Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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The Improvements for Fire Retardancy and Radiation Resistance of Chloroprene Rubber

클로로프렌 고무의 난연성 및 내방사선 특성 향상

  • 김기엽 (한국원자력연구소 방사선이용연구부) ;
  • 이청 (한국원자력연구소 방사선이용연구부) ;
  • 류부형 (동국대학교 안전공학과)
  • Published : 2004.11.01
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Abstract

This study has investigated radiation degradation of chloroprene rubber in the presence of some fire retardant. Ammonium polyphosphate, aluminium trihydroxide, magnesium hydroxide, calcium carbonate and antimony trioxide were selected as flame retardant. Samples were irradiated using a Co$^{60}$ ${\gamma}$ -ray and ray up to 2000 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, samples were assessed fire retardancy with electrical properties and mechanical properties. Some considerations concerning the effects of the fire retardants added to chloroprene rubber on the radiation and thermal stability of chloroprene rubber are presented. From fire retardancy with electrical and mechanical property measurements, it was found that addition of magnesium hydroxide resulted in maximum fire retardant effect.

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References

  1. F. Bouquet and J. Winslow, 'Radiation Data for Design and Qualification of Nuclear Plant Equipment', EPRI Report, NP-4172SP, 1985
  2. D. W. Clegg and A. A. Collyer, 'Irradiation Effects on Polymers', ISBN 1-85166-563-3, pp. 360-370, Elsevier Science Publishers, 1991
  3. Maurice Morton, 'Rubber Technology', p. 339, and p. 360, 1987
  4. W. Tillar Shugg, 'Handbook of Electrical and Electronic Insulating Materials', p. 26, and p. 121, 1986
  5. W. C. Kuryl and A. J. Papa, 'Flame retardancy of polymeric materials', Marcel Dekker, New York, Vol. 3, p. 29, 1980
  6. H. K. Kim, J. H. Keun, H. S. Hahm, M. S. Pyoun, and H. S. Park, 'Preparation of Phosphate Type Softening Flame Retardant for Synthetic Fibers and Its Characterization', J. Kor. Fiber Soc. 30, p. 752, 1993
  7. C. M. Dick, J. J. Liggat, and C. E. Snape, 'Solid state 13C NMR study of the char forming processes in polychloroprene', Polymer Degradation and Stability, Vol. 74, p. 397, 2001 https://doi.org/10.1016/S0141-3910(01)00174-4
  8. B. Ivan, J. P. Kennedy, S. S. Plamthottam, T. Kelen, and F. Tudos, 'Characterization of polychloroprenes and cationically modified polychloroprenes by thermal dehydrochlorination', J. Polym. Sci.: Polym. Chem. Ed., Vol. 18, p. 1685, 1980
  9. Y. Miyata and M. Atsumi, 'Spectroscopic studies on the initial stages of thermal degradation of polychloroprene', J. Polym. Sci.: Part A : Polym. Chem., Vol. 26, p. 2561, 1988 https://doi.org/10.1002/pola.1988.080260925
  10. D. D. Jiang, 'Thermal degradation of crosslinked polyisoprene and polychloroprene', Polymer Degradation and Stability, Vol. 68, p. 75, 2000 https://doi.org/10.1016/S0141-3910(99)00167-6
  11. P. Budrugeac and E. Segal, 'Thermal degradation of polychloroprene rubber under isothermal and non-isothermal conditions', Journal of Thermal Analysis, Vol. 53, p. 441, 1998 https://doi.org/10.1023/A:1010185223746
  12. P. E. Mallon, W. J. McGill, and D. P. Shillington, 'A DSC study of the crosslinking of polychloroprene with ZnO and MgO', J. Appl. Polym. Sci., Vol. 55, p. 705, 1995 https://doi.org/10.1002/app.1995.070550507
  13. Young-II Mok, 'A Review of the Flame Retardation of Flamable Polymer', Chemical Engineering, Vol. 15, No.4, 1977
  14. 배헌재, "電氣 電線 絶綠材料", LG전선연구소,p. 138, 1987.
  15. Z. Wang, G. Wu, Y. Hu, and Y. Ding, 'Thermal degradaion of magnesium hydroxide and red phosphorus flame retarded polyethylene composites', Polymer Degradation and Stability, Vol. 77, p. 427, 2002 https://doi.org/10.1016/S0141-3910(02)00099-X
  16. 김기엽, 이 청, 김규백, 류부형, '난연제가 첨가된 Chlorosulfonated Polyethylene의 방사선 열화에 관한 연구', 전기전자재료학회논문지, 12권, 10호, p. 854, 1999
  17. 김기엽, 이 청, 김재희, 'NSSS 기기 건전성 검사 $\cdot$ 진단 기술 개발 기술보고서', 한국원자력연구소, 2004