• Resources Recycling
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• v.28 no.6
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• pp.46-53
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• 2019

Cement mortar was hydrothermal-synthesized with particle size of tailings using scheelite tailings deposited without proper treatment, and its physical properties were investigated. The mixing ratios of water-cement and sand-cement were fixed at 75 % and 400 %, respectively, during preparing cemnt mortar, and the sand was replaced by the tailings at 0 ~ 50 %. The particle size of tailings was controlled at 9.3 ~ 53.0 ℃, and the hydrothermal temperature was kept at 60 ~ 180 ℃ for 6 hours after the temperature increased to pretermined temperature with 2 ℃ heating rate. The compressive strength increased with increasing hydrothermal temperature. The compressive strengths were 55.2 MPa and 54.5 MPa when the mortars were prepared with 30 % low arsenic and high arsenic tailings after 60 min grinding. The compresiive strenght was enhanced 300 % compared with reference sample.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.3
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• pp.111-119
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• 2014

A novel pulsed laser ablation process in liquid was investigated to prepare scheelite-type ceramic [calcium tungstate ($CaWO_4$) and calcium molybdate ($CaMoO_4$)] nanocolloidal particles. The crystalline phase, particle morphology, particle size distribution, absorbance and optical band-gap were investigated. Stable colloidal suspensions consisting of well-dispersed $CaWO_4$ and $CaMoO_4$ nanoparticles with narrow size distribution could be obtained without any surfactant. Particle tracking analysis using optical microscope combined with image analysis was applied for a fast determination of particle size distribution in the prepared nanocolloidal suspensions. The mean nanoparticle size of $CaWO_4$ and $CaMoO_4$ colloidal nanoparticles were 16 nm and 30 nm, with the standard deviations of 2.1 and 5.2 nm, respectively. The optical absorption edges showed blue-shifted values about 60~70 nm than those of reported in bulk crystals. And also, the estimated optical energy band-gaps of $CaWO_4$ and $CaMoO_4$ colloidal particles were 5.2 and 4.7 eV. The observed band-gap widening and blue-shift of the optical absorbance could be ascribed to the quantum confinement effect due to the very small size of the $CaWO_4$ and $CaMoO_4$ nanocolloidal particles prepared by pulsed laser ablation in liquid.

• Korean Institute of Interior Design Journal
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• v.18 no.5
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• pp.175-182
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• 2009

Korea Protestant slower growth and social church's changes in the environment of the traditional worship center for the sermon to a variety of changes was required, because of this period reflects the availability of a new type of worship was to appear. These changes in the type of worship in the form of the worship space, and space configuration is affecting many more. This study was the type of church korea today, the type is classified as a traditional worship and contemporary worship, and to characterize the category by a change in the type of church worship space in the configuration that affects cases throughout the analysis was to investigate, study follows. Traditional worship the center of the altar, the altar placed platform form, a vertical elevation of the platform sheet form, the installation of the cross, place the side of the choir seats, church chair type attribute appears tradition and in part compressed pulpit appears symbolism. Contemporary worship to the exclusion of the symbolic elements of the platform open, flat sheet form and the platform was the preferred form of minor elevations of the flat, multi-purpose space used for worship to sermon platform placed around the altar of the adjustable type, the choir seats placed in scheelite, preferred form of scheelite was an individual chair. However, the characteristics of traditional and contemporary worship space features a mix of worship space, quite a lot of cases that have been found. Integrated and consistent element of the worship space, the worship of the discrepancy in the form of systematic theological depth analysis did not come true without lust about contemporary culture is changing rapidly to accommodate sprawl is judged. Therefore, the characteristics of the type of worship and prayer to understand the changes in the church building is a prerequisite to be a very important aspect.

• Economic and Environmental Geology
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• v.28 no.3
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• pp.287-303
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• 1995

