• Title/Summary/Keyword: segregation

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The effect of carbon content on hot cracking of low carbon steel weld (저탄소성 용접금속의 응고균열에 미치는 탄소함량의 영향)

  • ;;Masumoto, I.
    • Journal of Welding and Joining
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    • v.6 no.4
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    • pp.16-26
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    • 1988
  • The effect of carbon content on hot cracking of welded carbon steel was investigated Eight steel plates whose carbon content range from 0.02 to 0.23 percent were welded by autogeous gas tungsten are process. Constant strain was applied to the hot crack test specimen under the strain rate of 0.15 mm per second during welding. The hot cracking susceptibility ws high in the rnage of 0.02-0.05 and 0.12-0.23 percent carbon contents. The critical carbon content immune to hot cracking is in the range from 0.07 to 0.12 percent carbon. By electron probe microanalyser, amanganese segregation was not seen significantly in the whole carbon range. But segregation of silicon was higher in the region of low carbon contents. However, sulphur was segregated remarkably in the region betwen 0.18 and 0.23 percent carbon by peritectic reaction. Very smal lamount of dnedritic structure was observed in the region from 0.02 to 0.05 percent carbon by peritectic reaction. Very small amount of dendritic structure was observed in the region from 0.02 to 0.05 percent carbon but the predominant solidification structure was smooth by cellular growth. The higher the carbon content is, the more the columnar dendritic structure was observed.

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Strength Characteristics of Concrete Subjected In Horizontal Continuous Vibration During Initial Curing (초기양생중에 수평연속진동을 받은 콘크리트의 강도특성)

  • 장희석;김명식;김종수;한중기
    • Journal of the Korea Concrete Institute
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    • v.13 no.5
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    • pp.423-429
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    • 2001
  • In this study, strength characteristics of concrete specimens subjected to horizontal continuous vibration during initial curing were investigated. As experimental variables, vibration velocity(0.25, 0.5, 1.0, 2.0, 4.0 kine) and vibration time(3, 6, 12, 24 hrs) were used. Density and segregation of the specimens were also investigated. Vibrating was started soon after placing, and strengths investigated consist of compressive strength, splitting tensile strength, and bond strength. Strengths decrease were hardly occurred at 0.25 kine vibration velocity regardless of vibration times and all strengths were increased for 3 hrs vibration at 0.5 kine vibration velocity. Density was increased for all specimens due to the vibration and there was no serious segregation under even 4 kine vibration velocity.

Investigation of Catalytic Activity Through Controlling Its Size and Composition of RhPt Bimetallic Nanoparticles (RhPt 이종금속 나노입자의 크기 및 조성 제어를 통한 촉매 활성도에 관한 연구)

  • Park, Jeong-Young;Kim, Sun-Mi
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.538-545
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    • 2011
  • This study shows that catalytic activity of bimetallic RhPt nanoparticle arrays under CO oxidation can be tuned by varying the size and composition of nanoparticles. The tuning of size of RhPt nanoparticles was achieved by changing concentration of rhodium and platinum precursors in one-step polyol synthesis. Two-dimensional RhPt bimetallic nanoparticle arrays in different size and composition were prepared through Langmuir-Blodgett thin film technique. CO oxidation was carried out on these two-dimensional nanoparticle arrays, revealing higher activity on the smaller nanoparticles compared to the bigger nanoparticles. X-ray photoelectron spectroscopy (XPS) results indicate the preferential surface segregation of Rh compared to Pt on the smaller nanoparticles, which is consistent with the thermodynamic analysis. Because the catalytic activity is associated with differences in the rates of $O_2$ dissociative adsorption between Pt and Rh, this paper suppose that the surface segregation of Rh on the smaller bimetallic nanoparticles is responsible for the higher catalytic activity in CO oxidation. This result suggests a control mechanism of catalytic activity via synthetic approaches of colloid nanoparticles, with possible application in rational design of nanocatalysts.

