• Title/Summary/Keyword: scavenging coefficient

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Free radical scavenging activity and kinetic behavior of the Galgeuntang water extract

  • Shin, Jeong-Mi;Kim, Young-Ok;Baek, Seung-Hwa
    • Advances in Traditional Medicine
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    • v.8 no.1
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    • pp.32-38
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    • 2008
  • Galgeuntang water extract exhibited a strong free radical scavenging activity and reducing power determination. However, a gradual increase in the free radical scavenging activity and reducing power determination was obtained with increasing concentrations. The highest radical scavenging activity was shown by the water extract from Galgeuntang (116.93 ${\mu}g$/mL) and the water extract from Cinnamonum cassia Presl. (95.01 ${\mu}g$/mL). These results of phenolic and flavonoid contents of the extracts indicated that the strong radical scavenging activity of the Cinnamonum cassia Presl. extract might be in part due to the phenolic compounds. The correlation coefficient between TPC and DPPH ($r^2$ = 0.9312), TFC and DPPH ($r^2$ = 0.9677), showed positive correlation among total phenolic/flavonoid contents and antioxidant activity. These results suggest that Galgeuntang has a potential antioxidant activity.

ESTIMATION OF RAIN SCAVENGING RATIO FOR PARTICLE BOUND POLYCYCLIC AROMATIC HYDROCARBONS AND POLYCHLORINATED BIPHENYLS

  • Kim, Hyeon-Kook;Shin, Yong-Seung;Lee, Dong-Soo;Song, Byung-Joo;Kim, Jong-Guk
    • Environmental Engineering Research
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    • v.11 no.1
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    • pp.33-44
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    • 2006
  • The objective of this study was to develop and assess a method for estimating the rain scavenging ratios (RSRs) of particle-bound PAHs and PCBs using measured scavenging ratio of particulate matters (PM) and routinely available data of physico-chemical properties of PM. Paired atmospheric and rainwater sampling was conducted for a total of 4 rain events. Assuming equilibrium partitioning in rainwater-gas-PM system, an equation was derived for estimating the RSR of particle-bound chemicals as a function of RSR of PM and three equilibrium partition constants (i.e. dimensionless Henry's law constant, gas-particle partition coefficient, and water-particle partition coefficient). For all PAHs, the model significantly under-predicted the RSR while the model prediction for PCBs agreed with observation mostly within a factor of 5. The RSR model for the chemicals is of limited use as its accuracy critically depends on how close the observed partitioning of the chemicals in the gas-PM-rainwater system is to that estimated under the equilibrium assumption.

Distribution between Air-Soil Concentration of Organochlorine Pesticides (유기염소계 살충제의 대기-토양간 분배)

  • Choi, Min-Kyu;Chun, Man-Young
    • Environmental Analysis Health and Toxicology
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    • v.22 no.4
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    • pp.299-304
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    • 2007
  • This paper was studied to investigate the equilibrium state between organochlorine pesticides (OCPs) concentration of air and soil, and to know whether soil is a secondary pollution source of OCPs in air or not. The OCPs concentration of air ($C_{air}$) and soil ($C_{soil}$) is not related to molecular weight, vapor pressure ($P_L$) and octanol-air partition coefficient ($K_{oa}$). The slope of the regression line between soil-air partition coefficient ($K_{sa}$) and scavenging coefficient ($C_{soil}/C_{air}$) was 0.2952, which the OCPs concentration between air and soil did not reached to the equilibrium state. The soil/air fugacity quotients ($f_{soil}/f_{air}$) of p, p'-DDT/DDD/DDE and ${\beta}-HCH\;(0.30{\sim}0.67$), which is smaller than 1, means the deposit of OCPs from air to soil. However, $f_{soil}/f_{air}$ of heptachlor, heptachlor epoxide, ${\alpha}/{\gamma}-chlordane$, trans-nonachlor, endosulfan sulfate and ${\alpha}/{\gamma}-HCH\;(1.90{\sim}73.25)$, which is greater than 1, means that soil is secondary pollution source of OCPs in air.