Tungsten ore deposits in China show clearly their relationship between granitoids and orebodies. All kinds of different tungsten ore deposits, having the largest ore reserves in the world, occur in China. Major tungsten deposits in 1950'years were locally confined in three provinces such as Jiangxi, Hunan and Guangdong. However, the major tungsten ore deposits are replaced by new tungsten deposits such as Sandahozhuang, Xingluokeng, Shizhuan and Daminghsan deposit which may be larger than the previous major deposits. Tungsten ore deposits of China exhibit obviously the granitoid was the ore-bringer to form tungsten ore deposits. The wolframite-bearing quarz veins in China indicate that tungsten mineralization took place by crystallization of wolframite preferentially unless $Ca^{{+}{+}}$ was introduced from outside into the magma-origin-fluid, since it is understood that the scheelite in the Sangdong ore deposit was preferentially precipitated, because of chemical affinity, from the tungsten fluid in which Fe and Ca ions were as sufficient as to form magnetite, wolframite and scheelite. Tungsten deposits in the world are divided into two systems; W-Mo-Sn system and W-Mo system. Most of tungsten deposits in China dated to about 196-116 Ma belong to the W-Mo-Sn system, while late Cretaceous tungsten deposits such as the Sangdong deposit in Korea belongs to the W-Mo system. The genetic order of tin-tungsten-molybdenum mineralization observed in the Moping tungsten mine in China and the Sangdong in Korea may be attributed to volatile pressures in the same magma chamber. It is assumed from ages of tungsten mineralizations that ore elements such as tin, tungsten and molybdenum might be generated periodically by nuclear fission and fusion in a part of the mantle and the element generated was introduced into the magma chamber. The periodical generation of elements had determined association, depletion and enrichment of tin and molybdenum in tungsten mineralization and it results in little association of cassiterite in tungsten deposit of late Cretaceous ages. Different mechanism of emplacement of the ore-bearing magma has brought various genetic types of tungsten deposits as shown in China and the world.

• Journal of the Korean Ceramic Society
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• v.43 no.1 s.284
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• pp.10-15
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• 2006

Photoluminescence (PL) and crystal structures of the $(l-x)CaWO_4-xLi_2WO_4$ binary system added with $Eu_2O_3$ activator have been characterized. The $CaWO_4\;and\;Li_2WO_4$ have the scheelite and phenakite structures respectively. The $CaWO_4-Li_2WO_4-Eu_2O_3$ phosphors show the red luminescence of 613 nm peak wavelength. The wavelength range of excitation spectral band is $380\~470$ nm with the peak wavelength of 397 nm. The $0.88(0.5CaWO_4-0.5Li_2WO_4)-0.12Eu_2O_3$ showed the most superior luminescence characteristics. The effect of co-doping elements such as $Al_2O_3$ and rare-earth oxides on PL has been characterized. The co-doping elements deteriorated the luminescence intensity except the $Al_2O_3$ and $Gd_2O_3$. The PL characteristics of $CaWO_4-Li_2WO_4-Eu_2O_3$ phosphors have been compared to those of the alkali europium double molybdates (tungstates) of scheelite-related structure such as $LiEu(MoO_4)_2$ and $CsEu(MoO_4)_2$. The crystal structures of $(l-y)[(l-x)CaWO_4-xLi_2WO_4]-yEu_2O_3$ phosphors have been characterized using XRD data and rietveld refinement.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.5
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• pp.217-222
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• 2007

Microwave dielectric properties of $(1-x)CaWO_4-xYNbO_4$ ceramics have been investigated as a function of $YNbO_4$ content($0.05{\leq}x{\leq}0.4$). A single phase with tetragonal scheelite structure was obtained up to x=0.10 and then the secondary phase with fergusonite structure was increased. With the increase of $YNbO_4$ content, apparent densities of the specimens were decreased. This results were due to the lower theoretical density of $YNbO_4(5.581g/cm^3)$ than that of $CaWO_4(6.117g/cm^3)$. Dielectric constant(K) and quality factor(Qf) were decreased with $YNbO_4$ content which could be attribute to the decrease of density and the increase of secondary phase. Temperature coefficient of resonant frequency (TCF) of the specimens with the $YNbO_4$ content was depended on dielectric mixing rule.

• Economic and Environmental Geology
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• v.12 no.2
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• pp.79-93
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• 1979

Twenty five samples of the scheelite-powellite series from twelve Korean tungsten deposits of various geologic settings were studied mineralogically and geochemically. Variations in the trace-element contents of the scheelite minerals are considered in relation to geologic settings and mineralogic properties. Scheelites from ore deposits developed in similar geologic settings and under similar physicochemical conditions are characterized by specific combinations of trace elements.

• Economic and Environmental Geology
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• v.12 no.3
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• pp.127-146
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• 1979

Though tungsten minerals have been mined for over fifty years in Korea, which has become one of the worlds largest tungsten producers since 1951, knowledge of their mineralogy and geochemistry is somewhat limited to the school of tungsten students. There is a considerable amount of literature throughout the world on the tungsten mineralogy, the geochemical behaviour of tungsten, the nature of tungsten deposits and geological environments for tungsten mineralisation. Commonly known tungsten minerals such as scheelite and wolframite belong to one of two series, the scheelite or the wolframite series, as the primary tungsten minerals. Secondary tungsten minerals are known rather rare, however, some of them plays an important role-of exploration guide in search for tungsten deposits. The geochemistry of tungsten is imperfectly known, and apparently the behaviour of tungsten in geological processes has been the subject of few studies. Recently, some aspects of the fundamental geochemistry of tungsten has been worked out and compiled the data in broad the up to date by many authors. In order to facilitate the better understanding and future exploration of tungsten deposits, an attempt has been made to summarise the existing knowledge of the fundamental geochemistry of tungsten, together with its common geochemical association with various types of tungsten deposits.

