• 제목/요약/키워드: ring structure

검색결과 1,343건 처리시간 0.034초

갓(Brassica juncea)의 주 항균물질의 구조 분석 (Structural Analysis of Major Antimicrobial Substance Obtained from Leaf Mustard(Brassica juncea))

  • 강성구
    • 한국식품영양과학회지
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    • 제24권5호
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    • pp.702-706
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    • 1995
  • A major component(compound A) in the ethylacetate fraction exhibited a strong antimicrobial activity was identified by UV, IR, FABMS and NMR. The compound A showed strong absorbance at 209, 259 and 359nm, indicating a flavonoid ring structure. IR spectrum possessed absorbance of OH at 3400∼3300cm-1, ketone at around 1650cm-1, and aromatic C=C at around 1660cm-1. Molecular weight of the compound A calculated as 478 from the information of m/z 479(M+H)+ and m/z 477(M-H)+ in the FABMS spectrum. Molecular formula of this compound was found to be C22H22O12 from m/z 479.1220(+3.1mmu for C22H23O12) of HRFABMS spectrum and from 13C-NMR spectrum. 1H-NMR and 13C-NMR spectra of the compound A revealed aromatic proton and benzene rings. Distortionless enhancement by polarization transfer(DEPT) exhibited that the compound A possessed 10 quaternary carbons and 3 substituted benzene rings including a methoxy group substitution. The compound A was identified as isorhamnetin 3-O-β-glucopyranoside by spectrophotometric methods in conjunction with 1H-1H COSY, 1H-13C COSY and HMBC, which revealed a flavone with OH group at 3, 5, 7, and 4' and methoxy group at 3' positions esterified to glucose.

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Simultaneous source frequency phase referencing observations of H2O and SiO masers toward VX Sgr

  • Yoon, Dong-Hwan;Cho, Se-Hyung;Yun, Young-Joo;Choi, Yoon Kyung;Kim, Jaeheon
    • 천문학회보
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    • 제40권2호
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    • pp.40.3-41
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    • 2015
  • We performed simultaneous observations of H2O and SiO masers toward VX Sgr using the Korean VLBI Network (KVN) and Source Frequency Phase Referencing (SFPR) method. The observations were carried out at 5 epochs from 2014 February to 2015 June. The relative locations of the SiO with respect to the H2O maser emission were determined at two epochs by SFPR for the first time. The H2O masers show well developed asymmetric outflow features which are spread up to ~300 mas in diameter. On the other hand, the SiO masers show a ring-like structure close to the central star with ~ 30 mas diameter. The SFPR observational results at two epochs (${\varphi}=0.83$ and 0.99) provide similar relative locations of H2O and SiO maser features. These superposed maps of H2O and SiO masers lead us to investigate the development of outflow motions from relatively spherical SiO maser regions close to central star to aspherical H2O maser regions according to optical phase of stellar pulsation together with the prediction of the position of central star.

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Experimental Investigation of R(ω), T(ω) and L(ω) for Multi-Layer SRRs and Wires Metamaterials

  • Luo, Hao;Wang, Xian;Liao, Zhangqi;Wang, Tao;Gong, Rongzhou
    • Journal of electromagnetic engineering and science
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    • 제10권3호
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    • pp.186-189
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    • 2010
  • Reflection(R($\omega$)), transmission(T($\omega$)) and loss(L($\omega$)) characteristics of multi-layer metamaterials are investigated experimentally in free space with the incident EM waves perpendicular to the substrate plane. The sample is made of split-ring resonators(SRRs) and wires which are the typical model of metamaterials. The R($\omega$) and T($\omega$) of multi-layer metamaterials have been calculated from the measured S-parameters. In this paper, we got the impedance-matched result according to the curves of R($\omega$), meanwhile the T($\omega$) decreased with increasing number of layers. At last, we attained the result that the L($\omega$) gets to nearly 98% around 8 GHz, with R($\omega$)=T($\omega$)=0. The design presented in this paper achieves experimented loss near unity.