Cu-In-Ga 금속 전구체의 셀렌화 공정시 발생하는 Ga-segregation 억제에 관한 연구

  • Mun, Dong-Gwon;An, Se-Jin;Yun, Jae-Ho;Gwak, Ji-Hye;Jo, A-Ra;An, Seung-Gyu;Sin, Gi-Sik;Yun, Gyeong-Hun;Lee, Hui-Deok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.46.2-46.2
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    • 2011
  • CuInSe2 (CIS)계 화합물은 3족 원소(Ga, Al) 또는 6족 원소(S)를 첨가하여 밴드갭 조절이 가능하다는 장점을 가지고 있다. 실제로 동시 증발법으로 Ga을 첨가하여 만든 CuIn0.7Ga0.3Se2(CIGS) 태양전지는 약20%의 높은 효율 보이고 있다. 그러나 최고 효율을 달성한 동시 증발법은 대면적화가 어렵다는 점이 상용화의 걸림돌로 작용하고 있다. 따라서, 그 대안으로 대면적화가 용이한 스퍼터링 및 셀렌화 공정 연구가 진행되고 있다. 그러나 스퍼터링/셀렌화 공정은 Cu-In-Ga 금속 전구체의 셀렌화 시 Ga이 Mo쪽으로 이동하여 CIS/CGS 2개의 상으로 형성된다는 큰 단점을 갖고 있다. 이를 해결하기 위해 셀렌화 후 다시 H2S 기체 분위기에서 열처리하여 표면 밴드갭을 증가시키는 공정이 사용되고 있으나, 이는 열처리 과정이 2번 필요하다는 단점을 갖고 있다. 이러한 단점을 해결하고자 본 연구에서는 금속 전구체의 구조, 셀렌화 공정 조건 및 전구체 내의 상(phase) 조절을 통해 셀렌화 시 Ga segregation을 억제하고자 하였다. 특히 전구체의 상 조절을 통해서 Ga의 이동을 크게 완화시킬 수 있음을 확인하였다.

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Microstructure and Hardness of 1st layer with Crystallographic Orientation of Solidification Structure in Multipass Weld using High Mn-Ni Flux Cored Wire (고(<24%)Mn 플럭스코어드와이어를 사용한 다층 용접 시 초층 응고조직의 결정면방위에 따른 미세조직과 경도)

  • Han, Il-Wook;Eom, Jung-Bok;Yun, Joong-Gil;Lee, Bong-Geun;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.77-82
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    • 2016
  • In this study, Microstructure and hardness of 1st layer with crystallographic orientation were investigated about solidification structure in multipass weld using high Mn-Ni flux cored wire. Microstructure of solidification consisted of austenite matrix and a little ${\varepsilon}-phase$ in grain boundaries. Orientation of grains was usually (001), (101), (111). According to crystallographic orientation, morphology of primary dendrite was different. The depletion of Fe and the segregation of Mn, C, Ni, Si, Cu, Cr, O were found along the grain boundaries. The area of segregation was wide with an order of (001), (101), (111) grains. And hardness of grains with crystallographic orientation increased with an order of (001), (101), (111) grains because of the segregation along dendrite boundary.

Impact of Segregation Layer on Scalability and Analog/RF Performance of Nanoscale Schottky Barrier SOI MOSFET

  • Patil, Ganesh C.;Qureshi, S.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.1
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    • pp.66-74
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    • 2012
  • In this paper, the impact of segregation layer density ($N_{DSL}$) and length ($L_{DSL}$) on scalability and analog/RF performance of dopant-segregated Schottky barrier (DSSB) SOI MOSFET has been investigated in sub-30 nm regime. It has been found that, although by increasing the $N_{DSL}$ the increased off-state leakage, short-channel effects and the parasitic capacitances limits the scalability, the reduced Schottky barrier width at source-to-channel interface improves the analog/RF figures of merit of this device. Moreover, although by reducing the $L_{DSL}$ the increased voltage drop across the underlap length reduces the drive current, the increased effective channel length improves the scalability of this device. Further, the gain-bandwidth product in a common-source amplifier based on optimized DSSB SOI MOSFET has improved by ~40% over an amplifier based on raised source/drain ultrathin-body SOI MOSFET. Thus, optimizing $N_{DSL}$ and $L_{DSL}$ of DSSB SOI MOSFET makes it a suitable candidate for future nanoscale analog/RF circuits.

