• 제목/요약/키워드: ring structure

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유기태양전지용 안트라퀴논 기반 전자 받게 분자의 특성 분석 (Characterization of Anthraquinone-Based Electron Acceptors for Organic Solar Cells)

  • 현창석;안병관
    • 한국전기전자재료학회논문지
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    • 제35권4호
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    • pp.366-371
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    • 2022
  • Recently many efforts have been made to develop a novel class of non-fullerene electron acceptor materials for high-performance organic solar cells. In this work, anthraquinone derivatives, TMAQ and THAQ, were prepared and their availability as electron acceptor materials for organic solar cells were investigated in terms of optical, thermal, electrochemical properties, and solar cell devices. Compared to TMAQ, a significant bathochromic shift of absorption band was observed for THAQ owing to intramolecular hydrogen-bond-assisted CT interactions. Thanks to the fused aromatic ring structure and benzoquinone unit, both TMAQ and THAQ exhibited a high thermal stability and an efficient electron reduction process. In particular, the intramolecular O-H---O=C hydrogen bond of THAQ plays an important role in improving the thermal stability and electron reduction properties. In the P3HT:acceptor solar cell system, THAQ-based devices had more than ca. 6 times higher power conversion efficiency than TMAQ -based devices. These results serve as a guide for developing high-efficient anthraquinone-based electron acceptor materials.

Effect of Channel Variation on Switching Characteristics of LDMOSFET

  • Lee, Chan-Soo;Cui, Zhi-Yuan;Kim, Kyoung-Won
    • Journal of Semiconductor Engineering
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    • 제3권2호
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    • pp.161-167
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    • 2022
  • Electrical characteristics of LDMOS power device with LDD(Lightly Doped Drain) structure is studied with variation of the region of channel and LDD. The channel in LDMOSFET encloses a junction-type source and is believed to be an important parameter for determining the circuit operation of CMOS inverter. Two-dimensional TCAD MEDICI simulation is used to study hot-carrier effect, on-resistance Ron, breakdown voltage, and transient switching characteristic. The voltage-transfer characteristics and on-off switching properties are studied as a function of the channel length and doping levels. The digital logic levels of the output and input voltages are analyzed from the transfer curves and circuit operation. Study indicates that drain current significantly depends on the channel length rather than the LDD region, while the switching transient time is almost independent of the channel length. The high and low logic levels of the input voltage showed a strong dependency on the channel length, while the lateral substrate resistance from a latch-up path in the CMOS inverter was comparable to that of a typical CMOS inverter with a guard ring.

Microstructural observations of shear zones at cohesive soil-steel interfaces under large shear displacements

  • Mamen, Belgacem;Hammoud, Farid
    • Geomechanics and Engineering
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    • 제25권4호
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    • pp.275-282
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    • 2021
  • Failure mechanism which can affect geotechnical infrastructures (shallow foundations, retaining walls, and piles) constitutes one of the most encountered problems during the design process. In this respect, the shear behavior of interfaces between grained soils and solid building materials, as well as those between cohesive soils should be investigated. Therefore, a range of ring shear tests with different cohesive soils and stainless-steel interfaces have been carried out through the Bromhead apparatus that allows simulating large displacements along a failure surface. The effects of steel rings roughness and soil type on the residual friction coefficient and the shear zone features (structure, thickness, and texture orientation angle) have been investigated using the Scanning Electron Microscopy. The obtained results indicate that the residual friction coefficient and the structural characteristics of the shear zone vary according to the surface roughness and the soil type. Scanning electron microscopy reveals that the particles inside the shear zone tend to be re-oriented. Also, the shear failure mechanism can be identified along with the interface, within the soil, or simultaneously at the interface and within the soil specimen.

산불 피해 소나무재의 해부 및 물리학적 특성 (Anatomical and Physical Characteristics of Pinus Densiflora Wood Damaged by Forest Fire)

  • 황원중;권구중;김남훈
    • Journal of the Korean Wood Science and Technology
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    • 제31권4호
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    • pp.1-7
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    • 2003
  • 본 연구에서는 산불 피해를 입은 소나무재의 유효 활용을 위한 기초자료를 얻고자 해부 및 물리학적 특성을 조사하였다. 산불 피해재의 수지구, 에피델리얼세포와 방사유세포내에는 건전재와 달리 과립모양의 물질이 많이 존재하였으며, 그 외의 목부 조직구조는 정상재와 거의 차이가 없었다. 건전재와 비교하여, 산불 피해재는 상대결정화도가 다소 높았으며, 생재함수율과 접선 및 방사단면 흡수량은 다소 낮게 나타났다. 수축율 및 팽윤율과 기본밀도는 정상재와 거의 유사한 값을 보여주었다.

