• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.49 no.11
• /
• pp.893-900
• /
• 2021

In this study, air density in a narrow test section is measured using a laser absorption spectroscopy system that detects oxygen absorption lines. An absorption line pair at 13156.28 and 13156.62 cm^-1 are detected. A gas chamber with a height of 40 mm is used as a narrow test section. A triangular spiral-shaped laser path is applied in the gas chamber to amplify absorption strength by extending laser beam path length. A well-known logarithm amplifier and a secondary amplifier are used to electrically amplify absorption signal. An AC-coupling is applied after the logarithm amplifier for signal saturation prevention and noise suppression. Procedure of calculating spectral absorbance from output signal is introduced considering the logarithm amplifier circuit configuration. Air density is determined by fitting the theoretically calculated spectral absorbance to the measured spectral absorbance. Test conditions with room temperature and a pressure range of 10~100 kPa are made in a gas chamber using a Bourdon pressure gauge. It is confirmed that air density in a narrow test section can be measured within a 16 % error through absorption signal amplification using a triangular spiral-shaped beam path and a logarithm amplifier.

• Journal of the Microelectronics and Packaging Society
• /
• v.7 no.3
• /
• pp.37-44
• /
• 2000

The corrosion behavior of aluminum pad coated with epoxy molding compound (EMC) was investigated using electrochemical impedance spectroscopy (EIS). The impedance change was evaluated by the absorption of deionized water (DI water) to EMC coating and the interface between EMC and aluminum. During the absorption a decrease in resistance and thus an increase in capacitance of EMC as well as the interface of EMC/Al could be observed. Up to about 170 hours of absorption the EMC was saturated with the water molecules and ions generated from EMC. Subsequently the ionic water was penetrated to the interface and finally the corrosion of aluminum was occurred by the Dl water and ions. From measuring the adhesion strength with the Dl water absorption it was expected that the saturation of water and ions in the interface decreased the adhesion strength. The higher filler content of EMC should be necessary to inhibit the corrosion of aluminum electrode in microelectronic packages.

• Journal of Magnetics
• /
• v.19 no.3
• /
• pp.210-214
• /
• 2014

The effects of manganese substitution on the crystallographic and magnetic properties of Li-Zn-Cu ferrite, $Li_{0.5}Zn_{0.2}Cu_{0.4}Mn_xFe_{2.1-x}O_4$ ($0.0{\leq}x{\leq}0.8$), were investigated. Ferrites were synthesized via a conventional ceramic method. We confirmed the formation of crystallized particles using X-ray diffraction, field emission scanning electron microscopy and $M{\ddot{o}}ssbauer$ spectroscopy. All of the samples showed a single phase with a spinel structure, and the lattice constants linearly decreased as the substituted manganese content increased, and the particle size of the samples also somewhat decreased as the doped manganese content increased. All the $M{\ddot{o}}ssbauer$ spectra can be fitted with two Zeeman sextets, which are the typical spinel ferrite spectra of $Fe^{3+}$ with A- and B-sites, and one doublet. The cation distribution was determined from the variation of the $M{\ddot{o}}ssbauer$ parameters and of the absorption area ratio. The magnetic behavior of the samples showed that an increase in manganese content led to a decrease in the saturation magnetization, whereas the coercivity was nearly constant throughout. The maximum saturation magnetization was 73.35 emu/g at x = 0.0 in $Li_{0.5}Zn_{0.2}Cu_{0.4}Mn_xFe_{2.1-x}O_4$.

• Journal of Powder Materials
• /
• v.9 no.5
• /
• pp.341-345
• /
• 2002

Nanoparticles of $Fe_2O_3$ with a mean particle size of 4-30 nm have been prepared by a pulsed wire evaporation method, and its structural and magnetic properties were studied by SQUID magnetometer and Mossbauer spectroscopy. From the main peak intensity of XRD and absorption rate of Mossbauer spectrum, the amounts of $\gamma-Fe_2O_3$ and $\alpha-Fe_2O_3$ in as-prepared sample are about 70% and 30%, respectively. The coercivity (53 Oe) and the saturation magnetization (14 emu/g) are about 20% of those of the bulk $\gamma-Fe_2O_3$. The low value of coercivity and saturation magnetization indicate that the $\gamma-Fe_2O_3$ phase nearly shows the spin glass-like behavior. Analysis of the set of Mossbauer spectrum indicates a distribution of magnetic hyperfine fields due to the particle size distribution yielding 20 nm of average particle size. The magnetic hyperfine parameters are consistent with values reported of bulk $\gamma-Fe_2O_3$ and $alpha-Fe_2O_3$. A quadrupole line on the center of spectrum represents of superparamagnetic phase of $\gamma-Fe_2O_3$ with a mean particle size of 7 nm or below.

• Journal of Magnetics
• /
• v.15 no.1
• /
• pp.25-28
• /
• 2010

This study examined the crystallographic and magnetic properties of vanadium-substituted lithium cobalt titanium ferrite, $Li_{0.7}Co_{0.2}Ti_{0.2}V_{0.2}Fe_{1.7}O_4$. Ferrite was synthesized using a conventional ceramic method. The samples annealed below $1040^{\circ}C$ showed X-ray diffraction peaks for spinel and other phases. However, the sample annealed above $1040^{\circ}C$ showed a single spinel phase. The lattice constant of the sample was $8.351\;{\AA}$, which was relatively unaffected by vanadium-substitution. The average grain size after vanadium-substitution was $13.90\;{\mu}m$, as determined by scanning electron microscopy. The M$\ddot{o}$ssbauer spectrum could be fitted to two Zeeman sextets, which is the typical spinel ferrite spectra of $Fe^{3+}$ with A and B sites, and one doublet. From the absorption area ratio of the M$\ddot{o}$ssbauer spectrum, the cation distribution was found to be ($Co_{0.2}V_{0.2}Fe_{0.6})[Li_{0.7}Ti_{0.2}Fe_{1.1}]O_4$. Vibrating sample magnetometry revealed a saturation magnetization and coercivity of 36.9 emu/g and 88.6 Oe, respectively, which were decreased by vanadium-substitution.

