• Title/Summary/Keyword: school bonding

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Hydrogen Bonding in Aromatic Alcohol-Water Clusters: A Brief Review

  • Ahn, Doo-Sik;Jeon, In-Sun;Jang, Sang-Hee;Park, Sung-Woo;Lee, Sung-Yul;Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.695-702
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    • 2003
  • Recent experimental and theoretical advances on the aromatic alcohol-water clusters are reviewed, focusing on the structure of the hydrogen bonding between the alcoholic OH group and the binding water molecules. The interplay of experimental observations and theoretical calculations for the elucidation of the structure is demonstrated for phenol-water, benzyl alcohol-water, substituted phenol-water, naphthol-water and tropolone -water clusters. Discussion is made on assigning the role (either proton-donating or -accepting) of the hydroxyl group by measuring the shifts of infrared frequency of the OH stretching mode in the cluster from that of bare aromatic alcohol for the experimental determination of the cluster structure.

Pinning retrofit technique in masonry with application of polymer-cement pastes as bonding agents

  • Shrestha, Kshitij C.;Pareek, Sanjay;Suzuki, Yusuke;Araki, Yoshikazu
    • Earthquakes and Structures
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    • v.5 no.4
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    • pp.477-497
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    • 2013
  • This paper reports extensive experimental study done to compare workability and bond strength of five different types of polymer-based bonding agents for reinforcing bars in pinning retrofit. In pinning retrofit, steel pins of 6 to 10 mm diameters are inserted into holes drilled diagonally from mortar joints. This technique is superior to other techniques especially in retrofitting historic masonry constructions because it does not change the appearance of constructions. With an ordinary cement paste as bonding agent, it is very difficult to insert reinforcing bars at larger open times due to poor workability and very thin clearance available. Here, open time represents the time interval between the injection of bonding agent and the insertion of reinforcing bars. Use of polymer-cement paste (PCP), as bonding agent, is proposed in this study, with investigation on workability and bond strengths of various PCPs in brick masonry, at open times up to 10 minutes, which is unavoidable in practice. Corresponding nonlinear finite element models are developed to simulate the experimental observations. From the experimental and analytical study, the Styrene-Butadiene Rubber polymer-cement paste (SBR-PCP) with prior pretreatments of drilled holes showed strong bond with minimum strength variation at larger open times.

Development of A Process Map for Extrusion of Cu-Ti Bimetal Bar (구리-타이타늄 이중봉 직접압출의 공정지도 개발)

  • Kim Joong-Sik;Lee Yong-Sin;Sim K.S.;Park H.J.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.499-502
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    • 2005
  • A process map has been developed, which can identify the process conditions for weak mechanical bonding at the contact surface during the direct extrusion of a Cu-Ti bimetal bar. Bonding mechanism between Cu and Ti was assumed as a cold pressure welding. Then, the plastic deformation at the contact zone causes mechanical bonding and a new bonding criterion for pressure welding was developed as a function of the principal stretch ratio and normal pressure at the contact surface by analyzing micro local extrusion at the contact zone. Finite element analyses for extrusion of Cu-Ti bimetal bars were performed for various process conditions. The deformation history at the contact surface was traced and the proposed new bonding criterion was applied to predict whether the mechanical bonding at the Cu-Ti contact surface happens. Finally, a process map for the extrusion of Cu-Ti bimetal bar is suggested.

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Effect of Corrugating Medium's Properties on Microflute Formation (part2) -Relative importance of stiffness and fiber bonding on microflute formation- (원지특성에 따른 Microflute의 골 성형성(제2보) -Microflute 골 성형성에 영향하는 스트프니스와 섬유간 결합의 중요성 비교 -)

  • Min, Kyung-Eun;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.2 s.110
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    • pp.64-69
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    • 2005
  • Suitability of corrugating medium for microflute shape formation was analyzed in terms of fiber bonding strength and paper stiffness. Cationic starch and oxidized starch were applied to corrugating medium's surface by bar coater in order to compare the relative importance of stiffness and fiber bonding on microflute formation. It was found that cationic starch was beneficial for better stiffness and oxidized starch was beneficial for better fiber bonding. The results of the decreasing ratio of length by flute formation, the calculated conditioning effect, and the flute height before and after conditioning treatment were obtained. For better microflute shape formation and its preservation it was found that fiber bonding strength should be increased, proper stiffness was required, and resistance to water absorption from surroundings should be increased.