Transgenic Lettuce Expressing Chalcone Isomerase Gene of Chinese Cabbage Increased Levels of Flavonoids and Polyphenols

  • Han, Eun-Hyang;Lee, Ji-Sun;Lee, Jae-Woong;Chung, In-Sik;Lee, Youn-Hyung
    • 원예과학기술지
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    • 제29권5호
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    • pp.467-473
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    • 2011
  • Flavonoid are large group of the polyphenolic compounds which are distinguished by an aromatic or phenolic ring structure and the phenolic compounds are induced by microbial infection, ultraviolet radiation, temperature and chemical stress. They are known for their antioxidant activity, anti-allergic, anti-inflammatory, anti-microbial and anti-cancer activities. In this study, changes in flavonoid content were investigated using heterologous chalcone isomerase (CHI) expression system. Also, phenolic compounds level was measured to examine the relation between flavonoids and phenols contents. Explants of lettuce (Lactuca sativa L.) were transformed with Agrobacterium tumefaciens LBA 4404 strain containing pFLH-CHI (derived from pPZP2Ha3) vector constructed with CHI gene from Brassica rapa. The putative transgenic plants were confirmed by genomic DNA PCR analysis. Also the transcription levels of the gene were analyzed by semi-quantitative RT-PCR with gene specific primers. The total flavonoid contents were increased at $T_0$ and $T_1$ generations over 1.4 and 4.0 fold, respectively. Total phenol contents also increased at $T_1$ generation. These results indicate that CHI gene plays an important role to regulate the accumulation of flavonoids and its component changes.

정보보호 전문 인력 양성을 위한 교육과정 모델에 관한 연구 (A study on a curriculum for information protection specialty manpower training)

  • 이문구
    • 한국컴퓨터산업학회논문지
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    • 제5권8호
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    • pp.811-818
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    • 2004
  • 인터넷의 보급과, 산업 및 생활 전반에 걸쳐 전산화가 이루어지면서 사생활 보호 및 정보보호에 대한 요구가 증가하고 있지만 정보보호 산업분야의 전문 인력의 부족으로 많은 어려움이 있다. 때문에 본 논문에서는 정보보호 전문 인력 양성을 위한 교육과정을 제안하였다. 제안하는 교육과정은 필수 1,2 와 선택 1,2로 분류하였다. 정보보호 응용분야를 9개의 도메인으로 세분화 하여 시행되어야 할 교육과정을 링 구조로 제시하였다. 정보보호 응용분야의 9개 도메인에 따른 현장 실무 프로젝트와 연계된 교육 과정과 졸업 후 전공심화를 위한 강좌가 도메인별로 이루어져서 정보보호 심화과정을 지속적으로 진행한다.

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Ultrastructural Aspects of the Mixed Infections of Watermelon Mosaic Potyvirus and Cucumber Green Mottle Mosaic Tobamovirus Isolated from Watermelon

  • Kim, Jeong-Soo;Cho, Jeom-Deog;Park, Hong-Soo;Kim, Kyung-Soo
    • The Plant Pathology Journal
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    • 제16권4호
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    • pp.211-215
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    • 2000
  • Symptoms on 4 varieties of watermelons inoculated with watermelon mosaic potyvirus II isolated from watermelon (WMV-W) were severe mosaic and leaf malformation while those inoculated with cucumber green mottle mosaic tobamovirus from watermelon (CGMMV-W) were mild mosaic and chlorotic spots. Inoculation of the mixture of WMV-W and CGMMV-W produced extremely severe mosaic along with necrotic spots and general necrosis. Doubly infected plants were also stunted. Cells infected with WMV-W or CGMMV-W alone exhibited the intrinsically ultra-structural properties of each virus infection. WMV-W induced potyvirus-characteristic cylindrical inclusions in the cytosol. Virus particles were orderly aligned along the tonoplasts. CGMMV-W induced tobamovirus-characteristic stacked crystalline arrays of virus particles in the cytosol. Cells infected doubly with WMV-W and CGMMV-W contained striking cytopathic effects that were not present in single infection of each virus. The unique ring structure, nonagon, was that a single potyvirus particle was surrounded by 9 CGMMV-W tobamovirus particles.

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반능동 서스펜션용 MR CDC 댐퍼의 자기회로 설계기법 (Magnetic Circuit Design Methodology of MR CDC Dampers for Semi-Active Suspensions)

  • 박재우;정영대
    • 한국정밀공학회지
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    • 제25권10호
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    • pp.48-57
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    • 2008
  • MR Fluid, one of functional fluids, is developed for the application to automobile products. MR CDC damper using MR fluid has following principles. When ar electric current is applied to the solenoid, apparent viscosity of MR fluid passing through the annular gap which acts as magnetic circuits varies directly as the intensity of the current. These devices have a simple structure and excellent lime response characteristics, emerging as the alternatives of the conventional semi-active suspension systems. In this study, a design procedure of the magnetic circuit through the solenoid fore and the flux ring functioning as a magnetic path is investigated so as to optimize the design and performance of MR CDC dampers for the vehicles. In addition, an operating point on the B-H curve, the magnetization according to the variation in the annular gap, the pole piece width and the density of MR fluid are studied to design the optimal piston head within the restrained dimension range.

