• Title/Summary/Keyword: resistance change

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A Study on the Modification of NH4+Y-zeolite for Improving Adsorption/Desorption Performance of Benzene (NH4+Y-zeolite의 개질을 통한 벤젠 흡·탈착 성능 증진 연구)

  • Jang, Young Hee;Noh, Young Il;Lee, Sang Moon;Kim, Sung Su
    • Clean Technology
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    • v.25 no.1
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    • pp.33-39
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    • 2019
  • A.C (activated carbon) is mainly used to remove VOCs (volatile organic compounds), however, it has many problems such as fire risk due to increasing of adsorbent surface temperature during VOCs ad/desorption, increased cost by frequent replacement cycles requirement and performance degradation when containing moisture. In order to solve these problems, many researches, hydrophobic zeolite adsorbents, have been reported. In this study, $NH_4{^+}Y$-zeolite was synthesized with Y-zeolite through steam treatment and acid treatment, which is one of the hydrophobic modification methods, to secure high surface area, thermal stability and humidity resistance. The Y, Y-550-HN, Y-600-HN and Y-650-HN had adsorption capacities of $23mg\;g^{-1}$, $38mg\;g^{-1}$, $77mg\;g^{-1}$, $61mg\;g^{-1}$. The change of Si/Al ratio, which is an index to confirm the degree of modification, was confirmed by XRF (X-ray fluorescence spectrometer) analysis. As a result, the adsorbtion performance was improved when Y-zeolite modified, and the Si/Al ratio of Y, Y-550-HN, Y-600-HN, Y-650-HN were increased to 3.1765, 6.6706, 7.3079, and 7.4635, respectively. Whereas it was confirmed that structural crystallization due to high heat treatment temperature affected performance degradation. Therefore, there is an optimal heat treatment temperature of Y-zeolite, optimum modification condition study could be a substitute for activated carbon as a condition for producing an adsorbent having high durability and stability.

In vitro wear behavior between enamel cusp and three aesthetic restorative materials: Zirconia, porcelain, and composite resin

  • Jang, Yong-Seok;Nguyen, Thuy-Duong Thi;Ko, Young-Han;Lee, Dae-Woo;Baik, Byeong Ju;Lee, Min-Ho;Bae, Tae-Sung
    • The Journal of Advanced Prosthodontics
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    • v.11 no.1
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    • pp.7-15
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    • 2019
  • PURPOSE. The aim of this study was to identify the effects of three aesthetic restorative materials on the wear between tooth and restoration by a pin-on-disk manner. MATERIALS AND METHODS. Six aesthetic restorative materials were used to prepare disk specimens for wear test, which were Lava Zirconia as zirconia group, Vintage MP and Cerabien ZR as veneering porcelain group, Gradia Direct microhybrid composite containing prepolymerized fillers, Filtek Z250 microhybrid composite containing zirconia glass and colloidal silica particles, and Filtek Z350 nanocomposite as composite resin group. Vertical loss of the worn cusp, change of the surface roughness of the restoration materials, and the surface topography were investigated after wear test under 9.8-N contact load. RESULTS. The porcelain groups (Vintage MP and Cerabien ZR) caused the largest vertical loss of teeth when compared with those of the composite resin and zirconia groups, and Filtek Z250 microhybrid composite results in the second-largest vertical loss of teeth. The surface of Filtek Z350 nanocomposite was deeply worn out, but visible wear on the surface of the zirconia and Gradia Direct microhybrid composite was not observed. When the zirconia surface was roughened by sand-blasting, vertical loss of teeth considerably increased when compared with that in the case of fine polished zirconia. CONCLUSION. It was identified that microhybrid composite resin containing a prepolymerized filler and zirconia with reduced surface roughness by polishing were the most desirable restorative materials among the tested materials to prevent the two-body wear between aesthetic restorative material and tooth.

High Temperature Corrosion Effect of Superheater Materials by Alkali Chlorides (염화알칼리에 의한 과열기 소재의 고온부식 영향)

  • Kim, Beomjong;Jeong, Soohwa;Kim, Hyesoo;Ryu, Changkook;Lee, Uendo
    • Clean Technology
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    • v.24 no.4
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    • pp.339-347
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    • 2018
  • In order to cope with environmental problems and climate change caused by fossil fuels, renewable energy supply is increasing year by year. Currently, waste energy accounts for 60% of renewable energy production. However, waste has a lower calorific value than fossil fuels and contains various harmful substances, which causes serious problems when applied to power generation boilers. In particular, the chlorine in the waste fuel increases slagging and fouling of boiler heat exchangers, leading to a reduction in thermal efficiency and the main cause of high temperature corrosion, lowering facility operation rate and increasing operating cost. In this study, the high temperature corrosion experiments of superheater materials (ASME SA213/ASTM A213 T2, T12 and T22 alloy steel) by alkali chlorides were conducted, and their corrosion characteristics were analyzed by the weight loss method and SEM-EDS. Experiments show that the higher the temperature and chloride content, the more corrosion occurs, and KCl further corrodes the materials compared to NaCl under the same condition. In addition, the higher the chromium content of the material, the better the corrosion resistance to the alkali chlorides.