스크류 추진형 검측 로봇의 효율적인 검측을 위한 스크류 구조 변화 메커니즘 (Screw Transformation Mechanism of Screw-Propelled Robot for Efficient Void Detection in Grease Pipe)

  • 김동선;김호중;김진현
    • 로봇학회논문지
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    • 제17권2호
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    • pp.172-177
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    • 2022
  • In general, detection robots using ultrasonic sensors are equipped with sensors to protrude outward or to contact objects. However, in the case of a screw-propelled robot that detects the inside of a reactor tendon duct, if the ultrasonic sensor protrudes to the outside, resistance due to grease is generated, and thus the propulsion efficiency is reduced. In order to increase the propulsion efficiency, the screw must be sharp, and the sharper the screw, the more difficult it is to apply a high-performance ultrasonic sensor, and the detection efficiency decreases. This paper proposes a screw shape-changing mechanism that can improve both propulsion efficiency and detection efficiency. This mechanism includes an overlapped helical ring (OHR) structure and a magnetic clutch system (MCS), and thus the shape of a screw may be changed to a compact size. As a result, the Screw-propelled robot with this mechanism can reduce the overall length by about 150 mm and change the shape of the screw faster and more accurately than a robot with a linear actuator.

Shrinkage and crack characteristics of filling materials for precast member joint under various restraint conditions

  • Lim, Dong-Kyu;Choi, Myoung-Sung
    • Advances in concrete construction
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    • 제14권2호
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    • pp.139-151
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    • 2022
  • Filling materials poured into precast member joint are subjected to restraint stress by the precast member and joint reinforcement. The induced stress will likely cause cracks at early ages and performance degradation of the entire structure. To prevent these issues and design reasonable joints, it is very important to analyze and evaluate the restrained shrinkage cracks of filling materials at various restraint conditions. In this study, a new time zero-that defines the shrinkage development time of a filling material-is proposed to calculate the accurate amount of shrinkage. The tensile stresses and strengths at different ages were compared through the ring test (AASHTO PP34) to evaluate the crack potential of the restrained filling materials at various restraint conditions. The mixture which contained an expansive additive and a shrinkage reducing agent exhibited high resistance to shrinkage cracking owing to the high-drying shrinkage compensation effect. The high-performance, fiber-reinforced cement composite, and ultra-high-performance, fiber-reinforced cement composite yielded very high resistance to shrinkage and cracking owing to the pull-out property of steel fibers. To this end, multiple nonlinear regression analyses were conducted based on the test results. Accordingly, a modified tensile stress equation that considered both the geometric shape of the specimen and the intrinsic properties of the material is proposed.

Direct strength evaluation of the structural strength of a 500 cbm LNG bunkering ship

  • Muttaqie, Teguh;Jung, DongHo;Cho, Sang-Rai;Sohn, Jung Min
    • Structural Engineering and Mechanics
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    • 제81권6호
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    • pp.781-790
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    • 2022
  • The present paper describes a general procedure of the structural safety assessment for the independent type C tank of LNG bunkering ship. This strength assessment procedure consists of two main scheme, global Finite Element Analysis (FEA) model primarily for hull structure assessment and detailed LNG Tank structures FEA model including the cylindrical tank itself and saddle-support structures. Two kinds of mechanism are used, fixed and slides constraints in fore and rear of the saddle-support structures that result in a variation of the reaction forces. Finite Element (FE) analyses have been performed and verified by the strength acceptance criteria to evaluate the safety adequacy of yielding and buckling of the hull and supporting structures. The detail of FE model for an LNG type C tank and its saddle supports was made, which includes the structural members such as cylindrical tank shell, ring stiffeners, swash bulkhead, and saddle supports. Subsequently, the FE buckling analysis of the Type C tank has been performed under external pressure following International Gas Containment (IGC) code requirements. Meanwhile, the assessment is also performed for yielding and buckling strength evaluation of the cylindrical LNG tank according to the PD 5500 unfired fusion welded pressure vessels code. Finally, a complete procedure for assessing the structural strength of 500 CBM LNG cargo tank, saddle support and hull structures have been provided.