Effect of Post-Annealing Conditions on Interfacial Adhesion Energy of Cu-Cu Bonding for 3-D IC Integration (3차원 소자 집적을 위한 Cu-Cu 접합의 계면접착에너지에 미치는 후속 열처리의 영향)

  • Jang, Eun-Jung;Pfeiffer, Sarah;Kim, Bi-Oh;Mtthias, Thorsten;Hyun, Seung-Min;Lee, Hak-Joo;Park, Young-Bae
    • Korean Journal of Materials Research
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    • v.18 no.4
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    • pp.204-210
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    • 2008
  • $1.5\;{\mu}m$-thick copper films deposited on silicon wafers were successfully bonded at $415^{\circ}C$/25 kN for 40 minutes in a thermo-compression bonding method that did not involve a pre-cleaning or pre-annealing process. The original copper bonding interface disappeared and showed a homogeneous microstructure with few voids at the original bonding interface. Quantitative interfacial adhesion energies were greater than $10.4\;J/m^2$ as measured via a four-point bending test. Post-bonding annealing at a temperature that was less than $300^{\circ}C$ had only a slight effect on the bonding energy, whereas an oxygen environment significantly deteriorated the bonding energy over $400^{\circ}C$. This was most likely due to the fast growth of brittle interfacial oxides. Therefore, the annealing environment and temperature conditions greatly affect the interfacial bonding energy and reliability in Cu-Cu bonded wafer stacks.

A STUDY ON THE BONDING STRENGTH OF RESILIENT DENTURE LINERS (탄성 의치상 이장재의 접착력에 관한 연구)

  • Lee Sang-Hoon;Chung Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.3
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    • pp.411-436
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    • 1992
  • The purpose of this study was to assess the adhesion of resilient denture liners (such as, heat-cured silicone molloplast B,cold- cured silicone Mollosil) to polymethyl metacrylate (K-33) and metal (Megalloy) in the laboratory by peel test. The resilient denture lines were processed according to manufactures instruction, onto prepared specimens(original resin base plate, rough resin base plate, stippled metal plate, mesh metal plate ) 75mm long and 25m wide. And then, the peel test was performed by instron. The results were as follows : 1. The bonding strength of Mollosil was stronger than that of Molloplast B except the specimen of stippled metal plate. 2. The tensile strength of Mollosil was weaker than that of Molloplast Bas tearing of Mollosil was occured in the peel test. 3. Mesh metal plate had the highest bonding strength in the case of Molloplast B and Mollosil. But stippled metal plate have high bonding strength in the case of Molloplast B and have the lowest bonding strength in the case of Mollosil. 4. The bonding strength of rough resin base plate was stronger than that of original resin base plate in the case of Molloplast B and Mollosil. 5. The bonding strength of metal plates was stronger than that of resin base plates in the case of Molloplast B and Mollosil except the case of bonding strength between the stippled metal plate and Mollosil. 6. It seems that the Increase of surface and retention form of metal plate and resin base plate produces higher physical bonding strength.

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Optimization of Surface Treatment for Bonding S trength between Zirconia and Veneering Porcelain

  • Won, H.Y.;Kim, H.S.L.;Yun, C.H.;Son, M.K.;Cho, H.C.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.332-332
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    • 2012
  • All-ceramic prostheses are widely used to fulfill the high esthetic demand. However, bonding failure between zirconia and porcelain is one of the all-ceramic prostheses failures. In order to improve clinical sucess of all-ceramic prostheses, laboratory or in-office surface conditioning techniques on zirconia have been studied.