• Economic and Environmental Geology
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• v.18 no.2
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• pp.93-105
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• 1985

Whether a skarn deposit in carbonate host occurs in contact with certain igneous mass or not has been a general criterion in identifying the igneous rock that genetically relates to the skarn deposit. It is well known, however, that there are many skarn deposits which are not close to any given igneous contact but are far away from the contact. In this paper the reason why such deposits can be formed at a distance from the contact as mentioned is expressed based on the concept that skarn deposits and related igneous rocks are genetically connected at depth where ore-forming fluids emanate from magma and are removed upwards; the movement of ore-forming fluids separated from magma at any depth may have a tendency to infiltrate upward in bulk rather than to diffuse laterally; the paths of magma and cogenetic ore-forming fluids may be identical at lower depths but the latter can be diverted from the former with upward movement so that the positions of the skarn deposits which resulted from the ore-forming fludis at upper levels can be distant from the igneous contacts on a given horizontal section. Statistics indicate that the majority of exoskarns are found at distances up to 800 meters or rarely up to 3,000 meters from igneous contacts and endoskarns up to 600 meters or more. Numerous case studies of skarn deposits in various parts of the world support the above reasoning indicating a general downward convergency of skarn orebodies and related igneous masses with depth. A typical example of this situation is well demonstrated at the Keumseong molybdenum deposit, which is apart from the Jecheon granite on the surface but gets closer to the granite body with depth and finally is intertongued with the granite apophyses in its root zone. Another case for skarn deposit not associated with igneous contact either laterally or vertically but with a deep-seated distal igneous mass is the Sangdong scheelite deposit; 700 meters below the scheelite orebody a blind pluton of muscovite granite, which intruded into the Precambrian crystalline schist, has been recently discovered by deep drilling.

• Economic and Environmental Geology
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• v.15 no.1
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• pp.17-32
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• 1982

The Wolak tungsten-molybdenum deposits are tungsten-molybdenum bearing quartz veins which filled the fractures in Pre-Cambrian pebble-bearing calcareous hornfels, hornfels and Cretaceous granite. There are two vein groups in this mine, Dongsan vein group in the west and Kwangcheon vein group in the east. The ore minerals are wolframite, scheelite, molybdenite, native bismuth, bismuthinite, pyrite, arsenopyrite, chalcopyrite, cubanite, stannite, pyrrhotite, sphalerite, galena, marcasite, Pb-Bi sulfosalt and ilmenite. Quartz, calcite, beryl, fluorite, muscovite, rhodochrosite and siderite are gangue minerals. Fluid inclusion studies were carried out for the quartz, beryl, scheelite, early and late fluorite. Fluid inclusion studies reveal that liquid-gas inclusions are most common and occur in all of the minerals examined. Filling degree of the inclusions in the late fluorite is much higher than that of the inclusions in quartz and early fluorite. Liquid $CO_2$ bearing liquid-gas inclusions occur in quartz and early fluorite. Liquid, gas and solid phase inclusions occur in quartz, beryl and scheelite. Salinities of inclusions in quartz and beryl from Dongsan vein group range from 3.9 to 8.0, from 5.3 to 7.7 wt.% NaCl equivalent respectively. Salinities in the late fluorite range from 1.5 to 3.2 wt.% NaCl equivalent. In Kwangcheon vein group salinities range from 3.9 to 9.6 wt.% NaCl equivalent in quartz, from 2.8 to 7.3 wt.% NaCl equivalent in early fluorite, from 1.3 to 1.5 wt.% NaCl equivalent in late fluorite. Homogenization temperatures of inclusions range from $239^{\circ}$ to higher than $360^{\circ}C$ in quartz, over $360^{\circ}C$ in scheelite, from $288^{\circ}C$ to higher than $360^{\circ}C$ in beryl, and from $159^{\circ}$ to $202^{\circ}C$ in late fluorite of the Dongsan vein group. In Kwangcheon vein group, homo genization temperatures of inclusions range from $240^{\circ}C$ to higher than $360^{\circ}C$ in quartz and from $240^{\circ}$ to $328^{\circ}C$ in early fluorite. As a whole, in Dongsan and Kwangcheon vein groups it seems that there are no distinct differences in mineralogy, salinities and homogenization temperatures. No distinct variations in homogenization temperatures are revealed through about 300 m vertically in both district. The faint trend of increase in salinities in the lower level can be detected. The salinity, $CO_2$ content and the temperature of ore fluid were much higher in the early vein stage and then dropped off in the late stage of mineralization as represented by the quartz and fluorite inclusion data.