금속 유도 일측면 선결정화에 의해 제작된 다채널 다결정 실리콘 박막 트랜지스터 소자 및 회로의 전기적 특성 평가 (Dynamic Characteristics of Multi-Channel Metal-Induced Unilaterally Precrystallized Polycrystalline Silicon Thin-Film Transistor Devices and Circuits)

  • 황욱중;강일석;임성규;김병일;양준모;안치원;홍순구
    • 한국재료학회지
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    • 제18권9호
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    • pp.507-510
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    • 2008
  • Electrical properties of multi-channel metal-induced unilaterally precrystallized polycrystalline silicon thin-film transistor (MIUP poly-Si TFT) devices and circuits were investigated. Although their structure was integrated into small area, reducing annealing process time for fuller crystallization than that of conventional crystal filtered MIUP poly-Si TFTs, the multi-channel MIUP poly-Si TFTs showed the effect of crystal filtering. The multi-channel MIUP poly-Si TFTs showed a higher carrier mobility of more than 1.5 times that of the conventional MIUP poly-Si TFTs. Moreover, PMOS inverters consisting of the multi-channel MIUP poly-Si TFTs showed high dynamic performance compared with inverters consisting of the conventional MIUP poly-Si TFTs.

Synthesis and Characterization of Dendritic Nonlinear Optical Chromophore Containing Phenylene Attached with Bulky Alkyl Group

  • Choi, Jin-Joo;Kim, Kyoung-Mahn;Lim, Jong-Sun;Lee, Chang-Jin;Kim, Dong-Wook
    • Macromolecular Research
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    • 제15권1호
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    • pp.59-64
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    • 2007
  • Star-shaped, nonlinear optical (NLO) material was synthesized and its optical, thermal, and electro-optic properties were investigated. Three NLO-active dipolar chromophores containing a phenylene ring substituted with a bulky alkyl chain as a conjugation bridge were chemically bonded to the core of 1,1,1-tris(4-hydroxyphenyl)ethane to form a dendritic architecture. The chemical structure and purity of the chromophore were verified by NMR spectroscopy. The chromophore exhibited a broad absorption band centered at around 608 nm tailing up to 760 nm in toluene solution and also showed a discernible solvatochromic shift in more polar solvent. The chloroform solution of the dendrimer produced an absorption band with a red-shifted maximum as large as 28 nm when compared to that of the toluene solution. It was thermally stable up to $275^{\circ}C$ in a nitrogen atmosphere and had a glass transition temperature of $76^{\circ}C$. In a preliminary result, the polymer film containing the dendritic compound exhibited a shift of 19 pm/V taken at $1.55{\mu}$.

ICBD 법에 의한 $ Y_2O_3$박막특성에 관한 연구 (Properties of $ Y_2O_3$ Thin Films Prepared by ICBD Method)

  • 전정식;문종;이상인;심태언;황정남
    • 한국진공학회지
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    • 제5권3호
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    • pp.245-250
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    • 1996
  • $Y_2O_3$ thin film on si(100) was successfully grown by ionized cluster beam(ICBD) technique at substrate temperature of around $500^{\circ}C$ and pressure of ~$10^{-5}$Torr.To prevent the oxidation of Si substrae, a very thin yttrium layer was deposited on Si before reactive depositing of oxygen and yttrium source. In asdeposited stage, b.c.c and h.c.p strucutres of $Y_2O_3$ were observed from S-ary analysis. From the observation of spots and ring patterns in selected area diffractin(SAD) patterns. crystallane formation and growth could be proceeded during the deposition. $Y_2O_3$/mixed layer/$SiO_2=170\AA/50\AA/10\AA$ structure were verified by high resolution transmition electron imcroscopy(HRTEM) image, and the formation of amorphous layer of SiO2 was discussed . Electricla charateristics of the film were also investigated . In as-deposited Pt/$Y_2O_3$/Si sturcuture, leakage current was less than $10^{-6}$A/$\textrm{cm}^2$ at 7MV/cm strength.

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