• Title/Summary/Keyword: seebeck

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Computational Simulations of Thermoelectric Transport Properties

  • Ryu, Byungki;Oh, Min-Wook
    • Journal of the Korean Ceramic Society
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    • v.53 no.3
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    • pp.273-281
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    • 2016
  • This review examines computational simulations of thermoelectric properties, such as electrical conductivity, Seebeck coefficient, and thermal conductivity. With increasing computing power and the development of several efficient simulation codes for electronic structure and transport properties calculations, we can evaluate all the thermoelectric properties within the first-principles calculations with the relaxation time approximation. This review presents the basic principles of electrical and thermal transport equations and how they evaluate properties from the first-principles calculations. As a model case, this review presents results on $Bi_2Te_3$ and Si. Even though there is still an unsolved parameter such as the relaxation time, the effectiveness of the computational simulations on the transport properties will provide much help to experimental scientist researching novel thermoelectric materials.

Electronic conductivity of $LaCrO_3$ ceramics prepared by self-propagating high temperature synthesis

  • Soh, Deawha;Korobova, N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.909-912
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    • 2001
  • Lanthanide orthochromite materials have been widely studied as refractory conducting ceramics because of their electrical conductivity, oxidation resistance and high melting points. In this paper theoretical and experimental analysis about electric conductivity of the SHS prepared ceramics was carried out. The usefulness of the Seebeck-coefficient measurements as a function of P(O$_2$) is emphasized. Electronic conduction was found to be n-type in the lower P(O$_2$) range, and p-type in the higher P(O$_2$) range. The carrier concentrations were calculated as a function of P(O$_2$) and defect structure.

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Unidirectional Solidification of $Bi_2Te_{2.55}Se_{0.45}$ using a VGF Method (VGF법을 이용한 $Bi_2Te_{2.55}Se_{0.45}$의 일방향 응고에 관한 연구)

  • 김영희;김기수;김수룡;정상진;이윤주;박동선
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.62-66
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    • 2003
  • The preparation of n-type thermoelectric material of Bi₂ Te/sub 2.55/Se/sub 0.45/ doped with CuBr₂ was carried out using a vertical gradient freezing method. With this method, unidirectional solidified Bi₂Te/sub 2.55/Se/sub 0.45/ has been obtained. XRD analysis demonstrated that Bi₂/sub 2.55/Se/sub 0.45/ 5 ingot has grown with prefer orientation of (0 1 5) face. Seebeck coefficient and electrical conductivity were measured as functions of temperature in the range of 373 K to 523 K on the sample which prepared via VGF method.

A Study on the Performance of Thermoelectric Module and Thermoelectric Cooling System (열전소자 및 열전냉각장치의 성능에 관한 연구)

  • 유성연;홍정표;심우섭
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.1
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    • pp.62-69
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    • 2004
  • Thermoelectric module is a device that can produce cooling in a direct manner using the electrical energy. The purpose of this study is to investigate the performance of thermoelectric module and cooling system equipped with the thermoelectric module. The performance of a thermoelectric module is estimated using two methods; theoretical analysis based on one-dimensional energy equations and experimental tests using heat source, heat sink and brass conduction extenders. For the thermoelectric cooling system, the temperatures in the chamber are recorded and then compared with those of lumped system analysis. The results show that the cooling capacity and COP of the thermoelectric module increases as the temperature difference between hot and cold surface decreases, and there is particular current at which cooling capacity reaches its maximum value. The experimental results for the thermoelectric cooling system are similar to those of lumped system analysis.

Influence of hot deformation and composition on microstructure development of magnesium-stannide alloys

  • Pandel, Divija;Banerjee, Malay K.
    • Advances in materials Research
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    • v.9 no.3
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    • pp.171-187
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    • 2020
  • The microstructural evolution of different compositions of Mg-Sn alloys (30%Sn-70%Mg, 40%Sn-60%Mg and 50%Sn-50%Mg) is studied at first to understand the changes observed with change in tin content and deformation conditions. The Mg2Sn phase increases with increase in tin content and a significant substructure development is found in 50%Sn-50%Mg alloy. The above observation led to further deformation studies on Mg2Sn based thermoelectric materials with higher tin percentage. The microstructure in terms of Electron backscatter diffraction (EBSD)measurements is studied in detail followed by the determination of thermoelectric properties i.e., Seebeck coefficient and electrical conductivity for both as cast and extruded Mg(2+x)Sn-Ag alloys. The electrical conductivity of the extruded Mg(2+x)Sn-.3wt%Ag {x =1} alloy was found to be more than its as cast counterpart while the Seebeck coefficient values remained almost the same.

Effect of Oxidation ont he Thermoelectricity of Fe-Si based Materials (Fe-Si계 재료의 열전성에 미치는 산화의 효과)

  • 송태호;최준영;이홍림;배철훈
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.74-82
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    • 1996
  • Fe-Si based powders prepare by melting the metals in the composition of FeSi2,.Fe0.95Mn0.05Si2 and Fe0.95Co0.05Si0.2 were used as the starting materials together with a commercial FeSi2 powder to study the effect of oxidation on their thermoelectric properties. The powders were heated at 650~80$0^{\circ}C$ in dired air before forming and sintering at 1190 and 120$0^{\circ}C$ in Ar+7%H2. The microstructure and phases of the annealed specimens were observed using the optical microscopty SEM, EDS and XRD. The thermoelectric properties of the specimens were also measured. The temperature at which Seebe다 coefficient showed the maximum value increased with the degree of oxidation. Electrical conductivity showed a tendency to decrease in the oxidized samples regardless of their compositions. Seebeck coefficient of the specimen showed almost the same value even after oxidation which may be explained by the formation of the discontinuous second phases from impurities in the oxidized specimens.

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Carrier Densities of CdSe Thin Films (CdSe 박막반도체의 반송자 밀도)

  • 김기원
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.21 no.5
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    • pp.7-10
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    • 1984
  • Generally, free carrier densities of single crystal semiconductors are indifferent to methods of measurement. Free carrier densities of CdSe thin films, however, were measured invarious values with different methods In this paper, C-V method, Seebeck effect and a.c. Hall effect were used to measure carries densities of CdSe thin films. Carrier densities of CdSe thin films were in the range of 10 - 10 carriers/㎤. And causes of different results were discussed.

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Analysis of the Thermoelectric Devices' Power Generation Performance for Utilizing the Waste Heat of LED Tunnel Lighting Module (LED터널등 모듈의 폐열활용을 위한 열전소자의 발전 성능 분석)

  • Jeong, Ji-Young;Her, In-Sung;Lee, Se-Il;Kim, Myeong-Ho;Yu, Young Moon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.8
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    • pp.1-6
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    • 2015
  • In this paper, we propose the LED(Light-Emitting-Diode) emergency lighting in a tunnel by using the thermoelectric devices. To achieve high generated power, thermoelectric device should be have high Seebeck coefficient and small contact area. Also, we reveal that a moderate heatsink required for high generated power. From the waste heat of LED tunnel lighting module (25W), the generated power was 0.062W by thermoelectric device, and it could illuminate for 1hour after charge the battery of emergency lighting during about 101hours.