• Title/Summary/Keyword: rheological properties

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Basic Studies on the Native Colored-Soybean Cultivars III. Variations and Preformances in Chemical Composition and Textural Property in Seeds of Collected Colored-Soybean Cultivars (유색 대두수집종의 특성연구 제III보 유색 대두수집종의 화학적 조성과 특성 변이)

  • 구자옥;이종욱;이영만
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.3
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    • pp.345-350
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    • 1983
  • Collected 38 varieties of colored-soybean seed cultivated under a given cultural conditions were tested in the various chemical compositions and rheological properties in seeds. As it were, protein, fat, carbohydrate, ash and water contents as a chemical contents were studied not only on their statistical variations, but also on interrelationships with their collaborated rheological characteristics; hardness, cohesiveness, elasticity, gumminess and chewiness. For the rheological analysis of the materials, the General Foods Texturometer and typical texturometer curve were used.

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Evaluation of interfacial tension for poly(methyl methacrylate) and polystyrene by rheological measurements and interaction parameter of the two polymers

  • Sung, Y.T.;Seo, W.J.;Kim, Y.H.;Lee, H.S.;Kim, W.N.
    • Korea-Australia Rheology Journal
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    • v.16 no.3
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    • pp.135-140
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    • 2004
  • Morphological and rheological properties of the poly(methyl methacrylate) (PMMA) and polystyrene (PS) blends were studied by scanning electron microscopy (SEM) and advanced rheometric expansion system (ARES). From the SEM results, the PMMA-PS blends showed dispersed morphology and the particle size of the dispersed phase was quite small (0.1~0.6 $\mu\textrm{m}$ compared with other immiscible polymer blends. Values of the interfacial tension of the PMMA-PS blend were obtained from the Choi-Schowalter and the Palierne emulsion models using the storage modulus of the PMMA and PS, and found to be 1.0 and 2.0 mN/m, respectively. The interfacial tension between the PMMA and PS was also calculated from the Flory-Huggins polymer-polymer interaction parameter ($\chi$) and found to be from 0.98 to 1.86 mN/m depending on the molecular weight and composition. Comparing the values of the interfacial tension from the Flory-Huggins polymer-polymer interaction parameter and the values measured by oscillatory rheometer, it is suggested that the interfacial tension of the PMMA-PS blend obtained from the polymer-polymer interaction parameter are in good agreement with the values obtained by rheological measurements.

Morphology and Rheology on the Blends of PLA/CMPS

  • Shin, Boo-Young;Jo, Gyu-Soon;Kang, Kyoung-Su;Lee, Tae-Jin;Kim, Bong-Shik;Lee, Sang-Il;Song, Jeong-Sup
    • Macromolecular Research
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    • v.15 no.4
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    • pp.291-301
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    • 2007
  • The rheological behaviors and morphologies of polylactide (PLA) and chemically modified plasticized starch (CMPS) blends were investigated. For this study, oscillatory shear flow measurements of the PLA, CMPS and their blends were performed. A scanning electron microscope (SEM) study was also conducted on the extracted extrudates of the blends. The morphology of the blend changed in relation to the composition: sphere-shaped CMPS disperse/continuous PLA, rod-like deformed CMPS phase/continuous PLA, a co-continuous structure with bridged CMPS long rods and PLA dispersed/continuous CMPS. The composition of the phase inversion could be estimated and closely coincided from the observed morphology experimental results. The rheological behavior of the blends, from oscillatory measurements, was found to vary in relation to the composition, and reflected the morphologies of the blends. PLA showed Newtonian flow behavior, while CMPS showed strong shear thinning behavior. The relationships between the morphology and rheological properties were observed in detail.

Rheological Characteristics of Thermal Gelatinized Corn Starch Solution (옥수수 전분 호화액의 리올로지 특성)

  • Kim, Ju-Bong;Lee, Shin-Young;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.24 no.1
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    • pp.54-58
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    • 1992
  • The reological properties of commercial corn starch solutions at various concentrations($4{\sim}9%$) and temperatures($30{\sim}60^{\circ}C$) were investigated. The rheological behavior of corn starch solutions was illustrated by Herschel-Bulkley equation and exhibited pseudoplastic behavior with yield stress. The degree of pseudoplasticity of starch solution increased as the starch concentration increased but was independent on temperature. Apparent viscosity and yield stress of starch solutions were exponentially dependent on concentration and temperature. The critical concentrations for sol-gel transition and for the onset of close-packing of the starch granules were $6.22{\sim}6.52%\;and\;2.68{\sim}2.78%$ respectively.

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A Fundamental Study on Bingham Characteristics of Electro-Rheological Fluids for Control System Application (제어 시스템 적용을 위한 ER유체의 빙햄 특성에 관한 기초적 연구)

  • Jang, Sung-Cheol;Jeong, Young-Bin;Jang, Gil-Sik
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.3 no.3
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    • pp.86-92
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    • 2004
  • This paper describes the properties of temperature-viscosity characteristics of hydrous and anhydrous electro-rheological fluids containing starch and titanium particle in silicone oil ER effects arise from electrostatic forces between the starch particles and titanium particles dispersed to the electrically insulating silicone oil induced when electric field is applied ER fluids under electric field control have been found to provide resonable estimates of ER fluid viscosity variation characteristics. Yield shear stress of the ER fluids were measured the couette cell type rheometer as a function of electrlc fields. The outer cup is connected to positive electrode(+) and bob becomes ground(-). The electrie field is applied by high voltage DC power supply. In this experiment shear rates were increased from 0 to 200 $s^{-1}$ in 2 minutes. The ER fluid's viscosity change is very small and stable at the temperature range of $40^{\circ}C$ to $60^{\circ}C$. Therefore, applications of a new ER fluid to control systems application are suitable.