Optimization of Hot Water Extraction for Enhancing Antioxidative Activity from Auricularia auricula Using Taguchi Approach (Taguchi 법에 의한 흑목이버섯의 항산화활성 증진을 위한 열수추출 최적화)

  • Kim, Hyeon-Min;Hur, Won;Lee, Shin-Young
    • Food Engineering Progress
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    • v.15 no.3
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    • pp.221-229
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    • 2011
  • Optimization study of the hot water extraction for enhancing antioxidative activity from Auricularia auricula was performed by Taguchi approach using orthogonal matrix $L_9(3^4)$ method. The correlation between DPPH radical scavenging activity and the components of samples extracted from different extraction conditions were also analyzed. The correlation coefficient between DPPH radical scavenging activity and melanin content of A. auricula were 0.93, indicating 'good correlation'. The optimum extraction conditions was obtained at the extraction time of 1 hr. temperature of $85^{\circ}C$, solid: water ratio of 1: 40(w/v) and frequency of 2 times. Under these conditions, values of maximum DPPH free radical scavenging activity and melanin contents of A. auricula were $67.21{\pm}2.17$ and $52.94{\pm}2.10 mg/g$, respectively. Melanin content of 1.6 times and DPPH free radical scavenging effect of 130% were enhanced by optimization.

Relationship of Phenolic Compounds and Free-radical Scavenging Activity in Black and Red Rice Extract

  • Hu, Gao-Sheng;Xu, Kai-Xiu;Jeong, Soon Jae;Kim, Doh-Hoon
    • Korean Journal of Breeding Science
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    • v.42 no.2
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    • pp.129-138
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    • 2010
  • Total phenolic content, total anthocyanin content and antioxidant activity were analyzed from rice samples collected in Korea, Japan and China. The results showed that the total phenolic content and free-radical scavenging activity differed significantly in these rice lines. The correlation between content and activity was subsequently investigated. The results showed that in black rice, anthocyanin was the major phenolic component and that both phenolic content and anthocyanin content were closely correlated with free-radical scavenging activity. Reverse Phase High Performance Liquid Chromatography (RP-HPLC) data showed that cyanidin-3-O-glucoside and peonidin-3-O-glucoside composed about 90% of the total anthocyanin content in black rice and in red rice. In the red rice extract, the total phenolic content produced a high correlation coefficient with antioxidant activity but correlated very poorly with the total anthocyanin content. The $OD_{458}$ and the $OD_{500}$ values which represent the proanthocyanidin content of the rice extract, produced high correlation coefficients with antioxidant activity and total phenolic content. These results suggest that the $OD_{458}$ and the $OD_{500}$ values can be used to evaluate the quality of red rice. In addition, based on the data obtained, a competitive accumulation model of anthocyanin and proanthocyanidin in black and red rice was proposed.

Antioxidant Activities of Beverage Concentrates and Purees (음료 농축액 및 퓨레의 항산화 활성)

  • Kim, Dan Bi;Shin, Gi Hae;Cho, Ju Hyun;Baik, Soon Ok;Lee, Ok-Hawn
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.7
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    • pp.997-1002
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    • 2013
  • This study investigated the physicochemical properties (pH, Brix), total phenol content, antioxidant activities (DPPH radical scavenging activity and oxygen radical absorbance capacity (ORAC)), and nitrite scavenging activity of beverage concentrates and purees. All concentrates and purees were produced from natural materials and have been used as the main ingredients in health-related beverages. Our results show that the pH values and Brix of all concentrates and purees ranged from 2.81 to 5.12 and 1.70 to 70.30 Brix, respectively. The highest total phenol content (182.71 mg GAE/mL), DPPH radical scavenging activity (69.88%) and nitrite scavenging activity (28.19%) were obtained from acai berry puree. The concentrate from wild blueberry had the highest ORAC value ($27,514{\mu}M$ TE/mL). Among the correlation coefficient data, the total phenol content exhibited a high correlation coefficient (r=0.9099) and DPPH radical scavenging activity. These results suggest that concentrates and purees from natural materials contribute to antioxidant activities in healthy beverages.

Evaluation of Antioxidant and Nitrite Scavenging Activity of Seaweed Extracts (해조류 추출물의 항산화 및 nitrite 소거활성 평가)