• Journal of Magnetics
• /
• v.20 no.1
• /
• pp.26-30
• /
• 2015

The crystallographic and magnetic properties of gallium-substituted cobalt ferrite ($CoGa_xFe_{2-x}O_4$) were investigated. The new material was synthesized using conventional ceramic methods, with gallium substituted for ferrite in the range of x = 0.0 to 1.0, in steps of 0.2. X-ray diffraction and M$\ddot{o}$ssbauer spectroscopy were used to confirm the presence of crystallized particles in the $CoGa_xFe_{2-x}O_4$ ferrite powders. All of the samples exhibited a single phase with a spinel structure, and the lattice parameters decreased as the gallium content increased. The particle size of the samples also decreased as gallium increased. For $x{\leq}0.4$, the M$\ddot{o}$ssbauer spectra of $CoGa_xFe_{2-x}O_4$ could be fitted with two Zeeman sextets, which are the typical spinel ferrite spectra of $Fe^{3+}$ with A- and B-sites. However, for $x{\geq}0.6$, the M$\ddot{o}$ssbauer spectra could be fitted with two Zeeman sextets and one doublet. The variation in the M$\ddot{o}$ssbauer parameters and the absorption area ratio indicated a cation distribution of $(Co_{0.2-0.2x}Ga_xFe_{0.8-0.6x})[Co_{0.8+0.2x}Fe_{1.2-0.4x}]O_4$, and the magnetic behavior of the samples suggested that the increase in gallium content led to a decrease in the saturation magnetization and in the coercivity.

• Proceedings of the SCSK Conference
• /
• 2003.09b
• /
• pp.218-218
• /
• 2003

Recently we showed the prototype portable device for the determination of human skin moisture by using near infrared spectroscopy. In order to optimize the acquiring condition of NIR spectrum of skin and control the target information of water depending the site such as epidermis and dermis, skin depth profiling was investigated changing the distance between illuminations and receiving of radiation in the terminal of fiber probe. The colleted light information could be controlled by changing the distance of the fiber optic probes. It was confirmed that the longer distance we used, the deeper site from the skin surface we could get information from in this study. Four kinds of probes with distances such as 0.03 mm, 0.1 mm, 0.5 mm, and 1.0 mm were used. In addition, the gap size from 0.3 mm to 3.0 mm was studied to control the intensity of water absorbance effectively and to avoid saturation of water absorption. We also investigated the reference materials depending the reflectance ratio for water absorption not to be saturated because of the strong absorptivity of water. Furthermore, spectroscopic information regarding free water and bound water around 1850 nm was investigated by using the different distance of fiber optic probes. This study would be great help to control the spectroscopic information of water to be measured depending the site where water exists.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.305-305
• /
• 2012

The organic-inorganic hybrid polymer thin films were deposited using the gas phase method which known as molecular layer deposition (MLD). Titaniumchloride (TiCl4) and 1,4-phenylenediamine (PD) were used as monomers to deposit hybrid polymer. Self-terminating nature of TiCl4 and PD reaction were demonstrated by growth rate saturation versus precursors dosing time. Infrared spectroscopic and X-ray photoelectron spectroscopy were employed to determine the chemical composition and state of hybrid polymer thin films. Layer by layer growth was showed by increasing UV-VIS absorption peak of hybrid polymer thin films.

• Proceedings of the Optical Society of Korea Conference
• /
• 2000.08a
• /
• pp.86-87
• /
• 2000

최근 들어 희토류 원소(Rare earth elements)에 대한 학문적 가치와 산업적 응용에의 중요성에 대한 인식이 증대되면서 이들 원소에 대한 분광학적 연구가 활발하게 이루어지고 있다. 란탄족 원소(Lantanoid)로도 일컬어지는 6주기 3족 원소(원자번호 57~71번)인 희토류 원소들은 일반적으로 녹는점 및 끓는점이 상대적으로 높고 보다 복잡한 원자 구조를 가지고 있으므로 원자 분광학적 연구가 쉽지 않다. 따라서 이들 원소들에 대한 분광학적 정보를 얻기 위해서는 고효율의 원자 시료 발생 방법 및 고분해능의 원자 분광법이 요구된다$^{(1)}$ . (중략)

• Journal of Magnetics
• /
• v.18 no.1
• /
• pp.1-4
• /
• 2013

Structural and magnetic properties of $Fe_{50}Mn_{50}$ nanocrystalline alloys prepared by the mechanical alloying technique (using commercial Fe and Mn powders as the precursors) are studied as a function of milling time, 1 hr to 48 hrs. The nano-crystallite size and shape are examined by using scanning electron microscopy (SEM). The effect of milling time on structural characterization was investigated using X-ray diffractometer (XRD) and extended X-ray absorption fine structure spectroscopy (EXAFS). Both XRD and EXAFS studies showed that the alloying process should be completed after 36 hrs milling. Concerning the magnetic behavior, the data obtained from superconducting quantum interference devices (SQUID) exhibited both magnetic saturation ($M_s$) and coercivity ($H_c$) depend strongly on the milling time, which are related to the changes in the crystallite size and magnetic dilution.