• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.261-264
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• 2005

For concrete structures immersed in seawater, the concentration of chloride used to estimate the chloride diffusion coefficient can be defined as the seawater chloride concentration. However, for seashore concrete structures which are not coming into direct contact with seawater, establishing the interface concentration of chloride becomes delicate. In addition, concrete structures are greatly affected by salt attack primarily due to airborne sea salt like it can be seen through the corrosion of rebar. This study intends to investigate characteristics on the salinity of airborne sea salt by height. Salinity measurement devices were installed at height of 2, 10 and 19m on the seashore water tower located in the area of Samchuk in the Eastern coast. Analysis results of the decrease of salinity with respect to the height above the ground at a distance of 30m from the seashore showed that the reduction reached about 40$\%$ at a height of 10m and 60$\%$ at 20m.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.169-172
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• 2006

The IIA structures exposed to marine environment is subject to many different types of potential attack. The physical attack due to drying and wetting would increase the internal stress of concrete. The chemical attack resulting from the diffusion of ions$(Cl^-,SO_4^{2-},Mg^+)$ from seawater through the pores in concrete. Therefore the sea water resistance of concrete must be considered when it is used for structure in the ocean. The objective of this study is to evaluate chloride diffusion and corrosion characteristics of concrete when using the various concrete materials under marine environment. After 5 years of exposure, concrete incorporating 40% blast-furnace slag as replacement for type I cement with low w/c ratio of 0.42 and using the inhibitor shows excellent performance.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.911-914
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• 2008

해수, 지하수 등과 같이 황산염이온이 포함된 환경에 콘크리트 구조물이 증가함에 콘크리트의 황산염침식 및 관련 메카니즘에 대한 관심이 증가하는 추세이다. 콘크리트의 황산염침식을 방지하기 위한 연구가 전세계적으로 여러 연구자들에 의하여 수행되었지만 침식 메카니즘의 복잡성 등으로 인하여 아직도 만족할 만한 성과가 가시적으로 나타나고 있지 않다. 따라서, 본 원고에서는 콘크리트의 황산염침식을 유발하는 반응생성물의 생성과정 및 평가방법 등에 대한 고찰을 실시하였으며, 황산염환경하에 노출된 콘크리트 구조물의 합리적 내구성설계를 위한 참고자료를 제공하고자 한다.

• 콘크리트학회논문집
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• 제22권6호
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• pp.769-776
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• 2010

해수에 침적되어 있는 구조물은 일정한 외부 염화물 조건을 가지게 되지만 비래염분의 환경하에 있는 콘크리트 구조물은 지역, 해안으로부터 거리, 구조물의 방향, 풍향 등 주변환경에 따라서 다양한 조건의 외부 염화물 조건을 갖게 된다. 따라서, 해수와 직접 접하지 않더라도 지역적인 특성에 따라 비래염분에 의한 염해를 받을 수 있으며, 그러한 사례들이 보고되고 있다. 그러나, 이러한 비래염분 환경조건을 규명하기는 쉽지 않아 이제까지는 많은 연구가 행하여 지지 못하였다. 따라서, 이 연구에서는 우리나라의 해안가 27개 지역 72개 지점을 선정하여 3년간 대기중의 비래염분에 대한 측정을 실시하여 분석하였다. 그 결과, 비래염분은 지역적 특성이 강하게 나타났으며, 계절적인 영향 또한 크게 나타났다. 또한, 해안으로부터 거리에 따라서 $y=ax^{-b}$의 함수의 경향으로 감소하는 것으로 밝혀졌다. 이러한 비래염분 분포에 대한 분석결과는 향후 해안 인근 구조물의 내구성 설계나 유지관리에 큰 도움이 될 것으로 판단된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.573-576
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• 2008