  • Ahn, Seon-Mi;Hong, Yong-Ki;Kwon, Gi-Seok;Sohn, Ho-Yong
    • Journal of Life Science
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    • v.21 no.4
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    • pp.576-583
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    • 2011
  • In the course of study for the development of functional food ingredients from seaweeds having useful biological activities, the in-vitro antioxidant and nitrite scavenging activities of the methanol extracts prepared from 35 different seaweeds (17 phaeophyta, 11 rhodophyta and 7 chlorophyta) were determined. At $500\;{\mu}g/ml$ concentration of the methanol extracts, Ecklonia cava, Ecklonia stolonifera, Eisenia bicyclis (Kjellman) Setchell, Ishige foliacea, I. okamurai, Sargassum confusum, S. fulvellum, S. yamade and Zostera marina showed 60% more DPPH and ABTS scavenging activity. The exceptions were found in I. okamurai and Z. marina, which showed 45% and 53% ABTS scavenging activity, respectively. The correlation coefficient between DPPH and ABTS scavenging activities was 0.855, suggesting that the 9 different seaweeds extracts could scavenge anion and cation radicals concurrently. In reducing power, only E.cava, E.stolonifera and E.bicyclis showed above 0.88 ($Abs_{700}$). In a while, in nitrite scavenging activity at $100\;{\mu}g/ml$ concentration of the methanol extracts, 19 different seaweeds extracts including I. foliacea, I. okamurai, S. confusum, S. fulvellum, and S. yamade showed 60% more activity. Calculation of $IC_{50}s$ of DPPH, ABTS and nitrite scavenging activities of 9 different seaweeds extracts further showed that I. foliacea and S. yamade, besides E.cava, E.stolonifera and E.bicyclis, have strong antioxidant and nitrite scavenging activity. These results suggest that the selected 9 different seaweeds could be developed as functional food ingredients and I. foliacea and S. yamade have potential as novel natural sources of antioxidant and nitrite scavenger.

Characteristic Factors of Air-Plant Partitioning of PCBs (PCBs의 대기-식물간 분배 특성 인자들)

  • 여현구;최민규;천만영;김태욱;선우영
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.5
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    • pp.415-424
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    • 2001
  • The concentrations of PCBs (polychlorinated biphenyls) in air and plants (MOrus allba, Allum turberosum) were measured every other week at Hankyong University located in Ansung, Kyoung-ki province, Korea from July to November in 1999. Total concentrations of PCBs in air ranged from 19.8 to 71.9 pg/ $m^3$. It was observed in air that the concentrations of tai-chlorinated biphenyls(CBs) were higher than those of other PCB homologs probably due to their higher vapor pressure. Total concentrations of PCBs in plants ranged from 24.5 to 1,287 pg/g dry weight for Morus allba and 26.5 to 337 pg/g dry weight for Allum turberosum. A positive linear correlation was observed between log plant-air partition coefficients ( $m^3$air/g plant dry weight-defined here as the scavenging coefficient[S.C]) and log octanol-air partition coefficients ( $K_{oa}$ ) for each plant. In this study, slope of log S.C and log $K_{oa}$ for Morus allba, Allum turberosum were 1.07 ($R^2$= 0.83, p<0.01), 0.84 ($R^2$=0.53, p<0.05), respectively. This means that these plants may approach to equilibrium for air-plant partitioning.

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Extraction Procedures for Free Radical Scavenging Activity from Noni Fruit (Morinda citrifolia) (노니 과실에 함유된 항산화물의 추출 공정)

  • Gwak, Mi-Kyung;Choi, Hee-Sun;Manochai, Benya;Hong, Jeong-Hwa
    • Korean Journal of Medicinal Crop Science
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    • v.19 no.1
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    • pp.38-46
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    • 2011
  • In this study, we investigated maximum yield of radical scavenging activity (RSA) using each of various extraction solvents and procedure from noni friut (Morinda citrifolia). Noni fruits were either sun-dried (FS) or hot-air dried (FO) at $60^{\circ}C$ after steam blanching. For optimum aqueous extraction, noni fruits should be sun dried and autoclave extraction time should not be over 30 min to produce extraction with high RSA with low cost. In case of 50% ethanol extraction, reflux extracts of FS and FO resulted in $IC_{50}$ of 1.92 mg/mL and 3.06 mg/mL at 8 hr. When $IC_{50}$ values were lower than 5 mg/mL, coefficient of correlation was 0.71 indicating that 71% of the phenolic antioxidants in noni fruits were accounted for the activity by scavenging free DPPH. However, coefficient of correlation significantly decreased to 0.63 over $IC_{50}$ values of 5 mg/mL. Autoclave extraction contained chlorogenic acid of $14.69 \;{\mu}g/mL$ and scopoletin of $3.86 \;{\mu}g/mL$. Reflux extraction showed all three compounds, chlorogenic acid ($26.19 \;{\mu}g/mL$), quercetin ($19.59 \;{\mu}g/mL$), and scopoletin ($17.4 \;{\mu}g/mL$). Therefore, the result of this study indicated that the potential antioxidant activities and functional values were obtained significantly with reflux extraction from noni fruit.