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http://dx.doi.org/10.5762/KAIS.2013.14.9.4627

Post-combustion CO2 capture with potassium L-lysine  

Lim, Jin Ah (Greenhouse Gas Research Center, Korea Institute of Energy Research)
Yoon, Yeo Il (Greenhouse Gas Research Center, Korea Institute of Energy Research)
Nam, Sung Chan (Greenhouse Gas Research Center, Korea Institute of Energy Research)
Jeong, Soon Kwan (Greenhouse Gas Research Center, Korea Institute of Energy Research)
Publication Information
Journal of the Korea Academia-Industrial cooperation Society / v.14, no.9, 2013 , pp. 4627-4634 More about this Journal
Abstract
Carbon dioxide is one of the main causes of global warming. In order to develop a novel absorbent, the characteristics of amino acid salts solution as a solvent for $CO_2$ capture in continuous process were investigated. The cost of $CO_2$ capture is almost 70% of total cost of CCS (carbon dioxide capture and storage). In the carbon dioxide capture process, process maintenance costs consist of the absorbent including the absorption, regeneration, degradation, and etc. It is very important to study the characteristics of absorbent in continuous process. In this study, we have investigated the properties of potassium L-lysine (PL) for getting scale-up factors in continuous process. To obtain optimum condition for removal efficiency of $CO_2$ in continuous process by varying liquid-gas (L/G) ratio, concentration of $CO_2$ and absorbent (PL) were tested. The stable condition of absorber and regenerator (L/G) ratio is 3.5. In addition, PL system reveals the highest removal efficiency of $CO_2$ with 3.5 of L/G and 10.5 vol% $CO_2$ ($1.5Nm^3/h$).
Keywords
Potassium L-lysine; Amino acid salt solution; $CO_2$ capture; Continuous process;
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  • Reference
1 Korea Carbon Capture & Sequestration R&D Center, www.kcrc.re.kr
2 J. K. Lim, "UNFCCC National Communication", Korea Energy Economics Institute, 2003.
3 B. A. Oyenekan, G. T. Rochelle, "Energy Performance of Stripper Configurations for $CO_2$ Capture by Aqueous Amines", Ind. Eng. Chem. Res., 45, 2457-2464, 2006 DOI: http://dx.doi.org/10.1021/ie050548k   DOI   ScienceOn
4 A. Belld, and R. O. Idem, "Comprehensive Study of the Kinetics of the Oxidative Degradation of $CO_2$ Loaded and Concentrated Aqueous Monoethanolamine(MEA) with and without Sodium Metavanadate during $CO_2$ Absorption from Flue Gases", Ind. Eng. Chem. Res., 45, 2569-2579, 2006. DOI: http://dx.doi.org/10.1021/ie050562x   DOI   ScienceOn
5 J. Gabrielsen, H. F. Svendsen, M. L.Michelsen, E. H. Stenby, G. M.Kontgeorgis, " Experimental Validation of a Rate-based Model for $CO_2$ Capture using an AMP Solution", Chem. Eng. Sci., 62, 2397-2413, 2007 DOI: http://dx.doi.org/10.1016/j.ces.2007.01.034   DOI   ScienceOn
6 J. Zhang, S. Zhang, K. Dong, Y. Zhang, Y. Shen, X. Lv, "Supported absorption of $CO_2$ by tetrabutyphosphonium amino acid ionic liquids." Chemistry., 12(5), 4021-4026, 2006   DOI   ScienceOn
7 P.S. Kumar, J.A. Hogendoorn, P.H.M. Feron, G.F. Versteeg, "Equilibrium solubility of $CO_2$ in aqueous potassium taurate solutions: Part 1. Crystallization in carbon dioxide loaded aqueous salt solutions of amino acids.", In. Eng. Chem. Res., 42(12) 2832-2840, 2003 DOI: http://dx.doi.org/10.1021/ie0206002   DOI   ScienceOn
8 P.S. Kumar, J.A. Hogendeeorn, S.J. Timmer, P.H.M Feron, G.F. Versteeg, Equilibrium solubility of $CO_2$ in aqueous potassium taurate solutions: Part 2. Experimental VLE data and model.", In. Eng. Chem. Res., 42(12) 2841-2852 ,2003   DOI   ScienceOn
9 Lee, S., Song, H.J., Maken, S., H.C., Song, H.C. and Park, J., "Physical solubility and diffusivity of N2O and $CO_2$ in aqueous sodium glycinate solution.", J. Chem. Eng. Data., 51(2), 504-509, 2006 DOI: http://dx.doi.org/10.1021/je0503913   DOI   ScienceOn
10 H.J. Song, S.M. Lee, J.H. Lee, J.W. Park, K.R. Jang, J.G. Shim, J.H. Kim, "Absorption of carbon dioxide into aquous potassium salt of serine.", KSEE., 31, 505-514, 2008
11 J.E. Crooks, J.P. Donnellan, "Kinetics and Mechanism of the Reaction between Carbon Dioxide and Amines in Aqueous Solution", J. Chem. Soc., Perkin transactions 2, 4, 331-333, 1989 DOI: http://dx.doi.org/10.1039/p29890000331   DOI
12 E. S. Fernamdez, E. L. V. Goetheer, " DECAB: process development of a phase change absorption process", Energy Procedia, 4, 868-875, 2011. DOI: http://dx.doi.org/10.1016/j.egypro.2011.01.131   DOI   ScienceOn
13 H. Bosch, G.F. Versteeg, W.P.M. Van Swaaij, "Gas-liquid mass transfer with parallel reversible reaction-I. Absorption of $CO_2$ into solutions of sterically hindered amines", Chem. Eng. Sci., 44(11), 2723-2734, 1989 DOI: http://dx.doi.org/10.1016/0009-2509(89)85217-0   DOI   ScienceOn
14 P.M.M. Blauwhoff, G.F. Versteeg, W.P.M. Van Swaaij, "A Study on The Reaction Between $CO_2$ and Alkanolamines in Aqueous Solutions", Chem. Eng. Sci., 39(2), 207-225, 1984 DOI: http://dx.doi.org/10.1016/0009-2509(84)80021-4   DOI   ScienceOn
15 G.F. Versteeg, J.A.M. Kuipers, F.P.H. Van Beckum, W.P.M. Van Swaaij, "Mass transfer with complex reversible chemical reactions-I. Single reversible chemical reaction. Chem. Eng. Sci., 44(10), 2295-2310, 1989 DOI: http://dx.doi.org/10.1016/0009-2509(89)85163-2   DOI   ScienceOn