Study on the Crack and Thermal Degradation of GFRP for UPE Gelcoat Coated Underground Pipes Under the High Temperature Water-Immersion Environment (고온 수침 환경에서 UPE 겔코트 코팅된 지중 매설 파이프용 GFRP의 열화 및 크랙 발생 특성에 관한 연구)

  • Kim, Daehoon;Eom, Jaewon;Ko, Youngjong;Lee, Kang-Il
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.4
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    • pp.169-177
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    • 2018
  • Glass fiber reinforced polyester (GFRP) composites are widely used as structural materials in harsh environment such as underground pipes, tanks and boat hulls, which requires long-term water resistance. Especially, these materials might be damaged due to delamination between gelcoat and composites through an osmotic process when they are immersed in water. In this study, GFRP laminates were prepared by surface treatment of UPE (unsaturated polyester) gelcoat by vacuum infusion process to improve the durability of composite materials used in underground pipes. The composite surface coated with gelcoat was examined for surface defects, cracking, and hardness change characteristics in water-immersion environments (different temperatures of $60^{\circ}C$, $75^{\circ}C$, and $85^{\circ}C$). The penetration depth of cracks was investigated by micro CT imaging according to water immersion temperature. It was confirmed that cracks developed into the composites material at $75^{\circ}C$ and $85^{\circ}C$ causing loss of durability of the materials. The point at which the initial crack initiated was defined as the failure time and the life expectancy at $23^{\circ}C$ was measured using the Arrhenius equation. The results from this study is expected to be applied to reliability evaluation of various industrial fields where gelcoat is applied such as civil engineering, construction, and marine industry.

Physiochemical Characteristics and its Applicable Potential of Blast Furnace Slag Grout Mixtures of Sodium Silicate and Calcium Hydroxide (규산소다 및 수산화칼슘을 적용한 고로슬래그 그라우트의 적용성 및 물리화학적 특성)

  • Kim, Joung-Souk;Yoon, Nam-Sik;Xin, Zhen-Hua;Moon, Jun-Ho;Park, Young-Bok;Kim, Young-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.1
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    • pp.200-207
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    • 2019
  • Cement is one of the most commonly used materials in the construction and civil engineering industry. However, emissions of carbon dioxide generated during the production of cement have been linked to climate change and environment pollutants. In order to replace cement, many studies have been actively performed research to utilizing Blast Furnace Slag(BFS), which is a byproduct of the steel industry. This study aims to investigate the physiochemical properties of the BFS powder based grout to determine whether it can be used as an environment-friendly grout material. As a fine powder, BSF can be used instead of cement grout due to its potential hydraulic property. BSF has also been known for its ability to strengthen materials long-term and to densify the internal structure of concrete. In order to investigate the physicochemical properties of the BFS powder based grout as a grout material, in this study assessment tests were performed through a gel-time measurement, uniaxial compressive strength, and chemical resistance tests, and heavy-metal leaching test. Characteristics and advantages of the slag were studied by comparing slag and cement in various methods.

Evaluation of Soil Disturbance Due to Bucket Installation in Sand (모래지반에서 버켓기초 설치에 의한 지반교란 평가)

  • Kim, Jae-Hyun;Lee, Seung-Tae;Kim, Dong-Soo
    • Journal of the Korean Geotechnical Society
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    • v.34 no.11
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    • pp.21-31
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    • 2018
  • Bucket foundations are widely used in offshore areas due to their various benefits such as easy and fast installations. A bucket is installed using self-weight and the hydraulic pressure difference across the lid generated by pumping out water from inside the bucket. When buckets are installed in high permeable soil such as sands, upward seepage flow occurs around the bucket tip and interior, leading to a decrease in the effective stress in the soil inside the buckets. This process reduces the penetration resistance of buckets. However, the soil inside and outside the bucket can be disturbed due to the upward seepage flow and this can change the soil properties around the bucket. Moreover, upward seepage flow can create significant soil plug heave, thereby hindering the penetration of the bucket to the target depth. Despite of these problems, soil disturbance and soil plug heave created by suction installation are not well understood. This study aims to investigate the behavior of soil during suction installation. To comprehend the phenomena of soil plug heave during installation, a series of small-scale model tests were conducted with different testing conditions. From a series of tests, the effects of tip thickness of bucket, penetration rate, and self-weight were identified. Finally, soil properties inside the bucket after installation were approximated from the measured soil plug heave.

Discharge Computation from Float Measurement in Vegetated Stream (부자 측정 시 식생을 고려한 유량산정에 관한 연구)

  • Lee, Tae Hee;Jung, Sung Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.39 no.2
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    • pp.307-316
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    • 2019
  • Development of vegetation in stream channel increases resistance to flow, resulting in increase in river stage upon flood and affecting change in stage-discharge relationship. Vegetation revealed in stream by water level reaching a peak and then declined upon flood is mostly found as prone. Taking an account of flow distribution with the number of vegetation, prone vegetation layer might be at height where discharge rate is zero (0) (Stephan and Guthnecht, 2002). However, there is a tendency that flow rate is overestimated when applying the height of river bed to flow area with no consideration of the height of vegetation layer in flow rate by float measurement. In this study, reliable flow measurement in stream with vegetation was calculated by measuring the height of vegetation layer after flood and excluding the vegetation layer-projected area from the flow area. The result showed the minimum 4.34 % to maximum 10.82 % of flow deviation depending on the scale of discharge. Accordingly, reliable velocity-area methods would be determined if vegetation layer-projected area in stream is considered in flow rate estimation using the flow area during the flood.