Defects evolution and element segregation of Ni-Mo-Cr alloy irradiated by 30 keV Ar ions

  • Liu, Min;Liu, Wenguan;He, Xiujie;Gao, Yantao;Liu, Renduo;Zhou, Xingtai
    • Nuclear Engineering and Technology
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    • v.52 no.8
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    • pp.1749-1755
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    • 2020
  • In present study, TEM foils of Ni-Mo-Cr alloy were directly irradiated with 30 keV Ar ions to allow direct characterization. The defects evolution and element segregation after irradiation were investigated by TEM and HAADF-EDS linear scanning. At low irradiation doses (1.38 and 2.76 dpa), black dots were formed and grew with increasing dose. Complicated defects including peas-shaped dislocation loops, polygon dislocation networks and large loops were visible in samples irradiated to high doses (13.8 and 27.6 dpa). Meanwhile, dislocation channels appeared, in which defects were swept out. Significant Mo depletions at dislocation lines and grain boundaries were induced by irradiation due to large misfits between Mo-Ni atoms and high content of Mo.

The Environmental Privacy on the Perspective of Integration and Segregation of Spatial Areas in Facilities for the Elderly (노인시설 내 공간영역의 통합과 분리측면에서 본 환경적 프라이버시)

  • Lee, Min-Ah
    • Journal of the Korean housing association
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    • v.25 no.2
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    • pp.89-98
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    • 2014
  • The purpose of this study was to analyze the environmental privacy on the perspective of integration and segregation of spatial areas in facilities for the elderly, through investigating required environmental privacy at each hierarchical space, the contextual situation and counterplan for the privacy. For the study, a content analysis for 35 foreign academic journal articles published from 1990 to August of 2013 was conducted. The results of the study were as follows: First, four hierarchical spaces had somewhat integrated characteristics as being required various types of privacy beyond the original features of each space. Especially semi-public and public spaces were needed the privacy similar to in private or semi-private areas. Second, the contextual situation for the privacy was mainly from undesirable access and psychological pressure of other residents, staff and etc. to the residents' personal space, stuff, and behaviors. The other was from no space (no sitting) or no equipments for privacy. Third, the counterplan for privacy was categorized as improvements of physical environments and making defensible space or keeping physical distance of the elderly. It is suggested that welfare of the aged act in Korea about the room capacity for the elderly facilities needs to be reconsidered for the privacy in their individual rooms and the privacy in semi-public and public area must be considered to make the behavior scope of the elderly extended.

Habitat Segregation between NE and NS Type of Zacco korean us (Cyprinidae) (참갈겨니, Zacco koreanus(잉어과)의 NE형과 NS형의 서식처 분리)

  • Chae, Byung-Soo;Yoon, Hee-Nam
    • Korean Journal of Ichthyology
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    • v.22 no.1
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    • pp.49-55
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    • 2010
  • Sympatric sites of type NE and NS of Zacco korean us were found in the upper reaches of many tributaries of the Nakdong and Seomjin rivers, as well as in some streams draining into the South Sea, Korea. In streams where the two types exist together, there was a tendency for individuals of NE to densely populate the upper reaches and those of NS to populate the middle reaches. A habitat-segregation phenomenon was observed in the cohabiting sites. Fishes of NE preferred rapids, whereas fishes of NS preferred slowly flowing or lentic regions. It seemed that the number of NE was proportional to the flow velocity, but NS showed an opposite trend in the cohabiting sites. On the other hand, such tendency was not found in regions where NE and NS exist separately.

A Study on the Space Analysis of Rural House Plans and Types in Bonghwa Area Using the Space Syntax (봉화지역의 농촌주택 유형과 공간구문론에 의한 공간 분석)

  • Hwang, Yong-Woon
    • Korean Institute of Interior Design Journal
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    • v.24 no.2
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    • pp.142-150
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    • 2015
  • The purpose of this study is to analysis the change of rural house type and house plans in Bonghwa province. According to definition of rural area, the scopes of the research of rural houses limited the Bonghwa rural area(1 eup, 9 myeon). The method of study is to compare and analyze about housing situation, structure of house, housing type and construction of house space etc. through the statistical data of Bongwha statistical yearbook, space syntax(convex analysis) and other various data etc. during these 10 years. As a results of the analysis 1) According to Change of family member the supply ratio of detached house is steadily decreasing and changing from a detached house to multi-household house in Bongwha areas. 2) Most of houses structure were using lightweight steel construction because of cost-cutting of construction and easy way to construct etc.. 3) The highest Integration space is living space in rural house plans 4) The highest segregation space is bathroom space of master bed room in rural house plans. Some of bed rooms are classed as segregation space regardless of Integration space 5) Traditional front yard's function is changing from the place with the various functions to the place with the specific functions.