• Title/Summary/Keyword: rubber properties

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A review: role of interfacial adhesion between carbon blacks and elastomeric materials

  • Kang, Min-Joo;Heo, Young-Jung;Jin, Fan-Long;Park, Soo-Jin
    • Carbon letters
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    • v.18
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    • pp.1-10
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    • 2016
  • Carbon blacks (CBs) have been widely used as reinforcing materials in advanced rubber composites. The mechanical properties of CB-reinforced rubber composites are mostly controlled by the extent of interfacial adhesion between the CBs and the rubber. Surface treatments are generally performed on CBs to introduce chemical functional groups on its surface. In this study, we review the effects of various surface treatment methods for CBs. In addition, the preparation and properties of CB-reinforced rubber composites are discussed.

A Study on Electromagnetic Wave Absorbing Properties of Complex Isotropic Ferrite-Rubber Composite (복합형 등방성 Ferrite-Rubber Composite의 전자파 흡수특성에 관한 연구)

  • 김동일;박연준;김하근;사공건
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.1
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    • pp.35-42
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    • 1999
  • This paper describes the characteristics of the complex isotropic ferrite-rubber composite for a super wideband electromagnetic absorber in RP-A-PF type, which can be used for an anechoic chamber, wall material to prevent TV ghost, etc. The $Ni_x-A_{0.1}-ZN_{(1-x0.1)}$. $Fe{_2}O_4$ ferrite powder has been fabricated. Using this, then, [$Ni_x-A_{0.1}-ZN_{(1-x0.1)}$. $Fe{_2}O_4$]-Rubber composite for RF-layer in the RF-A-PF type absorber has been fabricated and it's characteristics has been analyzed. As a result, it has been shown that the [$Ni_x-A_{0.1}-ZN_{(1-x0.1)}$. $Fe{_2}O_4$].Rubber composite has excellent electromagnetic wave absorbing properties.

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The Improvements for Fire Retardancy and Radiation Resistance of Chloroprene Rubber (클로로프렌 고무의 난연성 및 내방사선 특성 향상)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1205-1211
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    • 2004
  • This study has investigated radiation degradation of chloroprene rubber in the presence of some fire retardant. Ammonium polyphosphate, aluminium trihydroxide, magnesium hydroxide, calcium carbonate and antimony trioxide were selected as flame retardant. Samples were irradiated using a Co$^{60}$ ${\gamma}$ -ray and ray up to 2000 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, samples were assessed fire retardancy with electrical properties and mechanical properties. Some considerations concerning the effects of the fire retardants added to chloroprene rubber on the radiation and thermal stability of chloroprene rubber are presented. From fire retardancy with electrical and mechanical property measurements, it was found that addition of magnesium hydroxide resulted in maximum fire retardant effect.

THE ABSORPTION PROPERTIES OF Cu-Zn FERRITE/RUBBER COMPOSITE MICROWAVE ABSORBER WITH PZT ADDITIVE

  • Shin, Kwang-Ho;Geon, Sa-Gong
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.556-560
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    • 1995
  • The absorption properties of Cu-Zn ferrite/rubber composite microwave absorbers with PZT(Lead Zirconate Titanate) additive were evaluated. The composite specimens have prepared by molding and curing the mixture of matrix rubber and Cu-Zn ferrite powders which are synthesized by the coprecipitation method using Fe Cl/sub 3/ .center dot. 6H/sub 2/O, CuCl/sub 2/ .center dot. 2H/sub 2/O and Zn Cl/sub 2/ as a starting raw materials. PZT is used as another filler particles to adjust the material constants of Cu-Zn ferrite/rubber composite specimens. We have found that the material constants of specimens could be controlled by various PZT mixing ratio. On the Cu-Zn ferrite/rubber composite specimens with PZT 10[wt%] additive, the reflection losses were larger than 30[dB] in the frequency range from 2.72 to 4.4[GHz]' by adjusing the thickness.

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Effects of Fiber Aspect Ratio, Fiber Content, and Bonding Agent on Tensile and Tear Properties of Short-Fiber Reinforced Rubber

  • Lee, Dong-Joo;Ryu, Sang-Ryeoul
    • Journal of Mechanical Science and Technology
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    • v.15 no.1
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    • pp.35-43
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    • 2001
  • Both tensile and tear properties of short-fiber reinforced Chloroprene rubber have been studied as functions of the fiber aspect ratio and fiber content. Both properties increased when both the fiber aspect ratio and fiber content were increased. The fiber reinforced rubbers exhibited maximum values of these properties at a fiber aspect ratio of about 300. When the fiber aspect ratio exceeds 400, the mechanical properties decreased with the fiber content because of the non-uniform dispersion of fibers. The tensile modulus was compared with the prediction by the Halpin-Tsai equations for randomly oriented cases. A bonding agent was used in the fiber treating process. It was found that the ultimate tensile strength, torque, tearing energy and tensile modulus of the rubbers with treated fibers were much higher than those with untreated ones.