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Effect of additional etching and ethanol-wet bonding on the dentin bond strength of one-step self-etch adhesives

  • Ahn, Joonghee;Jung, Kyoung-Hwa;Son, Sung-Ae;Hur, Bock;Kwon, Yong-Hoon;Park, Jeong-Kil
    • Restorative Dentistry and Endodontics
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    • v.40 no.1
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    • pp.68-74
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    • 2015
  • Objectives: This study examined the effects of additional acid etching on the dentin bond strength of one-step self-etch adhesives with different compositions and pH. The effect of ethanol wetting on etched dentin bond strength of self-etch adhesives was also evaluated. Materials and Methods: Forty-two human permanent molars were classified into 21 groups according to the adhesive types (Clearfil SE Bond [SE, control]; G-aenial Bond [GB]; Xeno V [XV]; Beauti Bond [BB]; Adper Easy Bond [AE]; Single Bond Universal [SU]; All Bond Universal [AU]), and the dentin conditioning methods. Composite resins were placed on the dentin surfaces, and the teeth were sectioned. The microtensile bond strength was measured, and the failure mode of the fractured specimens was examined. The data were analyzed statistically using two-way ANOVA and Duncan's post hoc test. Results: In GB, XV and SE ($pH{\leq}2$), the bond strength was decreased significantly when the dentin was etched (p < 0.05). In BB, AE and SU (pH 2.4 - 2.7), additional etching did not affect the bond strength (p > 0.05). In AU (pH = 3.2), additional etching increased the bond strength significantly (p < 0.05). When adhesives were applied to the acid etched dentin with ethanol-wet bonding, the bond strength was significantly higher than that of the no ethanol-wet bonding groups, and the incidence of cohesive failure was increased. Conclusions: The effect of additional acid etching on the dentin bond strength was influenced by the pH of one-step self-etch adhesives. Ethanol wetting on etched dentin could create a stronger bonding performance of one-step self-etch adhesives for acid etched dentin.

Novel Hybrid Hydroxyapatite Spacers Ensure Sufficient Bone Bonding in Cervical Laminoplasty

  • Tanaka, Nobuhiro;Nakanishi, Kazuyoshi;Kamei, Naosuke;Nakamae, Toshio;Kotaka, Shinji;Fujimoto, Yoshinori;Ochi, Mitsuo;Adachi, Nobuo
    • Asian Spine Journal
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    • v.12 no.6
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    • pp.1078-1084
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    • 2018
  • Study Design: Prospective observational study. Purpose: This prospective analysis aimed to evaluate the efficacy and bone-bonding rate of hybrid hydroxyapatite (HA) spacers in expansive laminoplasty. Overview of Literature: Various types of spacers or plates have been developed for expansive laminoplasty. Methods: Expansive open-door laminoplasty was performed in 146 patients with cervical myelopathy; 450 hybrid HA spacers and 41 autogenous bone spacers harvested from the spinous processes were grafted into the opened side of each lamina. The patients were followed up using computed tomography (CT), and their bone-bonding rates for hybrid HA and autogenous spacers, bone-fusion rates of the hinges of the laminae, and complications associated with the implants were then examined. Results: Clinical symptoms significantly improved in all patients, and no major complications related to the procedure were noted. The hybrid HA spacers exhibited sufficient bone bonding on postoperative CT. The hinges completely fused in over 95% patients within 1 year of the procedure. Only 4 spacers (0.9%) developed lamina sinking, and most expanded laminae maintained their positions without sinking or floating throughout the follow-up period. Conclusions: Hybrid HA spacers contributed to high bone-fusion rates of the spacers and hinges of the laminae, and no complications were associated with their use. Cervical laminoplasty with these spacers is safe and simple, and it yields sufficient fixation strength while ensuring sufficient bone bonding during the immediate postoperative period.