해양 환경하의 조건에서 건설된 콘크리트 구조물이 해수에 직접 닿을 경우, 해수중의 염화물 농도를 측정함으로서 콘크리트 구조물의 염화물 확산계수 산정이 용이하지만, 해수와 직접 접촉되지 않는 경우, 비래염분 등에 의한 염화물 확산계수의 산정에 어려움이 있다. 따라서, 해안에 인접한 콘크리트 구조물에 날아드는 염분량 등을 측정 평가하는 것은 콘크리트 구조물의 설계 시공 및 유지관리에 중요한 기초자료로 활용될 수 있다. 따라서, 본 연구에서는 동해, 서해, 남해안의 27개 지역, 72개 지점을 선정하여 매월 1회 1개월간의 누적 비래염분량을 '03년 7월부터 '06년 6월까지 3년간 측정하여 국내 해안가의 비래염분 환경을 계절별 비래염분량의 측면에서 알아보고자 하였다. 측정 결과, 동해와 남해안에서는 여름철, 서해안에서는 겨울철에 상대적으로 많은 비래염분량이 발생하였으며, 이것은 계절풍에 기인한 것으로 판단된다.

• Corrosion Science and Technology
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• 제2권5호
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• pp.219-224
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• 2003

Crevice corrosion of stainless steels in natural seawater was investigated for several post weld treatments; as-annealed, as-welded, pickled, and ground. The results confirmed the effect of the biofilm on the cathodic reaction leading to an ennoblement of the rest potential. The degree of ennoblement of corrosion potential depends on the surface finish. As-annealed and pickled samples show stable corrosion potential approaching to 200 ~ 300 mV (SCE) while as-welded and ground samples show the fluctuating corrosion potential. This points to a situation where there are conflicting effects determining the trend in free corrosion potential. Crevice corrosion initiation will tend to pull the free corrosion potential in the active direction, whereas the presence of biofilm will tend to ennoble corrosion potential. There was no visible attack on UNS S31803, S32550, and 2205W. Therefore, those stainless steel grades appeared to be resistant to crevice corrosion in natural seawater on condition of weld metal.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.51-56
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• 2002

Protection against salt attack in seawater is obtained by using a dense, quality concrete with a low water-cement ratio, and a components appropriate for producing concrete having the needed salt resistance. The objective of this study is to evaluate the feature of corrosion with using the various concrete materials under marine exposure environment. According to the test results, slag powder and anti -corrosion inhibitor showed high chloride resistance effect. Also concre crack have an influence on corrosion of steel in spite of mixed design for salt resistance concrete. The requirement for low permeability is essential not only to delay the effect of salt attack, but also to afford adquate protection to reinforcement with admixtures.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.790-793
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• 2004

The factors influencing concrete deterioration in marine environment can be generally divided into the physical and chemical action. The physical attack due to drying and wetting would increase the internal stress of concrete. The chemical attack resulting from the diffusion of ions$(i,e,\;Cl^-,SO_4^{2-},Mg^+)$ from seawater through the pores in concrete. The objective of this study is to evaluate corrosion characteristics of steel when using the various concrete materials under marine exposure environment. After 3 years of exposure, concrete specimen incorporating $40\%$ blast-furnace slag as replacement for type I cement with low w/c ratio of 0.42 and using the inhibitor shows excellent performance.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.519-522
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• 2005

As this study is to test effects of chemical attack on deterioration of cement mortars using in crushed sand. Besides tests have been carried out with cement mortars by river sand and crushed sand by fine sand, cement mortars mix various proportions of slica fume and fly ash(up to $15\%$ and $50\%$ by weight for cement) were prepared and immersed in pure water, sodium sulfate solution, magnesium sulfate solution, seawater for 28days. Test on the change in the weight and compressive strength of cement mortars according to the duration of immersion time and the content of slica fume and fly ash was performed.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.181-184
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• 2005

When concrete structures are exposed under marine condition for a long time, the steel in concrete is corroded due to the ingression of chlorides in the seawater. Because the damages of corrosion resulting from the chloride ion are very serious, many researches have been performed. However evaluation on chloride attack of concrete structures are not fully examined, recently. Therefore, the objective of this paper is to study the applicability of colormetric method. For the purpose of this, reaction mechanism of colormetric method were investigated, and the colormetric method is applied for marine concrete structures. According to the test results, the diffusion coefficient by colormetric method is not so different to the value of chloride concentration profile test. It is confirmed that the colormetric method is useful tool for estimating the chloride of concrete structures in situ. The average chloride amount of colored parts indicates 0.9kg/$m^{3}$ per concrete unit weight.