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Friction and Wear Properties of Improved Polyurethane Based Magneto-Rheological Elastomer (향상된 폴리우레탄 기반 자기유변탄성체의 마찰 마모 특성연구)

  • Lian, Chenglong;Hong, Sung-Geun;Lee, Kwang-Hee;Lee, Chul-Hee;Kim, Cheol-Hyun
    • Tribology and Lubricants
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    • v.28 no.6
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    • pp.333-339
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    • 2012
  • Typical magneto-rheological (MR) elastomers consist of silicon-based material. A number of studies have been carried out to evaluate the vibration and tribological characteristics of silicon-based MR e-lastomers. However, these elastomers have quite low strength, so they have low wear resistance. In this study, polyurethane-based MR elastomers with performances better than those of MR elastomers. Experiments have been conducted on different MR elastomers (Pu MR elastomer, Pu-Si MR elastomer, and Pu-wrapped-Si MR elastomer) and different predefined magnetic directions (Non-Direction, Vertical Direction, and Horizontal Directionality) to evaluate the friction and wear performance under a magnetic field. The results show that Pu-wrapped-Si MR elastomer with a horizontal predefined magnetic field has the best performance in terms of wear.

Temperature-Dependent Hysteresis Investigation of Electro - Rheological Fluid Using Preisach Model (Preisach 모델을 이용한 ER 유체의 온도별 히스테리시스 특성 고찰)

  • 한영민;이호근;최승복;최형진
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.316-322
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    • 2002
  • This paper presents the temperature-dependent hysteresis identification of an electro-rheological (ER) fluid under various operating temperatures using the Preisach model. As a first step, polymethylaniline (PMA) particles are prepared and mixed with silicone oil to make an ER fluid. A couette type electroviscometer is then employed to obtain the field-dependent shear stress. In order to show the suitability of the Preisach model to predict a physical hysteresis phenomenon of the ER fluid, two significant properties; the minor loop property and the wiping-out property are experimentally examined under three dominant temperature conditions. Subsequently, the Preisach model fur the PMA-based ER fluid is identified using experimental first order descending (FOD) curves. The effectiveness of the identified hysteresis model is verified in the time domain by comparing the predicted field-dependent shear stress with the measured one under the both specified and unspecified temperatures. In addition, the hysteresis model proposed in this work is compared to Bingham model.

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Measurement of Shear Modulus Increment Ratio of Magneto-rheological Elastomer based on Silicon Matrix due to Induced Magnetic field (Silicon Matrix MRE 의 인가자기장에 따른 전단계수 증가율 측정)

  • Oh, Jae-Eung;Roh, Jeong-Joon;Lee, Sun-Hoon;Kim, Jin-Su;Jeong, Un-Chang
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.288-291
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    • 2014
  • MRE(Magneto-rheological Elastomer) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, Silicon was used as a matrix in order to manufacture MREs. Magnetic reactive powder(MRP), having rapid magnetic reaction, was selected as a magnetic particle to give magnetic field reactive modulus. The mechanical properties of manufactured MREs were measured with the application of magnetic field. The analysis of MR effect was carried out by FFT analyzer with various induced magnetic field. As the addition of CIP and induced magnetic field intensity increased, increment of MR effect was observed.

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Constitutive Equations for Dilute Bubble Suspensions and Rheological Behavior in Simple Shear and Uniaxial Elongational Flow Fields

  • Seo Dongjin;Youn Jae Ryoun
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.131-138
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    • 2005
  • A theoretical model is proposed in order to investigate rheological behavior of bubble suspension with large deformation. Theoretical constitutive equations for dilute bubble suspensions are derived by applying a deformation theory of ellipsoidal droplet [1] to a phenomenological suspension theory [2]. The rate of deformation tensor within the bubble and the time evolution of interface tensor are predicted by applying the proposed constitutive equations, which have two free fitting parameters. The transient and steady rheological properties of dilute bubble suspensions are studied for several capillary numbers (Ca) under simple shear flow and uniaxial elongational flow fields. The retraction force of the bubble caused by the interfacial tension increases as bubbles undergo deformation. The transient and steady relative viscosity decreases as Ca increases. The normal stress difference (NSD) under the simple shear has the largest value when Ca is around 1 and the ratio Of the first NSD to the second NSD has the value of 3/4 for large Ca but 2 for small Ca. In the uniaxial elongational flow, the elongational viscosity is three times as large as the shear viscosity like the Newtonian fluid.

Investigation on Temperature-dependent Hysteresis of Electro-rheological Fluid Using Preisach Model (Preisach 모델을 이용한 ER유체의 온도별 히스테리시스 특성 고찰)

  • 한영민;이호근;최승복;최형진
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.12 no.8
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    • pp.648-656
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    • 2002
  • This paper presents the identification of temperature-dependent hysteresis of an electro-rheological (ER) fluid under various operating temperatures using the Preisach model. As a first step, polymethylaniline (PMA) particles are prepared and mixed with silicone oil to make an ER fluid. A couette type electroviscometer is then employed to obtain the field-dependent shear stress. In order to show the suitability of the Preisach model to predict a physical hysteresis phenomenon of the ER fluid, two significant properties; the minor loop property and the wiping-out property are experimentally examined under three dominant temperature conditions. Subsequently, the Preisach model for the PMA-based ER fluid is identified using experimental multiple first order descending (FOD) curves. The effectiveness of the identified hysteresis model is verified in the time domain by comparing the predicted field-dependent shear stress with the measured one under the both specified and unspecified temperatures. In addition, the hysteresis model proposed in this work is compared to Bingham model.