• Title/Summary/Keyword: secondary emission

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An Experimental Study of Petroleum Cokes Air Staged Burner (공기다단 적용 석유코크스 연료 전용 연소기에 대한 실험적 연구)

  • Kwon, Minjun;Lee, Changyeop;Kim, Sewon
    • Journal of the Korean Society of Combustion
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    • v.20 no.2
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    • pp.40-45
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    • 2015
  • This study is aimed to study combustion characteristics of low $NO_X$ burner using petroleum cokes as fuel. The petroleum coke, which is produced through the oil refining process, is an attractive fuel in terms of its high heating value and relatively low price. But petroleum coke is a challenging fuel because of its low volatile content, high sulfur and nitrogen content, which give rise to undesirable emission characteristics and low ignitability. The petroleum cokes burner is operated at fuel rich condition, and overfire air are supplied to achieve fuel lean condition. The low $NO_X$ burner is designed to control fuel and air mixing to achieve air staged combustion, in addition secondary and tertiary air are supplied through swirler. Air distribution ratio of triple staged air are optimized experimentally. The result showed that $NO_X$ concentration is lowest when overfire air is used, and the burner function at a fuel rich condition.

Etching Mechanism of $YMnO_3$ Thin Films in High Density $CF_{4}/Ar$ Plasma (고밀도 $CF_{4}/Ar$ 플라즈마에서 $YMnO_3$ 박막의 식각 매카니즘)

  • Lee, Cheol-ln;Kim, Dong-Pyo;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05b
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    • pp.12-16
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    • 2001
  • We investigated the etching characteristics of $YMnO_3$ thin films in high-density plasma etching system. In this study. $YMnO_3$ thin films were etched with $CF_{4}/Ar$ gas chemistries in inductively coupled plasma (ICP). Etch rates of $YMnO_3$ were measured according to gas mixing ratios. The maximum etch rate of $YMnO_3$ is 18 nm/min at $CF_{4}/(CF_{4}+Ar)$ of 20%. In optical emission spectroscopy (OES) analysis, F radical and Ar* ions in plasma at various gas chemistries decreased with increasing $CF_4$ content. Chemical states of $YMnO_3$ films exposed in plasma were investigated with x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS). There is a chemical reaction between metal (Y, Mn) and F and metal-fluorides were removed effectively by Ar ion sputtering. $YF_x$, $MnF_x$ such as YF, $YF_2$, $YF_3$ and $MnF_3$ Were detected using SIMS analysis. The etch slope is about $65^{\circ}C$ and free of residues.

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Influence of constraint MgO deposition onto phosphors on luminance properties in AC Plasma Display Panels

  • Jeoung, Jin-Man;OH, P.Y.;Moon, M.W.;Lee, J.H.;Jeong, J.E.;Lee, H.J.;Han, Y.K.;Lee, S.B.;Jeong, S.H.;Yoo, C.K.;Yoo, N.R.;Choi, E.H.;Ko, B.D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1215-1217
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    • 2005
  • One of the important problems in recent AC-PDP technology is the image sticking. In this research, we have investigated the PDP cell with constraint deposition MgO on phosphor, the electrical and optical properties in the PDP cell were examined. Also, we have investigated the correlation with image sticking and degraded MgO protective layer, phosphor in AC-PDP. As a result, we measured the secondary electron emission coefficient ${\gamma}$, discharge characteristics and Brightness for the constraint degraded phosphor are compared with those of nondegraded phosphor.

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Characteristics of Electron Beam Extraction in Cold Cathode Type Large Cross-Sectional Pulsed Electron Beam Generator (냉음극형 대면적 펄스 전자빔 가속기의 빔인출 특성)

  • Woo, S.H.;Lee, K.S.;Lee, D.I.;Lee, H.S.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1609-1611
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    • 2001
  • A large cross-section pulsed electron beam generator of cold cathode type has been developed for industrial applications, for example, waste water cleaning, flue gas cleaning, and pasteurization etc. The operational principle is based on the emission of secondary electrons from cold cathode when ions in the plasma hit the cathode, which are accelerated toward exit window by the gradient of an electric potential. The conventional electron beam generators need an electron scanning beam because the small cross section thermal electron emitter is used. The electron beam of large cross-section pulsed electron beam generator do not need to be scanned over target material because the beam cross section is large by 300$cm^2$. We have fabricated the large cross-sectional pulsed electron beam generator with the peak energy of 200keV and beam diameter of 200mm and obtained the large area electron beam in the air. The electron beam current has been investigated as a function of accelerating voltage, glow discharge current, helium pressure, distance from the exit window and radial distribution in front of the exit window.

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Effects of annealing under oxygen atmosphere of PZT thin films on LTCC substrates (LTCC 기판위에 성장시킨 PZT 박막의 열처리시 $O_2$가 미치는 영향)

  • Lee, Kyung-Chun;Hur, Won-Young;Hwang, Hyun-Suk;Lee, Tae-Yong;Lee, Jong-Duk;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.205-205
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    • 2010
  • Recently, low temperature co-fired ceramic (LTCC) technology is widely used in sensors, actuators and microsystem fields because of its very good electrical and mechanical properties, high stability as well as possibility of making 3D micro structures. In this study, we investigated the effects of on $O_2$ annealing treatment on the electrical properties of Pb(ZrTi)$O_3$ (PZT) thin films deposited on LTCC substrate. The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 4 green tapes which consist of alumina and glass particle in an organic binder. The PZT thin films were deposited on Au / LTCC substrates by RF magnetron sputtering method. The change of the crystallization of the films were investigated under various atmosphere. The structural variation of the films were analyzed by using X-Ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) and secondary ion mass spectrometry (SIMS).