Concept Analysis of Frail Elderly based on Walker and Avant's Method (Walker와 Avant 방법에 근거한 허약 노인 개념 분석)

  • Kim, Jae-Hyeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.394-405
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    • 2019
  • The purpose of this study is to clarify the concept of the frail elderly and to obtain theoretical evidence. The research method was conducted using the basic principles for conceptual analysis of Walker and Avant(2005). As a Result of a review of the literature about how to utilize the concept of a frail elderly, frail elderly might be in the intermediate state of health and disease. They can be defined as physically vulnerable in the sarcopenia, inflammation, insulin resistance, and preceding advanced disease, lead to hospitalization, falls, disability, and death. The attributes were physiological, psychological, and socio-environmental and economic factors, so they had multidimensional factors. They were required the assist daily living of another person. Also, their attributes had decreased the amount of recovery time and degree, and exhaustion. The attributes of frail elderly consisted of these facts: dynamic process, multidimensional factors, dependency, vulnerability. The frail elderly was a dynamic process that involves the possibility of change to health and disease, and include physical, mental, cognitive, and social environmental factors. In addition, the frail elderly was difficulty in daily life, physical vulnerability and difficulty in adaption. In conclusion, frail elderly as defined by the results of this study will contribute to the foundation of health care systems, including community visiting nursing to understand the level of frail elderly and systemic management to do not go into long term care.

The Roles of Lactic Acid Bacteria for Control of Fungal Growth and Mycotoxins (곰팡이 생육 및 곰팡이 독소 생산의 억제에 있어서의 유산균의 역할)

  • Kim, Jihoo;Lee, Heeseob
    • Journal of Life Science
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    • v.30 no.12
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    • pp.1128-1139
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    • 2020
  • Over recent years, it has become evident that food and agricultural products are easily contaminated by fungi of Aspergillus, Fusarium, and Penicillium due to rapid climate change, which is not only a global food quality concern but also a serious health concern. Owing to consumers' interest in health, resistance to preservatives such as propionic acid and sorbic acid (which have been used in the past) is increasing, so it is necessary to develop a substitute from natural materials. In this review, the role of lactic acid bacteria as a biological method for controlling the growth and toxin production of fungi was examined. According to recent studies, lactic acid bacteria effectively inhibit the growth of fungi through various metabolites such as organic acids with low molecular weight, reuterin, proteinaceous compounds, hydroxy fatty acids, and phenol compounds. Lactic acid bacteria effectively reduced mycotoxin production by fungi via adsorption of mycotoxin with lactic acid bacteria cell surface components, degradation of fungal mycotoxin, and inhibition of mycotoxin production. Lactic acid bacteria could be regarded as a potential anti-fungal and anti-mycotoxigenic material in the prevention of fungal contamination of food and agricultural products because lactic acid bacteria produce various kinds of potent metabolic compounds with anti-fungal activities.

Reconfiguration of Physical Structure of Vegetation by Voxelization Based on 3D Point Clouds (3차원 포인트 클라우드 기반 복셀화에 의한 식생의 물리적 구조 재구현)

  • Ahn, Myeonghui;Jang, Eun-kyung;Bae, Inhyeok;Ji, Un
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.40 no.6
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    • pp.571-581
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    • 2020
  • Vegetation affects water level change and flow resistance in rivers and impacts waterway ecosystems as a whole. Therefore, it is important to have accurate information about the species, shape, and size of any river vegetation. However, it is not easy to collect full vegetation data on-site, so recent studies have attempted to obtain large amounts of vegetation data using terrestrial laser scanning (TLS). Also, due to the complex shape of vegetation, it is not easy to obtain accurate information about the canopy area, and there are limitations due to a complex range of variables. Therefore, the physical structure of vegetation was analyzed in this study by reconfiguring high-resolution point cloud data collected through 3-dimensional terrestrial laser scanning (3D TLS) in a voxel. Each physical structure was analyzed under three different conditions: a simple vegetation formation without leaves, a complete formation with leaves, and a patch-scale vegetation formation. In the raw data, the outlier and unnecessary data were filtered and removed by Statistical Outlier Removal (SOR), resulting in 17%, 26%, and 25% of data being removed, respectively. Also, vegetation volume by voxel size was reconfigured from post-processed point clouds and compared with vegetation volume; the analysis showed that the margin of error was 8%, 25%, and 63% for each condition, respectively. The larger the size of the target sample, the larger the error. The vegetation surface looked visually similar when resizing the voxel; however, the volume of the entire vegetation was susceptible to error.