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The Study on the Properties of EPDM/NR Blends (EPDM/NR 블랜드의 물성에 관한 연구)

  • Go, Jin-Hwan;Park, Sung-Soo
    • Elastomers and Composites
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    • v.29 no.2
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    • pp.121-130
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    • 1994
  • The physical properties of rubber blend between natural rubber(NR) and ethylene propylene diene terpolymer(EPDM) were investigated as a study of EPDM composite materials. For EPDM/NR blends, the effects of ethylene and diene contents in EPDM, blend ratio, dicumyl peroxide(DCP) curing system on the physical properties, interfacial adhesion force and dynamic crack growth etc. were studied. EPDM/NR blends loaded with carbon black were prepared by mechanical mixing and cured by plate heating cure press. Crosslinking density was measured by swelling method with toluene. The physical properties of all blends were measured with Instron, fatigue to failure(FTF), Demattia flex cracking tester(DMFC), scanning electron microscopy (SEM), etc. As the ethylene and diene contents in EPDM increased, the physical properties, such as dynamic crack growth, adhesion to other component were increased too. Interfacial adhesion force of EPDM/NR blends to dissimilar layer was improved by the use of optimum peroxide curing system.

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Characterization and Fatigue Life Evaluation of Rubber/Clay Nanocomposites (고무-점토 나노복합체 물성 및 피로내구성 평가)

  • Woo, Chang-Su;Park, Hyun-Sung;Joe, Deug-Hwan;Jun, Young-Sig
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1199-1203
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    • 2011
  • Nanocomposites were prepared through the compounding of rubber and clay. Measurements of the static and dynamic mechanical properties of different compositions over a temperature range $70-100^{\circ}C$ showed that the mechanical properties of these rubber/clay nanocomposites are superior to those of existing rubber materials. In this study, by using the parameter of the maximum Green.Lagrange strain appearing at certain locations, the relationship between fatigue life and maximum Green.Lagrange strain, and the correlations between test-piece tests and bench tests of actual rubber components are proved. In order to predict the fatigue life of rubber components at the design stage, a simple procedure of life prediction is suggested. The predicted fatigue lives of the rubber engine mounts agree fairly well with the fatigue lives determined experimentally.

Mechanical Property, Thermal Conductivity, Rebound Resilience and Thermal Property of Chloro Isobutylene Isoprene Rubber/Ethylene Propylene Diene Monomer Blend

  • Hwang, Young-Bea;Lee, Won-Ki;Park, Chan Young
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.80-85
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    • 2018
  • Chloro isobutylene isoprene rubber (CIIR) and ethylene propylene diene monomer (EPDM) compounded with other formulation chemicals, depending on the polymer blend, were prepared by mechanical mixing. After manufacturing the rubber vulcanizate by compression molding with a hot press, the mechanical and thermal properties including thermal conductivity, rebound resilience of the CIIR/EPDM blends were measured. As the EPDM rubber content increased, hardness and tension set showed a tendency to increase. Pure CIIR exhibited the lowest tensile strength; however, tensile strength increased with loading of EPDM rubber. On the other hand, in CIIR rubber, which is usually a low-rebound elastomer owing to a high damping effect, rebound resilience exhibited an increasing trend as the content of EPDM rubber increased. As the EPDM rubber content increased, thermal stability was improved due to reduction of decomposition rate in the rubber region of the blend vulcanizate.

The change of surface degradation properties of silicone rubber for salt fog (염무-열 반복 열화에 따른 실리콘 고무의 표면열화특성변화)

  • Oh, Tae-Seung;Lee, Chung;Park, Soo-Gil;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.886-889
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    • 2001
  • Silicone rubber is being used for the housing material of outdoor high voltage insulators such as composite insulator, bushing, surge arrestor and cable terminator because of good tracking and erosion resistance, good hydrophobicity and recovery of hydrophobicity and chemical stability. But, the leakge current occurs on surface of the composite polymeric insulation materials when the insulator is used for a long time with severe contaminative condition and it can lead the contamination flashover. So the leakage current is important to estimate the condition of the silicone rubber surface. In this paper, aging characteristics of silicone rubber used for outdoor insulation have been hydrophobicity of silicone rubber in salt fog chamber with average leakage current monitoring for observing the transformation of surface degradation properties of silicone rubber with different ATH(alumina trihydrate, A1$_2$O$_3$$.$3H$_2$O) filler contents. The experimental results show that a higher peak leakage current and to raise a long time for tracking with increasing amount of ATH by the salt fog and heat recycle ageing.

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Influence of Filler Composition Ratio on Properties of Both Silica and Carbon Black-Filled Styrene-Butadiene Rubber Compounds (실리카와 카본블랙으로 보강된 SBR 고무 배합물의 특성에 보강제 조성비가 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.37-43
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    • 2001
  • Influence of the filler composition ratio on cure characteristics and bound rubber content of the compounds and on physical properties of the vulcanizates were studied using both silica and carbon black-filled styrene-butadiene rubber (SBR) compounds with the total filler content of 80.0 phr. The bound rubber content increased slightly with increase of the silica content ratio. The viscosity also increased with increasing the silica content ratio, especially increased steeply after the silica content of 60.0 phr. The cure times obtained with a rheometer, t2, t40, and t90, are increased by increasing the silica content ratio and the cure rate decreased. The delta torque increased with the increased silica content ratio. Variation or the modulus with the silica content ratio showed a decreased trend though the delta torque increased. The tan ${\delta}$ at $60^{\circ}C$ decreased with increased of the silica content ratio.

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