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Enhanced Hole Injections in Organic Light Emitting Diode using Rhodium Oxide Coated Anode

  • Kim, Soo-Young;Choi, Ho-Won;Kim, Kwang-Young;Tak, Yoon-Heung;Lee, Jong-Lam
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.77-82
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    • 2005
  • We compare electrical and optical properties of organic light emitting diodes (OLEDs) using rhodium-oxide-coated indium-tin-oxide ($O_2$-Rh/ITO) to that using $O_2$-plasma-treated ITO (ITO) anodes. The turn-on voltage decreased from 7 V to 5 V and luminance value increased when the $O_2$ plasma treated Rh layer was deposited on ITO. Synchrotron radiation photoelectron spectroscopy results showed the dipole energies of both ITO and $O_2$-Rh/ITO were same with each other, - 0.3 eV, meaning the formation of same amount of interface dipole. The secondary electron emission spectra revealed that the work function of $O_2$-Rh/ITO is higher hy 0.2 eV than that of ITO, resulting in the decrease of the tum-on voltage via reduction ofhole injection barrier.

Catalytic oxidation kinetics of iron-containing carbon particles generated from diesel-sprayed hydrogen-air diffusion flame (디젤-분무 수소-공기 확산화염에서 생성된 철-함유 탄소입자의 촉매 산화반응 특성)

  • Kim, Yongho;Kim, Yong-Tae;Kim, Soo Hyung;Lee, Donggeun
    • Particle and aerosol research
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    • v.4 no.2
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    • pp.51-67
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    • 2008
  • In this study, we devoted to kinetic measurement of the catalytic oxidation of iron-containing flame soot particles and better understanding the role of catalytic particles on carbon oxidation in particular at low temperature, targeting on autothermal regeneration of diesel particulate filter by diesel exhaust gas. Carbon-based Fe-containing particles generated by spraying ferrocene-doped diesel fuel in an oxy-hydrogen flame are tested and compared with a commercial carbon black powder for thermogravimetric analysis (TGA), secondary ion mass spectrometry (SIMS), Fourier-transform infrared spectroscopy (FTIR), Induced coupled plasma-Atomic emission spectroscopy (ICP-AES), and High-resolution transmission electron microscopy (HR-TEM). As a result, we found that a small amount of the ferrocene addition led to significant reductions in a on-set temperature and an activation energy of the carbon oxidation as well. An oxygenated surface complex forming at the particle surface could be thought as active species that would be readily consumed in particular at low temperature.

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The study on MgO formation for AC PDP prepared by R.F. reactive magnetron Sputtering (반응성 R.F. 스퍼트링에 의한 AC PDP 용 MgO형성에 관한 연구)

  • Ha, H.J.;Lee, W.G.;Nam, S.O.;Ha, S.C.;Cho, J.S.;Park, C.H.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1576-1578
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    • 1996
  • MgO protection layer in ac PDP prevents the dielectric layer from sputtering of ion in discharge plasma in addition to the contribution to the memory function and also have the additional important roll in lowering the firing Voltage due to a large secondary electron emission yield(${\gamma}$). The methode of Sputtering are easy to apply on mass production and to enlarge the size of the panel and are known to have the superior Adhesion and Uniformity of thin film. MgO protection layer of $1000{\AA}$ on dielectric layer by Reactive R.F magnetron sputtering is formed. Discharge characteristics have done with the formation of protection layer.

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Source Apportionment and the Origin of Asian Dust Observed in Korea by Receptor Modelling (CMB) (수용모델(CMB)을 이용한 한반도에서 관측된 황사의 발원지 추정과 기여도에 대한 연구)

  • Shin S.A.;Han J.S.;Kim S.D.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.2
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    • pp.157-166
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    • 2006
  • Ambient TSP at four sites in Korea and soil samples from the source regions of Asian Dust in northern China were collected and analyzed for 15 metal components and 6 water-soluble ions to conduct a chemical mass balance (CMB). CMB receptor model was used to estimate the source contribution of TSP during the Asian Dust period, and the model results showed that China soil was the largest source contributor, accounting for 81% of TSP ($458.2{\mu}g/m^3$). Vehicle emission and geological sources contributed to about 8.8% and 4.4% of aerosol mass, followed by sea salt (1.5%) and secondary aerosol (2.9%). Fuel combustion and industrial process sources were found to be relatively minor contributors to TSP (${\leq}1%$). In addition to source contribution estimates, this study tried to identify the origin of Asian Dust observed in Korea. Among all 13 China soil profiles presented in this study, the most adoptable profile which can project the case well was selected and considered as the origin of the applied case.

Structural and discharge characteristics of MgO films prepared by Arc Ion Plating (AIP) method

  • Kim, Jong-Kuk;Kim, Do-Geun;Lee, Eun-Sung;Lee, Sung-Hun;Lee, Gun-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.625-627
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    • 2002
  • MgO thin films were deposited on glass and (100) Si substrates by an Arc Ion Plating (AIP) equipment using a magnesium metal target at various oxygen gas flow. In this work, we investigated the relationship between the structural properties and the discharge characteristics of MgO coating layers. X-ray diffraction and AFM have been used to study behaviors of the structure and surface morphology. The optical transmittance and the ion induced secondary electron emission coefficient of the MgO films have been also measured. The resistivity of the deposited MgO films was gradually increased from 0.17 G ohm/${\square}$ to 0.35 G ohm/${\square}$ with the oxygen gas flow. The growth rate of the MgO coating layer was decreased with increasing the oxygen gas flow, while the optical transmittance was improved.

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