• Title/Summary/Keyword: salt removal

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Influence of pH and Ionic Strength on Treatment of Radioactive Boric Acid Wastes by Forward Osmosis Membrane (정삼투막에 의한 붕산함유 방사성 폐액 처리를 위한 pH 및 이온강도 영향)

  • Choi, Hye-Min;Hwang, Doo-Seong;Lee, Kune-Woo;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.193-198
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    • 2013
  • In general, boron recovery of 40-90% could be achieved by Reverse Osmosis (RO) membranes in neutral pH condition. As an emerging technology, Forward Osmosis (FO) membrane has attracted growing interest in wastewater treatment and desalination. The objective of this study is to evaluate the possibility of the boron removal in radioactive liquid waste by FO. In this study, the performance of FO was investigated to remove boron in the simulated liquid waste as the factors such as pH, osmotic pressure, ionic strength of solution, etc. The pH of feed solution is a major operating parameter which strongly influences to the permeation of boron and more than 80% of boron content can be separated when conducted at pH values less than 7. The water flux is not influenced but the boron flux and permeation rate tends to decrease in the low salt concentration of 1,000 mg/L. The boron flux increases linearly, but the permeation ratio of reducing boron is nearly constant even with changes in the draw solution concentration.

Post-combustion CO2 capture with potassium L-lysine (Potassium L-lysine을 이용한 연소 후 이산화탄소 포집)

  • Lim, Jin Ah;Yoon, Yeo Il;Nam, Sung Chan;Jeong, Soon Kwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4627-4634
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    • 2013
  • Carbon dioxide is one of the main causes of global warming. In order to develop a novel absorbent, the characteristics of amino acid salts solution as a solvent for $CO_2$ capture in continuous process were investigated. The cost of $CO_2$ capture is almost 70% of total cost of CCS (carbon dioxide capture and storage). In the carbon dioxide capture process, process maintenance costs consist of the absorbent including the absorption, regeneration, degradation, and etc. It is very important to study the characteristics of absorbent in continuous process. In this study, we have investigated the properties of potassium L-lysine (PL) for getting scale-up factors in continuous process. To obtain optimum condition for removal efficiency of $CO_2$ in continuous process by varying liquid-gas (L/G) ratio, concentration of $CO_2$ and absorbent (PL) were tested. The stable condition of absorber and regenerator (L/G) ratio is 3.5. In addition, PL system reveals the highest removal efficiency of $CO_2$ with 3.5 of L/G and 10.5 vol% $CO_2$ ($1.5Nm^3/h$).

A Review of the Deterioration and Damage of the Top Flange of the Highway PSC Box Girder Bridge based on the Condition Assessment Results (상태평가 결과 기반 고속도로 PSC Box 거더교 상부플랜지 열화·손상 실태 고찰)

  • Ku, Young-Ho;Han, Sang-Mook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.23-32
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    • 2022
  • Although PSCB girder bridges account for 4% of the bridges in use on highways, they do not account for much, but 98% of PSCB girder bridges are 1st type and 2nd type of bridge. Also, the total length of the PSCB girder bridge is 16% (192km) of the total length of the highway bridge. Thus, the PSCB girder bridge can be one of the bridge types where maintenance is important. In order to analyze the damage types of PSCB girder bridges, a detailed analysis was conducted by selecting 62 places (477 spans) precision safety diagnosis reports considering ratio of the construction method and snow removal environment exposure class. Analysis of report and a field investigation was conducted, and as a result, most of the causes of deterioration damage were caused by rainwater (salt water) flowing into the bridge pavement soaking in between the top flange and the interface. After concrete slab deteriorate occurred then bridge pavement cracking and breaking increased and exfoliation of concrete occurred by corrosion and expansion of the reinforcing bars occurred. In addition, the cause of cracks in the longitudinal direction on the bottom of the top flange is considered to be cracks caused by restrained drying shrinkage. In conclusion, for reasonable maintenance considering the characteristics of PSCB girder bridges, it should be suggested in the design aspect that restrained drying shrinkage crack on top flange. Also, it is believed that differentiated maintenance method should be proposed according to snow removal environment exposure class.