Design of intelligent estimation of composite fluid-filled shell for three layered active control structure

  • Ghamkhar, Madiha;Hussain, Muzamal;Khadimallah, Mohamed A.;Ayed, Hamdi;Naz, Muhammad Yasin;Tounsi, Abdelouahed
    • Computers and Concrete
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    • 제29권2호
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    • pp.117-126
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    • 2022
  • The vibrational characteristic of three-layered cylindrical shell (CS) submerged in fluid with the ring support has been studied. The inner and outer layer is supposed to construct by isotropic layer. The composition of central layer is of functionally graded material type. Acoustic Wave condition has been utilized to present the impact of fluid. The central layer of cylindrical shell (CS) varies by volume fraction law that has been expressed in terms of polynomial. The main shell frequency equation has been obtained by theory of Love's shell and Rayleigh-Ritz technique. The oscillation of natural frequency has been examined under a variety of end conditions. The dependence of axial model has been executed with the help of characteristic beam function. The natural frequencies (NFs) of functionally graded material (FGM) shell have been observed of cylindrical shell along the shell axial direction. Different physical parameters has been used to examine the vibration characteristics due to the effect of volume fraction law. MATLAB software has been used to get result.

Methods of Improving Operational Reliability of Oil Well Casing

  • Sergey A. Dolgikh;Irek I. Mukhamatdinov
    • Corrosion Science and Technology
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    • 제23권1호
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    • pp.1-10
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    • 2024
  • Oil well casing leak is caused by contact of casing outer surface with formation electrolyte. It is usually associated with an aquifer with a high salt content or absence of a cement ring behind the casing. The only way to reduce external casing corrosion is through cathodic protection. Through cathodic polarization of casing structure, electron content in crystal lattice and electron density will increase, leading to a potential shift towards the cathodic region. At Tatneft enterprises, cathodic protection is carried out according to cluster and individual schemes. The main criterion for cathodic protection is the size of protective current. For a casing, the protective current is considered sufficient if measurements with a two-contact probe show that the electric current directed to the casing has eliminated all anode sites. To determine the value of required protective current, all methods are considered in this work. In addition, an analysis of all methods used to determine the minimum protective current of the casing is provided. Results show that the method of measuring potential drop along casing is one of the most reliable methods for determining the value of protective current.

포텐셜 자료해석을 통한 화산칼데라 구조 해석 (Analysis of the Geological Structure of the Hwasan Caldera Using Potential Data)

  • 박계순;류희영;양준모;이희순;권병두;엄주영;김동오;박찬홍
    • 한국지구과학회지
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    • 제29권1호
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    • pp.1-12
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    • 2008
  • 본 연구에서는 한반도 남동부의 의성분지 내에 위치하는 화산칼데라 지역을 대상으로 지구물리학적 연구를 수행하였다. 기존 연구들의 한계를 극복하기 위해 원격탐사를 통한 전체적인 구조 특성을 분석한 후에 정밀한 3차원 포텐셜 해석을 수행하는 기법을 적용하였다. 첫 번째 단계로, 수치지질도 및 DEM 자료와 인공위성 영상을 이용하여 대상 지역의 선구조를 분석하였다. 선구조 분석 결과는 선행 연구결과와 상당히 잘 부합되었고, 남-북 방향과 남동-북서방향이 가장 우세함을 보여주었다. 두 번째 단계로, 선구조 분석 결과를 고려하여 의성분지 전체 지역에서 조밀한 중력탐사 자료를 획득하였고 항공자력탐사 자료와의 복합 해석을 통해 광역적인 칼데라의 구조를 조사하였다. 파워 스펙트럼 기법을 이용한 분석 결과, 의성 분지 하부는 개략적으로 2개의 밀도 불연속면 이 존재하는 것으로 해석되었다. 첫 번째 불연속면의 심도는 약 1 km로 칼데라 지역 내에 존재하는 화산쇄설성 퇴적암의 심도나 화산칼데라의 ring vent 위치에서 관입하고 있는 관입암의 심도로 판단되며, 두 번째 심도는 약 3-5 km로 분지기반암의 심도와 관련 있는 것으로 추정된다. 또한 3차원 중력역산을 실시한 결과 남서쪽의 백악기 팔공산 화강암과 북동쪽의 불국사 관입암류에 의한 저밀도체가 나타나고, 화산칼데라 중앙부 부근에는 화산쇄설성 퇴적암류 또는 칼데라 형성 과정에서 침강된 상부의 퇴적층으로 해석된 퇴적층이 주변보다 낮은 밀도를 가지며 하부로 약 1.5 km까지 연장되어 있는 것으로 분석되었다. 그러나 포텐셜 자료는 그 특성상 수직 분해능이 양호하지 못하므로, 수직적인 발달 특성을 갖는 칼데라의 구조를 정확히 파악하기는 어렵다. 본 연구에서는 이런 한계점을 극복하기 위해서 동일 지역에서 이루어졌던 자기지전류 탐사 결과와 비교 분석하여 효과적인 해석을 수행하였다.