003

The nanoparticle magnetite of which diameter was about 3 nm was synthesized in a homogeneous aqueous solution without a template. The synthesized magnetite nanoparticle was easily oxidized to maghemite in an ambient condition. The magnetic properties of the ferrite nanoparticle show superparamagnetism at room temperature and its blocking temperature is around 93 K. Modifying the sequential adsorption method of metal bisphosphonate, we have prepared a multilayer thin film of the ferrite nanoparticle on planar substrates such as glass, quartz and Si wafer. In this multilayer the ferrite nanoparticle layer and an alkylbisphosphonate layer are alternately placed on the substrates by simple immersion in the solutions of the ferrite nanoparticle and 1, 10-decanediylbis (phosphonic acid) (DBPA), alternately. This is the first example, as far as we know, of nanoparticle/alkyl-bisphosphonate multilayer which is an analogy of metal bisphosphonate multilayer. UV-visible absorption and infrared reflection-absorption studies show that the growth of each layer is very systematic and the film is considerably optically transparent to visible light of 400-700 nm. Atomic force microscopic images of the film show that the surface morphology of the film follows that of the substrate in μm-scale image and the nanoparticle-terminated surface is differentiated from the DBPA-terminated one in nm-scale image. The magnetic properties of this ferrite/DBPA thin film are almost the same as those of the ferrite nanoparticle powder only.