Evaluation of RO Process Feasibility and Membrane Fouling for Wastewater Reuse (하수처리수 재이용을 위한 RO 공정의 타당성 및 막오염 평가)

  • Hong, Keewoong;Lee, Sangyoup;Kim, Changwoo;Boo, Chanhee;Park, Myunggyun;An, Hochul;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
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    • v.26 no.2
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    • pp.289-296
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    • 2010
  • The purpose of this study is to evaluate various pre-treatment methods and proprieties of water quality for wastewater reuse using reverse osmosis (RO) processes. Secondary effluents were sampled from wastewater treatment plants and lab scale pre-treatments and RO filtration test were conducted systematically. Specifically, different types of pre-treatments, such as coagulation, microfiltration and ultrafiltration, were employed to evaluate the removal efficiency of particle and organic matters which may affect the membrane fouling rate. RO process was later added to eliminate trace amounts of remaining organic matters and salt from the raw water for wastewater reclamation. The permeate through the RO process satisfied water quality regulations for industrial water uses. The experimental results showed that the initial fouling tendency differed not only by the feed water properties but also by the membrane characteristics. Membrane fouling was greater for the membranes with large surface roughness, regardless of the hydrophobicity and zeta potentials. Thus both careful consideration of pre-treatment options and proper selection of RO membrane are of paramount importance for an efficient operation of wastewater treatment.

Cleaning of the Waste Reverse Osmosis Membrane Filters for the Household Water Purifier and Their Performance Enhancement Study (정수기용 역삼투 폐분리막 필터의 세정 및 성능 향상 연구)

  • Cho, Young Ju;Rhim, Ji Won
    • Membrane Journal
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    • v.27 no.3
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    • pp.232-239
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    • 2017
  • In this study, the regeneration investigation for waste reverse osmosis membrane filters which were discarded after use for the household water purifiers has been carried out. Sodium hydroxide, sodium bisulfate, and ethylenediamine tetra acetic acid(EDTA). as the chemical cleaning agents were used. And they were in-situ cleaned with the micro-bubble generator as well. The best result was obtained when both 0.1% EDTA and micro-bubbles were used for 30 min cleaning. Thus, when the performance of the brand new RO membrane and restorated RO membrane were compared, the flux, 19.9%, the recovery ratio 45% were enhanced while the salt rejection was reduced for NaCl 100 mg/L solution, in other words, it has been recovered to the original brand new RO membrane filter. Also the removal of pollutants on membrane surface was confirmed in a naked eye through the scanning electron microscopy. Finally, this research has provided the possibility of the re-use of the waste RO membrane filters of household water purifier which were reclaimed or incinerated after use.

Correlation of Releases of Nutrient Salts in Sediment with Vicinal Oxic Conditions (퇴적물의 영양염류 용출과 호기적 조건과의 상관성 분석)

  • Cho, Dae-Chul;Lee, Eun-Mi;Park, Byung-Gi;Kwon, Sung-Hyun
    • Journal of Environmental Science International
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    • v.20 no.7
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    • pp.845-855
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    • 2011
  • The aim of this paper is to correlate the release characteristics of marine and lake sediment with their vicinal oxic conditions. We performed lab-scale simulation experiments using field sediment and water in order to compare the release concentrations and the release rates one another. To provide a few different kinds of oxic environments we used natural air flow and some oxygen releasing compounds such as $CaO_2$ and $MgO_2$. In case of phosphates, in each oxic condition, removal of phosphorus via biological activity and that via salt precipitation with the metal ions lowered the release rates. The behavior of the nitrogen-origin salts seemed to greatly depend on the typical biological actions - growth of biomass, nitrification, and partial denitrification. Generally speaking, the control of releases of $NH_3$-N, $PO_4$-P, T-N and T-P was successful under the oxic conditions meanwhile COD, nitrates and nitrites were difficult to reduce the releases into the bulk water because of the considerable microbial oxidation. Based on typical diffusive mass transfer kinetics the changes of concentrations of the nutrients were computed for qualitative and quantitative comparisons.

Purification and Properties of Wheat Fructan Exohydrolase (밀 Frucdtan Exohydrolase의 분리 및 특성)

  • Byeong Ryong, Jeong;Thomas L, Housley
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.4
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    • pp.456-464
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    • 1996
  • Fructans are the major vegetative storage carbohydrate in wheat(Triticum aestivum L.). The depolymerization of fructans occurs by the sequential removal of terminal fructosyl residues by a specific fructan exohydrolase(FEH). The objective of this study was to isolate and characterize this enzyme in wheat. From stems and sheaths of field-grown wheat(cv. Clark), FEH was purified 356-fold using salt precipitation and a series of chromatographic procedures including size exclusion, anion exchange, and affinity chromatography. FEH had a molecular weight of 63.7 kD and an optima at pH 5.5 and 3$0^{\circ}C$. The $K_{m}$s for $\beta$(2 longrightarrow1) linked oligofructans varied, from 10 to 37mM, with the lowest $K_{m}$ for tetrasaccharide. The $V_{max}$ increased as degree of polymerization (DP) increased. Wheat FEH hydrolyzed only, $\beta$(2 longrightarrow1) linked fructans but not, $\beta$(2 longrightarrow6) linked timothy fructan or sucrose. The role of this FEH in fructan metabolism in wheat is discussed.sed.

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Image Enhancement of Image Intensifying Device in Extremely Low-Light Levels using Multiple Filters and Anisotropic Diffusion (다중필터와 이방성 확산을 이용한 극 저조도 조건에서의 미광증폭장비 영상 개선)

  • Moon, Jin-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.7
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    • pp.36-41
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    • 2018
  • An image intensifying device is equipment that makes weak objects visible in a dark environment, such as making nighttime bright enough to let objects be visually observed. It is possible to obtain a clear image by amplifying the light in the presence of a certain amount of weak light. However, in an extremely low-light environment, where even moonlight is not present, there is not enough light to amplify anything, and the sharpness of the screen deteriorates. In this paper, a method is proposed to improve image quality by using multiple filters and anisotropic diffusion for output noise of the image-intensifying device in extreme low-light environments. For the experiment, the output of the image-intensifying device was obtained under extremely low-light conditions, and signal processing for improving the image quality was performed. The configuration of the filters for signal processing uses anisotropic diffusion after applying a median filter and a Wiener filter for effective removal of salt-and-pepper noise and Gaussian noise, which constitute the main noise appearing in the image. Experimental results show that the improvement visually enhanced image quality. Both peak signal-to-noise ratio (PSNR) and SSIM, which are quantitative indicators, show improved values.

Study on the Preparation of Nickel Cabonate Using Nickel Chloride Prepared from Nickel MHP (니켈 MHP로부터 제조된 염화니켈을 이용한 탄산니켈 제조연구)

  • Kang, Yong-Ho;Shin, Gi-Wung;Hyun, Soong-Keun
    • Resources Recycling
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    • v.27 no.5
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    • pp.23-29
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    • 2018
  • Generally $NiSO_4$ and $NiCl_2$ were used as raw materials for producing nickel carbonate. In the case of the produced nickel carbonate, $Na_2SO_4$ and NaCl are generated on the surface and inside of the nickel carbonate to decrease the purity of the nickel carbonate. High purity nickel carbonate can be produced according to the degree of removal of such impurities. In this study, $NiCl_2$ produced by nickel MHP solvent extraction process was used to study the production of nickel carbonate. High purity nickel carbonate was prepared by the conditions according to the nickel salt and carbonate equivalence ratio, the reduction of Na and Cl in nickel carbonate according to the washing of nickel carbonate, and the reduction of Na and Cl according to the washing water temperature.

Preparation and Characterization of Low Molecular Weight Water Soluble Chitosan Gene Carrier Fractioned according to Molecular Weight (저분자량 수용성 키토산이 분급화된 유전자 전달체의 제조 및 특성)

  • Jang, Min-Ja;Kim, Dong-Gon;Jeong, Young-Il;Jang, Mi-Kyeong;Nah, Jae-Woon
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.555-561
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    • 2007
  • To obtain low molecular weight water soluble chitosan (LMWSC) with various molecular weights, chitosan oligosaccharides (COS) with lactic acid was separated by using ultrafilteration technique and LMWSC with a free amine group was prepared by the novel salts-removal method. The characterization of LMWSC removed the lactic acid and degree of deacetylation (DDA) were identified by FT-IR and $^1H-NMR$ spectra. Polydispersity index (PDI) was $1.278{\sim}1.499$, which indicates a relatively molecular weight distribution. To identify the potential as a gene carrier, we confirmed the transfection efficiency of COS fractioned according to molecular weight successfully and the salt-removed LMWSC using 293T cell. Also, LMWSC derivatives prepared for improvement transfection efficiency were evaluated using Balb/C mice.